Simple and Robust Algorithm for Multiphase Equilibrium Computations at Temperature and Volume Specifications

SPE Journal ◽  
2021 ◽  
pp. 1-20
Author(s):  
Chang Lu ◽  
Zhehui Jin ◽  
Huazhou Li ◽  
Lingfei Xu

Summary Two-phase and three-phase equilibria are frequently encountered in a variety of industrial processes, such as carbon dioxide (CO2) injection for enhanced oil recovery in oil reservoirs, multiphase separation in surface separators, and multiphase flow in wellbores and pipelines. Simulation and engineering design of these processes using isothermal/isochoric (VT) multiphase equilibrium algorithms are sometimes more convenient than that using the conventional isothermal/isobaric (PT) algorithms. This work develops a robust algorithm for VT multiphase equilibrium calculations using a nested approach. The proposed algorithm is simple because a robust PT multiphase equilibrium algorithm is used in the inner loop without any further modifications, while an effective equation-solving method (i.e., Brent’s method; Brent 1971) is applied in the outer loop to solve the pressure corresponding to a given volume/temperature specification. The robustness of the VT algorithm is safeguarded by using a highly efficient trust-region-method-based PT algorithm. We demonstrate the good performance of the newly developed algorithm by applying it to calculate the isochores of fluid mixtures that exhibit both two-phase and three-phaseequilibria.

SPE Journal ◽  
2021 ◽  
pp. 1-17
Author(s):  
Saira ◽  
Emmanuel Ajoma ◽  
Furqan Le-Hussain

Summary Carbon dioxide (CO2) enhanced oil recovery is the most economical technique for carbon capture, usage, and storage. In depleted reservoirs, full or near-miscibility of injected CO2 with oil is difficult to achieve, and immiscible CO2 injection leaves a large volume of oil behind and limits available pore volume (PV) for storing CO2. In this paper, we present an experimental study to delineate the effect of ethanol-treated CO2 injection on oil recovery, net CO2 stored, and amount of ethanol left in the reservoir. We inject CO2 and ethanol-treated CO2 into Bentheimer Sandstone cores representing reservoirs. The oil phase consists of a mixture of 0.65 hexane and 0.35 decane (C6-C10 mixture) by molar fraction in one set of experimental runs, and pure decane (C10) in the other set of experimental runs. All experimental runs are conducted at constant temperature 70°C and various pressures to exhibit immiscibility (9.0 MPa for the C6-C10 mixture and 9.6 MPa for pure C10) or near-miscibility (11.7 MPa for the C6-C10 mixture and 12.1 MPa for pure C10). Pressure differences across the core, oil recovery, and compositions and rates of the produced fluids are recorded during the experimental runs. Ultimate oil recovery under immiscibility is found to be 9 to 15% greater using ethanol-treated CO2 injection than that using pure CO2 injection. Net CO2 stored for pure C10 under immiscibility is found to be 0.134 PV greater during ethanol-treated CO2 injection than during pure CO2 injection. For the C6-C10 mixture under immiscibility, both ethanol-treated CO2 injection and CO2 injection yield the same net CO2 stored. However, for the C6-C10 mixture under near-miscibility,ethanol-treated CO2 injection is found to yield 0.161 PV less net CO2 stored than does pure CO2 injection. These results suggest potential improvement in oil recovery and net CO2 stored using ethanol-treated CO2 injection instead of pure CO2 injection. If economically viable, ethanol-treated CO2 injection could be used as a carbon capture, usage, and storage method in low-pressure reservoirs, for which pure CO2 injection would be infeasible.


2021 ◽  
Vol 73 (06) ◽  
pp. 65-66
Author(s):  
Judy Feder

This article, written by JPT Technology Editor Judy Feder, contains highlights of paper SPE 200460, “A Case Study of SACROC CO2 Flooding in Marginal Pay Regions: Improving Asset Performance,” by John Kalteyer, SPE, Kinder Morgan, prepared for the 2020 SPE Improved Oil Recovery Conference, originally scheduled to be held in Tulsa, 18–22 April. The paper has not been peer reviewed. As one of the first fields in the world to use carbon dioxide (CO2) in enhanced oil recovery (EOR), the Scurry Area Canyon Reef Operators Committee (SACROC) unit of the Kelly-Snyder field in the Midland Basin of Texas provides a unique opportunity to study, learn from, and improve upon the development of CO2 flood technology. The complete paper reviews the history of EOR at SACROC, discusses changes in theory over time, and provides a look at the field’s future. Field Overview and Development History The first six pages of the paper discuss the field’s location, geology, and development before June 2000, when Kinder Morgan acquired the SACROC unit and took over as operator. Between initial gas injection in 1972 and 2000, approximately 1 TCF of CO2 had been injected into the Canyon Reef reservoir. Since 2000, cumulative CO2 injection has sur-passed 7 TCF and yielded cumulative EOR of over 180 million bbl. The reservoir is a primarily limestone reef complex containing an estimated original oil in place (OOIP) of just under 3 billion bbl. The reservoir ranges from 200 ft gross thickness in the south to 900 ft in the north, where the limestone matrix averages 8% porosity and 20-md permeability. The Canyon Reef structure is divided into four major intervals, of which the Upper Canyon zone provides the highest-quality pay. The field was discovered in 1948 at a pressure of 3,122 psi. By late 1950, 1,600 production wells had been drilled and the reservoir pressure plummeted, settling as low as 1,700 psi. Waterflooding begun in 1954 enabled the field to continue producing for nearly 20 years, at which time the operators deter-mined that another recovery mechanism would be needed to maximize recovery and reach additional areas of the field. The complete paper discusses various CO2 injection programs that were developed and applied—including a true tertiary response from a miscible CO2 flood in 1981—along with their outcomes. Acquisition and CO2-Injection Redevelopment In June 2000 Kinder Morgan acquired the SACROC Unit and took over as operator. Approximately 6.7 billion bbl of water and 1.3 TCF of CO2 had been injected across the unit to that date, but the daily oil rate of 8,700 B/D was approaching the field’s economic limit. An estimated 40% of the OOIP had been produced through the combination of recovery methods that each previous operator had used. Expanding on the conclusions of its immediate predecessor, the operator initiated large-scale CO2-flood redevelopment in a selection of project areas. These redevelopments were based on several key distinctions differentiating them from previous injection operations.


2021 ◽  
Author(s):  
Zakaria Hamdi ◽  
Nirmal Mohanadas ◽  
Margarita Lilaysromant ◽  
Oluwole Talabi

Abstract Some heavy oil production can be established using conventional methods; however, these methods are often somewhat ineffective with low recovery factors of less than 20%. Carbon dioxide (CO2) huff-n-puff or cyclic CO2 injection is one of the Enhanced oil recovery (EOR) methods that can be used in stimulating aging wells to recover some residual oil. The shut-in stage of this method results in a significant delay in the production time, and hence lower oil recovery. For the first time, in this paper, an attempt is made to overcome this issue by a novel approach, employing dual tubing completions. The aim of this is to increase the oil recovery with the production during soak time. Also, a majority of the remaining heavy oil reservoirs are carbonates, hence the research was focused on the same conditions. Numerical simulation is done using dual-tubing conditions in a dual-porosity model with conventional tubing as a base case. Optimization studies are done for injection rate, injection time, soaking time, production time, and huff-n-puff cycles. The results show that the recovery factor can increase significantly, with no discontinuity in production. Preliminary economic studies for the cases also showed a net increase in profit of 7% (1.3 million Dollars for the case chosen). This demonstrates the feasibility of the proposed method which can be implemented into conventional operations, for a more sustainable economy in the era of low oil prices.


2010 ◽  
Vol 13 (05) ◽  
pp. 791-804 ◽  
Author(s):  
Ian Taggart

Summary The solubility of carbon dioxide (CO2) in underground saline formations is considered to offer significant long-term storage capability to effectively sequester large amounts of anthropogenic CO2. Unlike enhanced oil recovery (EOR), geosequestration relies on longer time scales and involves significantly greater volumes of CO2. Many geosequestration studies assume that the initial brine state is one containing no dissolved hydrocarbons and, therefore, apply simplistic two-component solubility models starting from a zero dissolved-gas state. Many brine formations near hydrocarbons, however, tend to be close to saturation by methane (CH4). The introduction of excess CO2 in such systems results in an extraction of the CH4 into the CO2-rich phase, which, in turn, has implications for monitoring of any sequestration project and offers the possibly additional CH4 mobilization and recovery.


SPE Journal ◽  
2020 ◽  
pp. 1-9
Author(s):  
Emmanuel Ajoma ◽  
Thanarat Sungkachart ◽  
Saria ◽  
Hang Yin ◽  
Furqan Le-Hussain

Summary To determine the effect on oil recovery and carbon dioxide (CO2) storage, laboratory experiments are run with various fractions of CO2 injected (FCI): pure CO2 injection (FCI = 1), water-saturated CO2 (wsCO2) injection (FCI = 0.993), simultaneous water and gas (SWAG) (CO2) injection (FCI = 0.75), carbonated water injection (CWI) (FCI = 0.007), and water injection (FCI = 0). All experiments are performed on Bentheimer sandstone cores at 70°C and 11.7 MPa (1,700 psia). The oil phase is composed of 65% hexane and 35% decane by molar fraction. Before any fluid is injected, the core is filled with oil and irreducible water. Pressure difference across the core and production rate of gas are measured during the experiment. The collected produced fluids are analyzed in a gas chromatograph to determine their composition. Cumulative oil recovery after injection is found to be 78 to 83% for wsCO2, 78% for SWAG, 74% for pure CO2, 53% for CWI, and 35% for water. Net CO2 stored is also found to be the highest for wsCO2 (59 to 65% of the pore volume), followed by that for CO2 injection (56%) and that for SWAG (42%). These results suggest that wsCO2 injection might outperform pure CO2 injection at both oil recovery and net CO2stored.


2014 ◽  
Author(s):  
W.. Li ◽  
D. S. Schechter

Abstract Carbon dioxide (CO2) has been used commercially to recover oil from reservoirs by enhanced oil recovery (EOR) technologies for over 40 years. Currently, CO2 flooding is the second most applied EOR processes in the world behind steamflooding. Water alternating gas (WAG) injection has been a popular method to control mobility and improve volumetric sweep efficiency for CO2 flooding. The average improved recovery is about 9.7%, with a range of 6 to 20% for miscible WAG injection. Despite all the success of WAG injection, sweep efficiency during CO2 flooding is typically a challenge to reach higher oil recovery and better apply the technology. This paper proposes a new combination method called polymer alternating gas (PAG) to improve the volumetric sweep efficiency of the WAG process. The feature of this new method is that polymers are added to water during the WAG process to improve mobility ratio. In the PAG process, polymer flooding and immiscible/miscible CO2 injection are combined. To analyze the feasibility of PAG, models considering both miscible and polymer flooding processes are built to study the performance of PAG. In this paper, the sensitivity of polymer adsorption and concentration are studied. The feasibility of PAG in reservoirs with different permeabilities, different Dykstra-Parsons permeability variation coefficients (VDPs), and different fluids are also studied. A reservoir model from a typical section of the North Burbank Unit (NBU) is used to compare the performance between PAG, WAG, and polymer flooding. This study demonstrates that PAG can significantly improve recovery for immiscible/miscible flooding in homogeneous or heterogeneous reservoirs.


2019 ◽  
Author(s):  
Chem Int

Traditionally, carbon dioxide (CO2) injection has been considered an inefficient method for enhancing oil recovery from naturally fractured reservoirs. Obviously, it would be useful to experimentally investigate the efficiency of waterflooding naturally fractured reservoirs followed by carbon dioxide (CO2) injection. This issue was investigated by performing water imbibition followed by CO2 gravity drainage experiments on artificially fractured cores at reservoir conditions. The experiments were designed to illustrate the actual process of waterflooding and CO2 gravity drainage in a naturally fractured reservoir in the Brass Area, Bayelsa. The results demonstrate that CO2 gravity drainage could significantly increase oil recovery after a waterflood. During the experiments, the effects of different parameters such as permeability, initial water saturation and injection scheme was also examined. It was found that the efficiency of the CO2 gravity drainage decrease as the rock permeability decreases and the initial water saturation increases. Cyclic CO2 injection helped to improve oil recovery during the CO2 gravity drainage process which alters the water imbibition. Oil samples produced in the experiment were analyzed using gas chromatography to determine the mechanism of CO2-improved oil production from tight matrix blocks. The results show that lighter components are extracted and produced early in the test. The results of these experiments validate the premises that CO2 could be used to recover oil from a tight and unconfined matrix efficiently.


Author(s):  
Onur Coskun ◽  
Reid Grigg ◽  
Robert Svec ◽  
Sayavur I. Bakhtiyarov ◽  
Dennis Siginer

Carbon dioxide (CO2) injection has been used as a commercial process for enhanced oil recovery (EOR) since the 1970's. Recently, a new in-situ CO2 gas generation technology has been developed but not well studied. We conducted experiments to observe the dynamics of the system with different temperatures, injection sequences of chemical agents, chemical additives, and behavior of CO2 generation with respect to these varying factors and comparison of the actual CO2 pressure with the calculated values. Experiments on generation of CO2 gas as a result of reactions of gas forming and gas yielding solutions were carried out. It is shown that the injection sequence of the chemicals affects the reaction characteristics, but the total amount of CO2 gas generated does not vary significantly. Regardless of the injected solution (either gas forming or gas yielding) the maximum attainable pressures are less than the calculated pressures as a result of chemical equilibrium in the system; so this difference should be considered while calculating the size of the slug in the field applications. The brine concentration has an impact on CO2 solubility in water and so on CO2 pressure. Because of this impact, brine concentration of formation water should be considered in addition to the brine which is introduced to the system by the reaction.


SPE Journal ◽  
2011 ◽  
Vol 16 (04) ◽  
pp. 940-948 ◽  
Author(s):  
J. William Carey ◽  
Peter C. Lichtner

Summary Wellbore integrity is essential to ensuring long-term isolation of buoyant supercritical carbon dioxide (CO2) during geologic sequestration of CO2. In this paper, we summarize recent progress in numerical simulations of cement/brine/CO2 interactions with respect to migration of CO2 outside of casing. Using typical values for the hydrologic properties of cement, caprock (shale), and reservoir materials, we show that the capillary properties of good-quality cement will prevent flow of CO2 into and through cement. Rather, CO2, if present, is likely to be confined to the casing/cement or cement/formation interface. CO2 does react with the cement by diffusion from the interface into the cement, in which case it produces distinct carbonation fronts within the cement. This is consistent with observations of cement performance at the CO2-enhanced-oil-recovery Scurry Area Canyon Reef Operators Committee (SACROC) unit in west Texas (Carey et al. 2007). For poor-quality cement, flow through cement may occur and would produce a pattern of uniform carbonation without reaction fronts. We also consider an alternative explanation for cement carbonation reactions as caused by CO2 derived from caprock. We show that carbonation reactions in cement are limited to surficial reactions when CO2 pressure is low (< 10 bar), as might be expected in many caprock environments. For the case of caprock overlying natural CO2 reservoirs for millions of years, we consider the Scherer and Huet (2009) hypothesis of diffusive steady state between CO2 in the reservoir and in the caprock. We find that, in this case, the aqueous CO2 concentration would differ little from that in the reservoir and would be expected to produce carbonation reaction fronts in cements that are relatively uniform as a function of depth.


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