Novel C3N4/PANI@PA for enhancement of fire protection and smoke suppression in intumescent fire retardant epoxy coatings

2021 ◽  
Vol 161 ◽  
pp. 106496
Author(s):  
Huixin Dong ◽  
Wei Liu ◽  
Wenjiao Chen ◽  
Tingting Feng ◽  
Yaxuan Wang ◽  
...  
2021 ◽  
Vol 1038 ◽  
pp. 468-479
Author(s):  
Olga Skorodumova ◽  
Olena Tarakhno ◽  
Olena Chebotaryova ◽  
Oleg Bezuglov ◽  
Fatih Mehmet Emen

Based on the generalization of research results on the processes of obtaining SiO2 sols using tetraethoxysilane and ethyl silicates, the main factors influencing the elasticity of silica coatings on cotton fabrics and their fire-retardant properties are considered. The possibility of forming covalent bonds between the functional groups of cellulose, gel coating and flame retardant layer is considered, which explains the strong fixation of a thin layer of coating on the fibers of the fabric and improve its fire protection. The use of the developed compositions for fire-retardant elastic coatings based on ethyl silicate allows to increase the time of complete burning of cotton from 30s (untreated fabric) to 600s (treated with binary coating).


2020 ◽  
Vol 11 (3) ◽  
Author(s):  
V. V. Lomaha ◽  
O. Yu. Tsapko ◽  
Yu. V. Tsapko ◽  
O. P. Bondarenko

Reducing the fire prevention of timber is not only an economic task, but also has a social and environmental focus. From economic, technological and environmental perspective, an important problem in ensuring the viability and safe operation of construction sites is the development of fire-retardant coatings for wooden structures. The construction is increasingly looking for new highly effective means of fire protection of wood and wood products which should not only ensure the standardized fire resistance of wood, but also to maintain its operational parameters to solve environmental safety and durability. Studies of the effect of the radiation panel on the ignition of the wood sample have set the parameters of the flame ignition, which makes it possible to influence this process. It is proved that they consist in the formation of a layer of organic material on the surface, which provides heating to a critical temperature, when the intensive decomposition of the material begins with the release of the required amount of combustible gases and their ignition. This makes it possible to determine the effect of fire protection and the properties of protective compositions on the process of slowing down the rate of burning of wood. Experimental studies have confirmed that the untreated sample of wood, under the thermal action of the radiation panel has taken up, the flames spread over the entire surface, which led to its combustion. The application of a fire retardant varnish under the influence of temperature leads to a layer of foam coke and inhibition of heat transfer of high-temperature flame to the material and its ignition. Thanks to this, it became possible to determine the conditions for changing the parameters of combustion and braking during fire protection of wood, by forming a barrier for thermal conductivity. Thus, there is reason to argue for the possibility of directional control of the processes of fire protection of wood by the use of fireproof coatings that can form a protective layer on the surface of the material, which slows down the rate of burning of wood.


Author(s):  
Lyubov Vakhitova ◽  
◽  
Nadiya Taran ◽  
Konstantin Kalafat ◽  
◽  
...  

Purpose. Identification of the main directions of evolution of scientific researches concerning development and improvement of fire protective reactive coatings of intumescent type for steel constructions. Methods. Analysis of literature sources, study and generalization of information, classification and modeling of chemical processes. Results. As a result of the performed researches it has been shown that of all the developed reactive fire protection systems for increasing the fire resistance of steel structures the intumescent composition of ammonium polyphosphate/ pentaerythritol / melamine / polymer is the most widespread and economically justified. To reduce the cost of fire protection measures, it is necessary to improve the coatings of the intumescent type in the following main areas: increasing of fire protection efficiency with a decrease in the thickness of the fire protection layer; prolongation of life time with strengthening of resistance to external factors; reducing the cost of the prescription composition of intumescent paint due to the use of nanomaterials. Scientific novelty. It has been established that nanoclays, nanooxides of metals and silicon, LDH compounds and their analogues should be considered the most promising and multifunctional. The presence of nanomaterials in intumescent compositions allows to increase the environmental parameters of fire-retardant treatment due to the rejection of halogen flame retardants, boron compounds, formaldehyde resins. In addition, the presence of nanocompounds in intumescent coatings significantly reduces smoke in fire. Practical significance. The conclusions obtained from the literature review are of practical importance for the development of new approaches to the design of fire-fighting materials with improved performance through the use of nanomaterials, which provides a strong fire retardant foam char layer and provides rigidity of the insulation frame.


2010 ◽  
Vol 26-28 ◽  
pp. 608-611 ◽  
Author(s):  
Chang Kun Chen ◽  
Dong Zhang

A new design method for fire protection, based on analytic hierarchy process (AHP), was put forward, to explore an economic and secure strategy for fire protection of steel staggered-truss structure (SSTS). The chords and web members of SSTS were classified into different important grades by AHP according to the influence which components make on the stability of structure at elevated temperature. And the components are protected by different levels based on the important grades. Furthermore, a comparative investigation was conducted in order to appraise the economic and practical performance of the provided new fire protection method with traditional fire protection. The results indicate that the proposed fire protection strategy for SSTS based on AHP could achieve higher security with the same volume of fire retardant coatings.


Buildings ◽  
2020 ◽  
Vol 10 (10) ◽  
pp. 185
Author(s):  
Tatiana Eremina ◽  
Dmitry Korolchenko

The influence of basic components of intumescent paint on fire protection properties is studied. The resulting changes in properties are assessed by the intumescence coefficient and thermal analysis data. Influence of the binder polymer composition on fire protection properties under the same conditions was evaluated, quantitatively using the example of fire-retardant water-dispersion paint; the best result was obtained in the formulation based on vinyl acetate copolymers. The brands of ammonium polyphosphate (PFA) from different manufacturers were investigated under the same conditions. The results of the thermal analysis and testing of the physicochemical properties of the samples on various PFAs are presented, with conclusions about their influence on the fire-retardant properties of the paint. The results of the thermal analysis of the influence of orthophosphoric acid, as a modifying additive, on the fire-retardant properties of the paint are presented.


ce/papers ◽  
2019 ◽  
Vol 3 (3-4) ◽  
pp. 653-658
Author(s):  
Jonas Tolstrup ◽  
Luisa Giuliani ◽  
Harikrishna Narasimhan ◽  
Jakob Laigaard Jensen ◽  
Grunde Jomaas

2020 ◽  
Vol 992 ◽  
pp. 605-609
Author(s):  
L. Pestereva ◽  
N. Shakirov ◽  
Оlga G. Shakirova

This article discusses one of the methods of fire protection, namely, the coating of metal structures with fire retardant paints. Intumescent coatings are currently the most widely used. Fire retardant coatings based on epoxy paints have high performance characteristics and are promising. As the foaming component, the system of ammonium polyphosphate - pentaerythritol - melamine (in a ratio of 2: 1: 1) was selected. The fire retardant properties of the developed material were investigated. Coatings on the base of the developed fire retardant paint allow us to increase own level of fire resistance of metal constructions up to three (90 minutes).


Sign in / Sign up

Export Citation Format

Share Document