Effect of intercalation in graphite epoxy composites on the shielding of high energy radiation

1998 ◽  
Vol 13 (8) ◽  
pp. 2297-2301 ◽  
Author(s):  
James R. Gaier ◽  
Wendie C. Hardebeck ◽  
Jennifer R. Terry Bunch ◽  
Michelle L. Davidson ◽  
Dwight B. Beery

The half-thickness and mass absorption coefficient of 13.0 keV x-rays, 46.5 keV γ-rays, and 1.16 MeV βƟ particles have been measured for pristine, bromine intercalated, and iodine monobromide intercalated pitch-based graphite fiber composites. Since these materials have been proposed to replace aluminum structures in spacecraft, the results were compared to aluminum. Pristine graphite epoxy composites were found to have about 4.0 times the half-thickness, and 40% of the mass absorption of aluminum for ionizing radiation. Bromine intercalation improved performance to 90% of the half-thickness, and 1.7 times the mass absorption coefficient of aluminum. Iodine monobromide extended the performance to 70% of the half-thickness and 3.0 times the mass absorption of aluminum. Thus, intercalation not only makes up the deficiency conventional composites have in shielding components from ionizing radiation, but actually confers advantages in mass and thickness over aluminum. The βƟ particle shielding of all the materials tested was found to be very effective. The shielding of all of the materials was found to have nearly the same mass absorption coefficient of 17.8 ± 0.9 cm2/g. Inelastic scattering processes were found to be important in βƟ particle shielding; however, the extent of inelastic scattering and thus the distribution of energies of the transmitted electrons did not vary with material.

1990 ◽  
Vol 34 ◽  
pp. 325-335 ◽  
Author(s):  
Steve J. Chipera ◽  
David L. Bish

AbstractThe mass absorption coefficient is a useful parameter for quantitative characterization of materials. If the chemical composition of a sample is known, the mass absorption coefficient can be calculated directly. However, the mass absorption coefficient must be determined empirically if the chemical composition is unknown. Traditional methods for determining the mass absorption coefficient involve measuring the transmission of monochromatic X-rays through a sample of known thickness and density. Reynolds (1963,1967), however, proposed a method for determining the mass absorption coefficient by measuring the Compton or inelastic X-ray scattering from a sample using Mo radiation on an X-ray fluorescence spectrometer (XRF). With the recent advances in solid-state detectors/electronics for use with conventional powder diffractometers, it is now possible to readily determine mass absorption coefficients during routine X-ray diffraction (XRD) analyses.Using Cu Kα radiation and Reynolds’ method on a Siemens D-500 diffractometer fitted with a Kevex Si(Li) solid-state detector, we have measured the mass absorption coefficients of a suite of minerals and pure chemical compounds ranging in μ/ρ from graphite to Fe-metal (μ/ρ = 4.6-308 using Cu Kα radiation) to ±4.0% (lσ). The relationship between the known mass absorption coefficient and the inverse count rate is linear with a correlation coefficient of 0.997. Using mass absorption coefficients, phase abundances can be determined during quantitative XRD analysis without requiring the use of an internal standard, even when an amorphous component is present.


1992 ◽  
Vol 7 (4) ◽  
pp. 194-196 ◽  
Author(s):  
Stefano Battaglia ◽  
Marco Franzini ◽  
Leonardo Leoni

AbstractThis paper describes a new method for the simultaneous determination of mineral composition, mass thickness and mass absorption coefficient of a thin layer of a crystalline substance deposited on a crystalline substrate.The samples were deposited on membrane disc filters, consisting of mixtures of cellulose acetate and cellulose nitrate. Quantitative results are achieved by measuring the diffraction intensity of the analyte and the attenuation of a reflection of the crystalline material supporting the deposited sample. The mean accuracy of the analysis was found to be: ≈ 3% for mass thickness, ≈ 1% for mass absorption coefficient and ≈ 4% for quantitative mineralogical determination.


1969 ◽  
Vol 13 ◽  
pp. 632-638 ◽  
Author(s):  
P. Lublin ◽  
P. Cukor ◽  
R. J. Jaworowski

For quantitative electron probe analysis, the raw intensity ratios must be corrected to take into account deviations due to absorption, fluoresecnce and electron beam penetration. The major correction is usually the absorption correction, so that for best results, accurate mass absorption coefficients are required. Many tables of absorption coefficients are calculated by interpolation or extrapolation from available measured values, and therefore new measurements are required for increased reliability. The region which requires the most attention for present-day probe analysis is the 2 to 10 Å range.Thin foils of the lighter metals are available for mass absorption coefficient measurements, but heavy metal foils, which must be extremely thin, are not obtainable, A method has been developed to prepare thin films of heavy metals on a suitable substrate by pyrolytic decomposition of metal organic compounds.


2007 ◽  
Vol 190 (3) ◽  
pp. 1134-1140 ◽  
Author(s):  
Ralf Moeller ◽  
Peter Setlow ◽  
Gerda Horneck ◽  
Thomas Berger ◽  
Günther Reitz ◽  
...  

ABSTRACT The role of DNA repair by nonhomologous end joining (NHEJ), homologous recombination, spore photoproduct lyase, and DNA polymerase I and genome protection via α/β-type small, acid-soluble spore proteins (SASP) in Bacillus subtilis spore resistance to accelerated heavy ions (high-energy charged [HZE] particles) and X rays has been studied. Spores deficient in NHEJ and α/β-type SASP were significantly more sensitive to HZE particle bombardment and X-ray irradiation than were the recA, polA, and splB mutant and wild-type spores, indicating that NHEJ provides an efficient DNA double-strand break repair pathway during spore germination and that the loss of the α/β-type SASP leads to a significant radiosensitivity to ionizing radiation, suggesting the essential function of these spore proteins as protectants of spore DNA against ionizing radiation.


1968 ◽  
Vol 46 (10) ◽  
pp. S1087-S1089 ◽  
Author(s):  
Miriam A. Forman

The differential mass-absorption coefficient for rigidities between 2 and 15 GeV/c for IGY-type neutron monitors at sea level and at 500 mm Hg pressure altitude has been calculated from the variation of the neutron-monitor intensity and mass-absorption coefficient with cutoff rigidity. Combined with six sea-level surveys of neutron-monitor intensity between 1954 and 1962, and assuming no time variation in the neutron-monitor mass-absorption coefficient above 15 GeV/c cutoff, the calculated differential mass-absorption coefficient implies a solar-cycle variation of about 0.04%/mm Hg at 2 GeV/c cutoff rigidity at sea level.


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