Preparation and characterization of self-cleaning cotton fabric loaded with self-dispersive and reactive biphasic TiO2

Abstract In this article, amino functionalized TiO2 (TiO2/KH550) was obtained in a mild reaction between 3-aminopropyltriethoxysilane and TiO2 with the aid of concentrated ammonia solution. 4-(4,6-dichloro-1,3,5-triazine-2-yl) amino) sodium benzenesulfonate (SAT) was synthesized and characterized by 1H NMR and fourier transform infrared spectroscopy (FT-IR). Self-dispersive and reactive TiO2 (TiO2/KH550/SAT) was prepared by nucleophile substitution reaction between TiO2/KH550 and SAT. Finally, cotton fabrics loaded with different amounts of TiO2/KH550/SAT were achieved by pad-dry-cure method. The chemical structure, dispersion and thermal performance of TiO2, TiO2/KH550 and TiO2/KH550/SAT were investigated by FT-IR, zeta potential and thermogravimetric analysis (TG). The crystalline phase, morphology, chemical composition and optical absorption property of cotton fabrics were studied by X-ray diffraction (XRD), scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and ultraviolet-visible diffuse reflectance spectroscopy (UV-Vis DRS). Moreover, the anti-ultraviolet, self-cleaning and washing fastness properties of cotton fabrics were investigated. It has been found that TiO2/KH550/SAT demonstrated excellent dispersion stability in aqueous even after standing for a month. Cotton fabrics loaded with TiO2/KH550/SAT possessed adorable anti-ultraviolet performance, highly efficient and durable self-cleaning activity as well as appreciable washing fastness property. The mechanism and possible reactions for the preparation of self-cleaning cotton fabrics loaded with TiO2/KH550/SAT were proposed.

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Impact of Preparative pH on the Morphology and Photocatalytic Activity of BiVO4

International Journal of Photoenergy ◽

10.1155/2012/392865 ◽

2012 ◽

Vol 2012 ◽

pp. 1-7 ◽

Cited By ~ 10

Author(s):

Yongbiao Wan ◽

Sihong Wang ◽

Wenhao Luo ◽

Lianhua Zhao

Keyword(s):

Photocatalytic Activity ◽

Photoelectron Spectroscopy ◽

Diffuse Reflectance Spectroscopy ◽

Ammonia Solution ◽

Synthesis Process ◽

X Ray Diffraction ◽

X Ray ◽

Blue Solution ◽

Absorption Performance ◽

The Impact

Adjusting pH with an ammonia solution during the synthesis, single-crystalline BiVO4has been prepared using Bi(NO3)3·5H2O and NH4VO3as starting materials through aqueous-phase precipitation at room temperature. The prepared samples are characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM). The impact of pH on structure, surface morphology, visible-light photocatalytic activity, and light absorption performance of BiVO4is explored and discussed. During the synthesis process, neither extremely acidic (low pH) nor basic (high pH) conditions are desirable for the formation of BiVO4in monoclinic phase. The highest photocatalytic performance on the degradation of a methylene blue solution is observed under pH=7.0for BiVO4in monoclinic scheelite, which is attributed to its small grain size and marked surface oxygen evolution ability.

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Preparation of BiOCl/Bi2WO6 Photocatalyst for Efficient Fixation on Cotton Fabric: Applications in UV Shielding and Self-Cleaning Performances

Materials ◽

10.3390/ma14227002 ◽

2021 ◽

Vol 14 (22) ◽

pp. 7002

Author(s):

Jiayi Chen ◽

Kuang Wang ◽

Jialong Tian ◽

Wenhui Yu ◽

Yujie Chen ◽

...

Keyword(s):

Visible Light ◽

Cotton Fabric ◽

Photoelectron Spectroscopy ◽

Cotton Fabrics ◽

Diffuse Reflection Spectroscopy ◽

X Ray Diffraction ◽

X Ray ◽

Visible Light Driven ◽

Blue Solution ◽

Self Cleaning

In this work, a visible-light-driven BiOCl/Bi2WO6 photocatalyst was obtained via a facile hydrothermal method and characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive spectrometry (EDS), X-ray photoelectron spectroscopy (XPS), ultraviolet/visible light diffuse reflection spectroscopy (UV/Vis), and photocurrent (PC). BiOCl/Bi2WO6 was modified with (3-chloro-2-hydroxypropyl) trimethyl ammonium chloride to obtain the cationized BiOCl/Bi2WO6. Cotton fabric was pretreated with sodium hydroxide (NaOH) and sodium chloroacetate solution to obtain carboxymethylated cotton fabric, which was further reacted with cationized BiOCl/Bi2WO6 to achieve finished cotton fabric. The cotton fabrics were characterized by Fourier-transform infrared spectroscopy (FT-IR), XRD, SEM, and EDS. The photocatalytic activity of the BiOCl/Bi2WO6 photocatalyst and cotton fabrics was assessed by photocatalytic degradation of MB (methylene blue) solution under simulated visible light. The self-cleaning property of cotton fabrics was evaluated by removing MB solution and red-wine stains. Results revealed that the coated cotton fabrics exhibited appreciable photocatalytic and self-cleaning performance. In addition, anti-UV studies showed that the finished cotton fabrics had remarkable UV blocking properties in the UVA and UVB regions. Therefore, the finished cotton fabric with BiOCl/Bi2WO6 can provide a framework for the development of multifunctional textiles.

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Enhanced Photocatalytic Properties of Ag-Loaded N-Doped Tio2 Nanotube Arrays

Autex Research Journal ◽

10.1515/aut-2017-0005 ◽

2018 ◽

Vol 18 (1) ◽

pp. 67-72 ◽

Cited By ~ 4

Author(s):

Dawei Gao ◽

Zhenqian Lu ◽

Chunxia Wang ◽

Weiwei Li ◽

Pengyu Dong

Keyword(s):

Electron Microscopy ◽

Photoelectron Spectroscopy ◽

Ag Nanoparticles ◽

Diffuse Reflectance Spectroscopy ◽

Emission Spectra ◽

Ammonia Solution ◽

Photocatalytic Properties ◽

X Ray ◽

Elemental Silver ◽

N Doping

Abstract Highly ordered TiO2 nanotube (TiO2 NT) arrays were prepared by anodic oxidizing method on the surface of the Ti substrate. Nitrogen-doped TiO2 nanotube (N-TiO2 NT) arrays were carried out by ammonia solution immersion, and Ag nanoparticles loaded N-doped TiO2 nanotube (Ag/N-TiO2 NT) arrays were obtained by successive ionic layer adsorption and reaction (SILAR) technique. The samples were characterized by the X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM), photoluminescence (PL) emission spectra, ultraviolet–visible (UV–vis) diffuse reflectance spectroscopy (DRS). The result indicated that the diameter and wall thickness of the TiO2 NT are 100–120 and 20–30 nm, respectively. Moreover, the morphology and structure of the highly ordered TiO2 NTs were not affected by N-doping. Furthermore, Ag nanoparticles were evenly deposited on the surface of TiO2 NTs in the form of elemental silver. Finally, the photocatalytic activity of Ag/N-TiO2 NTs was evaluated by degradation of methyl orange (MO) under visible-light irradiation. The Ag/N-TiO2 NTs exhibited enhanced photocatalytic properties, which could reach 95% after 90-min irradiation.

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Photocatalytic Self-Cleaning Cotton Fabrics Coated by Cu2(OH)PO4 under VIS/NIR Irradiation

Materials ◽

10.3390/ma12020238 ◽

2019 ◽

Vol 12 (2) ◽

pp. 238 ◽

Cited By ~ 4

Author(s):

Dawei Gao ◽

Lili Wang ◽

Chunxia Wang ◽

Tan Chen

Keyword(s):

Electron Microscopy ◽

Scanning Electron Microscopy ◽

Transmission Electron Microscopy ◽

Photoelectron Spectroscopy ◽

Cotton Fabrics ◽

X Ray ◽

Transmission Electron ◽

Self Cleaning ◽

Coated Cotton ◽

Scanning Electron

In the present work, a mild strategy was employed to obtain cotton fabrics (CFs) coated with Cu2(OH)PO4 (CHP) nanoparticles to achieve self-cleaning property. The phytic acid (IP6) assisted method was employed to synthesize nanoparticles (CHP-IP6). The as-prepared coated cotton fabrics were characterized using the following techniques: Fourier-transform infrared spectroscopy (FTIR), X-ray diffractometry (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The CHP-IP6 coated cotton fabrics showed significant photocatalytic activity, excellent photocatalytic stability, and good discoloration of methylene blue (MB) stains when exposed to sunlight, which could have important applications as tablecloths, household apparels, and industrial workwear.

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A Facile Synthesis of Graphene-WO3Nanowire Clusters with High Photocatalytic Activity for O2Evolution

International Journal of Photoenergy ◽

10.1155/2014/943537 ◽

2014 ◽

Vol 2014 ◽

pp. 1-6

Author(s):

M.-J. Zhou ◽

N. Zhang ◽

Z. H. Hou

Keyword(s):

Photocatalytic Activity ◽

Water Splitting ◽

Photoelectron Spectroscopy ◽

Diffuse Reflectance Spectroscopy ◽

High Photocatalytic Activity ◽

X Ray Diffraction ◽

X Ray ◽

Transmission Electron ◽

Charge Transfer Rate ◽

Ft Ir

In the present work, graphene-WO3nanowire clusters were synthesizedviaa facile hydrothermal method. The obtained graphene-WO3nanowire clusters were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, and ultraviolet-visible diffuse reflectance spectroscopy (DRS) techniques. The photocatalytic oxygen (O2) evolution properties of the as-synthesized samples were investigated by measuring the amount of evolved O2from water splitting. The graphene-WO3nanowire clusters exhibited enhanced performance compared to pure WO3nanowire clusters for O2evolution. The amount of evolved O2from water splitting after 8 h for the graphene-WO3nanowire clusters isca.0.345 mmol/L, which is more than 1.9 times as much as that of the pure WO3nanowire clusters (ca.0.175 mmol/L). The high photocatalytic activity of the graphene-WO3nanowire clusters was attributed to a high charge transfer rate in the presence of graphene.

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Synthesis, Characterization, and Photocatalytic Activity of Microspheres Functionalized with Porphyrin

International Journal of Photoenergy ◽

10.1155/2012/348292 ◽

2012 ◽

Vol 2012 ◽

pp. 1-10 ◽

Cited By ~ 18

Author(s):

Jin-Hua Cai ◽

Jin-Wang Huang ◽

Han-Cheng Yu ◽

Liang-Nian Ji

Keyword(s):

Photocatalytic Activity ◽

Visible Light ◽

Photoelectron Spectroscopy ◽

Diffuse Reflectance ◽

Diffuse Reflectance Spectroscopy ◽

Reflectance Spectroscopy ◽

Model Reaction ◽

X Ray Diffraction ◽

X Ray ◽

Ft Ir

In order to utilize visible light more efficiently in the photocatalytic reaction, microspheres sensitized by 5-(4-allyloxy)phenyl-10,15,20-tri(4-methylphenyl)porphyrin (APTMPP) were prepared and characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), nitrogen physisorption, scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR) and UV-vis diffuse reflectance spectroscopy, and so forth, The characterization results indicated that APTMPP-MPS- was composed of the anatase crystal phase. The morphology of the composite materials was spheriform with size of 0.3–0.7 μm and the porphyrin was chemisorbed on the surface of through a Si–O–Ti bond. The photooxidation ofα-terpinene was employed as the model reaction to evaluate the photocatalytic activity of APTMPP-MPS- microspheres under visible light. The results indicated that the photodegradation ofα-terpinene was significantly enhanced in the presence of the APTMPP-MPS- compared with the nonmodified under visible light.

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In Situ Growth of MnO2 on pDA-Templated Cotton Fabric for Degradation of Formaldehyde

10.21203/rs.3.rs-1134182/v1 ◽

2021 ◽

Author(s):

Yali Zhang ◽

Zhong Zhao ◽

Daiqi Li ◽

Guangming Cai ◽

Xiaoning Tang ◽

...

Keyword(s):

Photoelectron Spectroscopy ◽

Cotton Fabrics ◽

Interior Decoration ◽

X Ray ◽

Ft Ir ◽

Manganese Dioxide Nanoparticles ◽

Coated Fabrics ◽

The Stability ◽

New Strategies

Abstract Degradation of formaldehyde (HCHO) in interior decoration has been an urgent issue due to its toxicity nature and potential threats to human health. In this work, manganese dioxide nanoparticles (MnO2 NPs) were in situ grown on the polydopamine (pDA)-templated cotton fabrics for environmentally friendly HCHO degradation applications. The morphology, elemental composition, and crystal structure of the cotton/pDA/MnO2 were characterized by scanning electron microscopy-energy dispersive X-ray spectrum (SEM-EDX), Fourier transform infrared (FT-IR), X-ray diffractometer (XRD) and X-ray photoelectron spectroscopy (XPS), respectively. The degradation of HCHO by the as-developed cotton/pDA/MnO2 was measured in a self-made quartz reactor, and the stability of adsorption was evaluated by cyclic experiments. The results showed that the HCHO removal efficiency reached to 100% within 20 min after three cycles, suggesting that the as-prepared fabrics exhibited good stability for the degradation of HCHO. The development of MnO2 NPs coated fabrics provides new strategies in degradation HCHO in interior decoration.

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Solid-Gas Phase Photo-Catalytic Behaviour of Rutile and TiOn (1 < n < 2) Sub-Oxide Phases for Self-Cleaning Applications

Materials ◽

10.3390/ma12010170 ◽

2019 ◽

Vol 12 (1) ◽

pp. 170 ◽

Cited By ~ 4

Author(s):

Manuel Nuño ◽

Vaia Adamaki ◽

David M. Tobaldi ◽

Maria J. Hortigüela Gallo ◽

Gonzalo Otero-Irurueta ◽

...

Keyword(s):

Gas Phase ◽

Photoelectron Spectroscopy ◽

Diffuse Reflectance Spectroscopy ◽

Catalytic Performance ◽

Thermal Reduction ◽

X Ray Diffraction ◽

X Ray ◽

Electrical Conductivities ◽

Oxide Phases ◽

Self Cleaning

The solid-gas phase photo-catalytic activities of rutile TiO2 and TiOn (1 < n < 2) sub-oxide phases have been evaluated. Varying concentrations of Ti3+ defects were introduced into the rutile polymorph of titanium dioxide through carbo-thermal reduction at temperatures ranging from 350 °C to 1300 °C. The resulting sub-oxides formed were characterized by X-ray diffraction, X-ray photoelectron spectroscopy, scanning electron microscopy, impedance spectroscopy and UV-visible diffuse reflectance spectroscopy. The presence of Ti3+ in rutile exposed to high reduction temperatures was confirmed by X-ray diffraction. In addition, a Ti3+-Ti4+ system was demonstrated to enhance the photo-catalytic properties of rutile for the degradation of the air pollutants NO2 and CO2 under UV irradiation of wavelengths (λ) 376–387 nm and 381–392 nm. The optimum reduction temperature for photo-catalytic activity was within the range 350–400 °C and attributed to improved charge-separation. The materials that were subject to carbo-thermal reduction at temperatures of 350 °C and 400 °C exhibited electrical conductivities over one hundred times higher compared to the non-reduced rutile. The results highlight that sub-oxide phases form an important alternative approach to doping with other elements to improve the photo-catalytic performance of TiO2. Such materials are important for applications such as self-cleaning where particles can be incorporated into surface coatings.

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Synthesis of Magnetic Ferrocene-Containing Polymer with Photothermal Effects for Rapid Degradation of Methylene Blue

Polymers ◽

10.3390/polym13040558 ◽

2021 ◽

Vol 13 (4) ◽

pp. 558

Author(s):

Wenhui Zhu ◽

Caiyun Zhang ◽

Yali Chen ◽

Qiliang Deng

Keyword(s):

Methylene Blue ◽

Photoelectron Spectroscopy ◽

Room Temperature ◽

Degradation Rate ◽

Model Compound ◽

Vibrating Sample Magnetometer ◽

Simulated Sunlight ◽

X Ray Diffraction ◽

X Ray ◽

Ft Ir

Photothermal materials are attracting more and more attention. In this research, we synthesized a ferrocene-containing polymer with magnetism and photothermal properties. The resulting polymer was characterized by Fourier-transform infrared (FT-IR), vibrating sample magnetometer (VSM), scanning electron microscope (SEM), energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), and thermogravimetric analysis (TGA). Its photo-thermocatalytic activity was investigated by choosing methylene blue (MB) as a model compound. The degradation percent of MB under an irradiated 808 nm laser reaches 99.5% within 15 min, and the degradation rate is 0.5517 min−1, which is 145 times more than that of room temperature degradation. Under irradiation with simulated sunlight, the degradation rate is 0.0092 min−1, which is approximately 2.5 times more than that of room temperature degradation. The present study may open up a feasible route to degrade organic pollutants.

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Enhanced Photocatalytic Activity of CuWO4 Doped TiO2 Photocatalyst Towards Carbamazepine Removal under UV Irradiation

Separations ◽

10.3390/separations8030025 ◽

2021 ◽

Vol 8 (3) ◽

pp. 25

Author(s):

Chukwuka Bethel Anucha ◽

Ilknur Altin ◽

Emin Bacaksız ◽

Tayfur Kucukomeroglu ◽

Masho Hilawie Belay ◽

...

Keyword(s):

Electron Microscopy ◽

Photocatalytic Activity ◽

Photoelectron Spectroscopy ◽

Diffuse Reflectance Spectroscopy ◽

Sol Gel ◽

Pure Tio2 ◽

Component Part ◽

Energy Yield ◽

Mechanical Agitation ◽

X Ray

Abatement of contaminants of emerging concerns (CECs) in water sources has been widely studied employing TiO2 based heterogeneous photocatalysis. However, low quantum energy yield among other limitations of titania has led to its modification with other semiconductor materials for improved photocatalytic activity. In this work, a 0.05 wt.% CuWO4 over TiO2 was prepared as a powder composite. Each component part synthesized via the sol-gel method for TiO2, and CuWO4 by co-precipitation assisted hydrothermal method from precursor salts, underwent gentle mechanical agitation. Homogenization of the nanopowder precursors was performed by zirconia ball milling for 2 h. The final material was obtained after annealing at 500 °C for 3.5 h. Structural and morphological characterization of the synthesized material has been achieved employing X-ray diffraction (XRD), Fourier transform infra-red (FTIR) spectroscopy, Brunauer–Emmett–Teller (BET) N2 adsorption–desorption analysis, Scanning electron microscopy-coupled Energy dispersive X-ray spectroscopy (SEM-EDS), Transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and UV-Vis diffuse reflectance spectroscopy (UV-vis DRS) for optical characterization. The 0.05 wt.% CuWO4-TiO2 catalyst was investigated for its photocatalytic activity over carbamazepine (CBZ), achieving a degradation of almost 100% after 2 h irradiation. A comparison with pure TiO2 prepared under those same conditions was made. The effect of pH, chemical scavengers, H2O2 as well as contaminant ion effects (anions, cations), and humic acid (HA) was investigated, and their related influences on the photocatalyst efficiency towards CBZ degradation highlighted accordingly.

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