Physico Chemical Characterization of Nanofibrous Poly(Ε-Caprolactone) Electrospun Templates for Cell Adhesion

MRS Advances ◽  
2017 ◽  
Vol 2 (49) ◽  
pp. 2689-2694
Author(s):  
Karla A. Gaspar-Ovalle ◽  
Juan V. Cauich-Rodriguez ◽  
Armando Encinas
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Cell Adhesion ◽  
Tensile Modulus ◽  
Chemical Characterization ◽  
Mechanical Analysis ◽  
Scanning Calorimetry ◽  
Water Contact ◽  
Physico Chemical ◽  
Static Water

ABSTRACTNanofibrous mats of poly ε-caprolactone (PCL) were fabricated by electrospinning. The nanofiber structures were investigated and characterized by scanning electron microscope, differential scanning calorimetry, thermogravimetric analysis, dynamic mechanical analysis, static water-contact-angle analysis and mechanical properties. The results showed that the nanofibrous PCL is an ideal biopolymer for cell adhesion, owing to its biocompatibility, biodegradability, structural stability and mechanical properties. Differential scanning calorimetry results showed that the fibrous structure of PCL does not alter its crystallinity. Studies of the mechanical properties, wettability and degradability showed that the structure of the electrospun PCL improved the tensile modulus, tensile strength, wettability and biodegradability of the nanotemplates. To evaluate the nanofibrous structure of PCL on cell adhesion, osteoblasts cells were seeded on these templates. The results showed that both adhesion and proliferation of the cells is viable on these electrospun PCL membranes. Thus electrospinning is a relatively inexpensive and scalable manufacturing technique for submicron to nanometer diameter fibers, which can be of interest in the commodity industry.

Thermal and Mechanical Properties of Cyclized Polybutadiene Dielectrics

1986 ◽  
Vol 76 ◽  
Author(s):  
C. W. Wilkins ◽  
H. E. Bair ◽  
M. G. Chan ◽  
R. S. Hutton
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Physical And Mechanical Properties ◽  
Mechanical Analysis ◽  
Infrared Analysis ◽  
Thermal And Mechanical Properties ◽  
Scanning Calorimetry ◽  
The Difference ◽  
Thermal Mechanical Analysis ◽  
Lower Glass Transition Temperature

ABSTRACTWe have studied some of the physical and mechanical properties of cyclized polybutadiene (CBR) dielectrics by dynamic mechanical analysis, thermal mechanical analysis, thermogravimetry, infrared analysis, and differential scanning calorimetry. Of interest is the difference in properties between thin (<30 μm) films which have been cured under vacuum and those which have been cured in air. Our results indicate that curing under vacuum prevents oxidation and reduces crosslinking. Vacuum cured films have 20% smaller moduli and 200 lower glass transition temperature than do films produced in air.

DEA and DSC study of cubic silsesquioxane epoxy resin nanocomposites

e-Polymers ◽  
2006 ◽  
Vol 6 (1) ◽  
Author(s):  
Newton Luiz Dias Filho ◽  
Hermes Adolfo de Aquino
Keyword(s):  
Mechanical Properties ◽  
Activation Energy ◽  
Fracture Toughness ◽  
Differential Scanning Calorimetry ◽  
Epoxy Resin ◽  
Loss Factor ◽  
Tensile Modulus ◽  
Dielectric Analysis ◽  
Epoxy Nanocomposites ◽  
Scanning Calorimetry

AbstractNon-isothermal dielectric analysis (DEA) and differential scanning calorimetry (DSC) techniques were used to study the epoxy nanocomposites prepared by reacting 1,3,5,7,9,11,13,15-octa[dimethylsiloxypropylglycidylether] pentaciclo [9.5.1.13,9.15,15 .17,13] octasilsesquioxane (ODPG) with methylenedianiline (MDA). Loss factor (ε”) and activation energy were calculated by DEA. The relationships between the loss factor, the activation energy, the structure of the network, and the mechanical properties were investigated. Activation energies determined by DEA and DSC, heat of polymerization, fracture toughness and tensile modulus show the same profile for mechanical properties with respect to ODPG content.

Pad Degradation During CMP Process: Effect of Soak in Slurry and Water on Thermal and Mechanical Properties of the CMP Pads

2003 ◽  
Vol 767 ◽  
Author(s):  
A. Tregub ◽  
G. Ng ◽  
M. Moinpour
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Thermal Gravimetric Analysis ◽  
Mechanical Analysis ◽  
Gravimetric Analysis ◽  
Thermal And Mechanical Properties ◽  
Thermal Gravimetric ◽  
Scanning Calorimetry ◽  
Modulated Differential Scanning Calorimetry ◽  
Thermal Mechanical Analysis

AbstractSoak of polyurethane-based CMP pads in tungsten slurry and de-ionized water and its effect on retention of thermal and mechanical properties of the pads was studied using Dynamic Mechanical Analysis (DMA), Thermal Mechanical Analysis (TMA), Thermal Gravimetric Analysis (TGA), and Modulated Differential Scanning Calorimetry (MDSC). Simultaneous cross-linking and plastisizing due to soak were established using DMA and MDSC analysis. The stable operating temperature range and its dependence on soak time were determined using TMA analysis. Substantial difference in diffusion behavior of the “soft” and “hard” pads was discovered: diffusion into the hard pads followed Fickian law [1], while diffusion into the multi-layer soft pads was dominated by the fast filling of the highly porous pad surface with liquid.During a traditional CMP process, which involves application of polishing pads and slurry, the pad properties can be substantially and irreversibly changed as the result of slurry/rinse water absorption.The retention of the pad properties after exposure was monitored using such thermal and mechanical techniques, as Thermal Mechanical Analysis (TMA), Dynamical Mechanical Analysis (DMA), Modulated Differential Scanning Calorimetry (MDSC), Thermal Gravimetric Analysis (TGA).

Thermotropic behavior of celecoxib-loaded beta-casein micelles: relevance to the improved bioavailability

2015 ◽  
Vol 7 (4) ◽  
Author(s):  
Hadas Perlstein ◽  
Tanya Turovsky ◽  
Peter Gimeson ◽  
Rivka Cohen ◽  
Abraham Rubinstein ◽  
...  
Keyword(s):  
Differential Scanning Calorimetry ◽  
Heat Capacity ◽  
Chemical Characterization ◽  
Scanning Calorimetry ◽  
Casein Micelles ◽  
Physiological Conditions ◽  
Physico Chemical ◽  
Beta Casein ◽  
Intraduodenal Administration

AbstractThe physico-chemical characterization of novel celecoxib-loaded beta-casein micelles (Cx/bCN) was recently described and its superiority in enhancing celecoxib bioavailability after intraduodenal administration to pigs was demonstrated. Here, using solution differential scanning calorimetry (DSC) combined with analysis of size distribution by DLS, zeta potential and changes in composition we demonstrate that the above superiority may be related to the thermotropic behavior of these micelles under physiological conditions. DSC of Cx/bCN reveals a characteristic irreversible exotherm upon heating, having its temperature of maximal change in heat capacity (T

scholarly journals Effect of short basalt fibers on durability, mechanical properties, and thermal properties of polylactic acid composites

2019 ◽  
Vol 10 (1-3) ◽  
pp. 45-59
Author(s):  
Lu Han ◽  
Fangwu Ma ◽  
Shixian Chen ◽  
Yongfeng Pu
Keyword(s):  
Mechanical Properties ◽  
Polylactic Acid ◽  
Basalt Fiber ◽  
Tensile Modulus ◽  
Accelerated Aging ◽  
Mechanical Analysis ◽  
Basalt Fibers ◽  
Scanning Calorimetry ◽  
Accelerated Aging Test ◽  
Aging Test

The effect of basalt fiber (BF) content on the properties of BF-reinforced polylactic acid (PLA) composites was investigated. Composites with 10, 20, 30, 40, 50, and 60 wt% BF were fabricated. The results revealed that (1) the mechanical properties improved with increasing BF content. The maximum tensile strength and modulus of the composites (i.e. 140 and 5050 MPa, respectively) occurred at a BF content of 50%. The maximum flexural strength, that is, 159.5 MPa was two times larger than that of the pure PLA and was obtained at a BF content of 40%. However, the mechanical properties deteriorated at BF contents >50%. (2) BF can stop storage modulus loss and are effective in improving the crystallinity, as revealed by dynamic mechanical analysis and differential scanning calorimetry measurements. The crystallinity improved from 34.6% to 54.6% with BF addition. (3) After the accelerated aging test, pure PLA was too weak for testing. However, high values of the tensile modulus (i.e. 60% that of the nonaged samples) were maintained by the BF-reinforced PLA. This resulted possibly from the high crystallinity of the PLA composites. Therefore, suitable amounts of BF as reinforcements can yield improvements in the performance of PLA composites.

The Thermal Stability and Mechanical Properties of Non-Segregating Blends of Polyimides with Copoly(Urethane-Imide)s

2020 ◽  
Vol 869 ◽  
pp. 280-295
Author(s):  
Andrei Didenko ◽  
Danila Kuznetcov ◽  
Gleb Vaganov ◽  
Valentina Smirnova ◽  
Elena Popova ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Thermal Stability ◽  
Differential Scanning Calorimetry ◽  
Mechanical Analysis ◽  
Strength Properties ◽  
Relative Content ◽  
Scanning Calorimetry ◽  
Aliphatic Polyesters ◽  
Polymer Systems ◽  
Aromatic Polyimides

The series of compositions containing thermodynamically incompatible flexible blocks of aliphatic polyesters and rigid blocks of aromatic bis (urethane) imides in the volume of polymers was obtained on the basis of multiblock (segmented) poly (urethane-imides) and related aromatic polyimides. The series includes segmented poly (urethane-imides) with different relative content of flexible and rigid blocks, non-segregating mixtures of poly (urethane-imides) and thermoplastic partially crystalline polyimide, statistical copolymers of poly (urethane-imide) with imide, and non-segregating mixtures of statistical copolymers with thermoplastic polyimide. The derived polymer systems were studied using thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical analysis. The deformation and strength properties of film samples are determined. It is shown that the properties of the studied polymers change as their content of imides blocks increases, and the transition from thermoplastic poly (urethane-imide) elastomers to thermoplastic polyimides is observed.

Thermophysical and Mechanical Properties of β-Tricalcium Phosphate Reinforced Polyhydroxybutyrate and Polyhydroxybutyrate-Co-Hydroxyvalerate Composites

2007 ◽  
Vol 334-335 ◽  
pp. 1217-1220 ◽  
Author(s):  
Ya Liu ◽  
Min Wang
Keyword(s):  
Mechanical Properties ◽  
Differential Scanning Calorimetry ◽  
Thermal Properties ◽  
Composite Materials ◽  
Tricalcium Phosphate ◽  
Tissue Repair ◽  
Mechanical Performance ◽  
Mechanical Analysis ◽  
Scanning Calorimetry ◽  
Biodegradable Composite

Two series of bioactive and biodegradable composite materials consisting of particulate β-tricalcium phosphate (β-TCP) and polyhydroxybutyrate (PHB) and its copolymer polyhydroxybutyrate-co-hydroxyvalerate (PHBV) were produced and investigated for bone tissue repair. A manufacturing route employing injection moulding was established for producing the biomedical composites. In the process, plates of composites containing 10%, 20%, 30% or 40% by volume of micro-sized TCP particles were successfully injection moulded for both TCP/PHB and TCP/PHBV composites. Thermal properties of as-produced TCP/PHB and TCP/PHBV composites were systematically evaluated using differential scanning calorimetry (DSC). The mechanical performance of TCP/PHB and TCP/PHBV composites was assessed using dynamic mechanical analysis (DMA).

scholarly journals Influence of Treated Distillate Aromatic Extract (TDAE) Content and Addition Time on Rubber-Filler Interactions in Silica Filled SBR/BR Blends

Polymers ◽  
2021 ◽  
Vol 13 (5) ◽  
pp. 698
Author(s):  
Selin Sökmen ◽  
Katja Oßwald ◽  
Katrin Reincke ◽  
Sybill Ilisch
Keyword(s):  
Mechanical Properties ◽  
Oil Content ◽  
Tensile Modulus ◽  
Mechanical Analysis ◽  
Styrene Butadiene Rubber ◽  
Butadiene Rubber ◽  
Binary Blends ◽  
Rubber Layer ◽  
Processing Aids ◽  
Rubber Filler

High compatibility and good rubber–filler interactions are required in order to obtain high quality products. Rubber–filler and filler–filler interactions can be influenced by various material factors, such as the presence of processing aids. Although different processing aids, especially the plasticizers, and their effects on compatibility have been investigated in the literature, their influence on rubber–filler interactions in highly active filler reinforced mixtures is not explicit and has not been investigated in depth. For this purpose, the influence of treated distillate aromatic extract (TDAE) oil content and its addition time on interactions between silica and rubber chains were investigated in this study. Rubber–filler and filler–filler interactions of uncured and cured silica-filled SBR/BR blends were characterized by using rubber layer L concept and dynamic mechanical analysis, whereas mechanical properties were studied by tensile test and Shore A hardness. Five parts per hundred rubber (phr) TDAE addition at 0, 1.5, and 3 min of mixing were characterized to investigate the influence of TDAE addition time on rubber–filler interactions. It was observed that addition time of TDAE can influence the development of bounded rubber structure and the interfacial interactions, especially at short time of mixing, less than 5 min. Oil addition with silica at 1.5 min of mixing resulted in fast rubber layer development and a small reduction in storage shear modulus of uncured blends. The influence of oil content on rubber–filler and filler–filler interactions were investigated for the binary blends without oil, with 5 and 20 phr TDAE content. The addition of 5 phr oil resulted in a slight increase in rubber layer and 0.05 MPa reduction in Payne effect of uncured blends. The storage tensile modulus of vulcanizates at small strains decreased from 13.97 to 8.28 MPa after oil addition. Twenty parts per hundred rubber (phr) oil addition to binary blends caused rubber layer L to decrease from 0.45 to 0.42. The storage tensile modulus of the vulcanizates and its reduction with higher amplitudes were incontrovertibly high among the vulcanizates with lower oil content, which were 13.57 and 4.49 MPa, respectively. When any consequential change in mechanical properties of styrene–butadiene rubber (SBR)/butadiene rubber (BR) blends could not be observed at different TDAE addition time, increasing amount of oil in blends enhanced elongation at break, and decreased Shore A hardness and tensile strength.

scholarly journals Relationship between the Stereocomplex Crystallization Behavior and Mechanical Properties of PLLA/PDLA Blends

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1851
Author(s):  
Hye-Seon Park ◽  
Chang-Kook Hong
Keyword(s):  
Mechanical Properties ◽  
Lactic Acid ◽  
Crystallization Behavior ◽  
Mechanical Analysis ◽  
X Ray Diffraction ◽  
Nucleation Agent ◽  
Scanning Calorimetry ◽  
Nucleation Sites ◽  
Wide Range ◽  
Degree Of Crystallization

Poly (l-lactic acid) (PLLA) is a promising biomedical polymer material with a wide range of applications. The diverse enantiomeric forms of PLLA provide great opportunities for thermal and mechanical enhancement through stereocomplex formation. The addition of poly (d-lactic acid) (PDLA) as a nucleation agent and the formation of stereocomplex crystallization (SC) have been proven to be an effective method to improve the crystallization and mechanical properties of the PLLA. In this study, PLLA was blended with different amounts of PDLA through a melt blending process and their properties were calculated. The effect of the PDLA on the crystallization behavior, thermal, and mechanical properties of PLLA were investigated systematically by thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), X-ray diffraction (XRD), polarized optical microscopy (POM), dynamic mechanical analysis (DMA), and tensile test. Based on our findings, SC formed easily when PDLA content was increased, and acts as nucleation sites. Both SC and homo crystals (HC) were observed in the PLLA/PDLA blends. As the content of PDLA increased, the degree of crystallization increased, and the mechanical strength also increased.

Sign in / Sign up

Export Citation Format

Share Document