Dense radical formation in L-alanine-3,3,3-d3 and L-alanine-d4 by 1.5 keV soft X-ray irradiation

Author(s):  
Seiko Nakagawa ◽  
Toshitaka Oka ◽  
Kentaro Fujii ◽  
Akinari Yokoya
Keyword(s):  
2019 ◽  
Vol 10 (6) ◽  
pp. 1382-1387 ◽  
Author(s):  
Kirsten Schnorr ◽  
Aditi Bhattacherjee ◽  
Katherine J. Oosterbaan ◽  
Mickaël G. Delcey ◽  
Zheyue Yang ◽  
...  

1995 ◽  
Vol 50 (12) ◽  
pp. 1799-1810 ◽  
Author(s):  
Hermann Josef Frohn ◽  
Thorsten Schroer ◽  
Gerald Henkel

The arylxenonium cation in the salt [C6F5Xe]+ [AsF6]- is isoelectronic to C6F5I, but coordinatively unsaturated with respect to N-bases like MeCN and pyridines. Co-ordination of strongly basic pyridines causes weakening of the Xe-C bond and C6F1 radical formation. The thermal decomposition of pyridine co-ordinated arylxenonium cations gives three groups of products: C-pentafluorophenylated pyridines, N-pentafluorophenylated pyridinium and N-protonated pyridinium salts. The co-ordination ability of the different pyridines shows a good correlation (C6F5 group) with the 19F NMR shift values of the p-F atom and the coupling constants 3J (19F-129Xe). An X-ray structure analysis was performed for the co-ordination product [C6F5Xe · 2,6-C5H3F2N ]+ [AsF6]- and for [C6F5-C5H5N]+ [(C6F5)2BF2]-, which was obtained by thermolysis of the corresponding adduct.


2008 ◽  
Vol 73 (4) ◽  
pp. 470-478 ◽  
Author(s):  
I. N. Shtarkman ◽  
S. V. Gudkov ◽  
A. V. Chernikov ◽  
V. I. Bruskov

Structure ◽  
2010 ◽  
Vol 18 (11) ◽  
pp. 1410-1419 ◽  
Author(s):  
Philippe Carpentier ◽  
Antoine Royant ◽  
Martin Weik ◽  
Dominique Bourgeois
Keyword(s):  

2017 ◽  
Vol 139 (13) ◽  
pp. 4797-4804 ◽  
Author(s):  
Miguel Ochmann ◽  
Inga von Ahnen ◽  
Amy A. Cordones ◽  
Abid Hussain ◽  
Jae Hyuk Lee ◽  
...  

1994 ◽  
Vol 144 ◽  
pp. 275-277
Author(s):  
M. Karlický ◽  
J. C. Hénoux

AbstractUsing a new ID hybrid model of the electron bombardment in flare loops, we study not only the evolution of densities, plasma velocities and temperatures in the loop, but also the temporal and spatial evolution of hard X-ray emission. In the present paper a continuous bombardment by electrons isotropically accelerated at the top of flare loop with a power-law injection distribution function is considered. The computations include the effects of the return-current that reduces significantly the depth of the chromospheric layer which is evaporated. The present modelling is made with superthermal electron parameters corresponding to the classical resistivity regime for an input energy flux of superthermal electrons of 109erg cm−2s−1. It was found that due to the electron bombardment the two chromospheric evaporation waves are generated at both feet of the loop and they propagate up to the top, where they collide and cause temporary density and hard X-ray enhancements.


1994 ◽  
Vol 144 ◽  
pp. 1-9
Author(s):  
A. H. Gabriel

The development of the physics of the solar atmosphere during the last 50 years has been greatly influenced by the increasing capability of observations made from space. Access to images and spectra of the hotter plasma in the UV, XUV and X-ray regions provided a major advance over the few coronal forbidden lines seen in the visible and enabled the cooler chromospheric and photospheric plasma to be seen in its proper perspective, as part of a total system. In this way space observations have stimulated new and important advances, not only in space but also in ground-based observations and theoretical modelling, so that today we find a well-balanced harmony between the three techniques.


1994 ◽  
Vol 144 ◽  
pp. 82
Author(s):  
E. Hildner

AbstractOver the last twenty years, orbiting coronagraphs have vastly increased the amount of observational material for the whitelight corona. Spanning almost two solar cycles, and augmented by ground-based K-coronameter, emission-line, and eclipse observations, these data allow us to assess,inter alia: the typical and atypical behavior of the corona; how the corona evolves on time scales from minutes to a decade; and (in some respects) the relation between photospheric, coronal, and interplanetary features. This talk will review recent results on these three topics. A remark or two will attempt to relate the whitelight corona between 1.5 and 6 R⊙to the corona seen at lower altitudes in soft X-rays (e.g., with Yohkoh). The whitelight emission depends only on integrated electron density independent of temperature, whereas the soft X-ray emission depends upon the integral of electron density squared times a temperature function. The properties of coronal mass ejections (CMEs) will be reviewed briefly and their relationships to other solar and interplanetary phenomena will be noted.


1988 ◽  
Vol 102 ◽  
pp. 47-50
Author(s):  
K. Masai ◽  
S. Hayakawa ◽  
F. Nagase

AbstractEmission mechanisms of the iron Kα-lines in X-ray binaries are discussed in relation with the characteristic temperature Txof continuum radiation thereof. The 6.7 keV line is ascribed to radiative recombination followed by cascades in a corona of ∼ 100 eV formed above the accretion disk. This mechanism is attained for Tx≲ 10 keV as observed for low mass X-ray binaries. The 6.4 keV line observed for binary X-ray pulsars with Tx> 10 keV is likely due to fluorescence outside the He II ionization front.


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