scholarly journals Graphene-Enhanced Battery Components in Rechargeable Lithium-Ion and Lithium Metal Batteries

2021 ◽  
Vol 7 (3) ◽  
pp. 65
Author(s):  
Hao-Hsun Chang ◽  
Tseng-Hsiang Ho ◽  
Yu-Sheng Su
Keyword(s):  
Hexagonal Lattice ◽  
Single Layer ◽  
Lithium Ion ◽  
High Energy ◽  
Consumer Electronics ◽  
High Energy Density ◽  
Battery Materials ◽  
Lithium Metal Batteries ◽  
The World ◽  
Vehicle Technologies

Stepping into the 21st century, “graphene fever” swept the world due to the discovery of graphene, made of single-layer carbon atoms with a hexagonal lattice. This wonder material displays impressive material properties, such as its electrical conductivity, thermal conductivity, and mechanical strength, and it also possesses unique optical and magnetic properties. Many researchers see graphene as a game changer for boosting the performance of various applications. Emerging consumer electronics and electric vehicle technologies require advanced battery systems to enhance their portability and driving range, respectively. Therefore, graphene seems to be a great candidate material for application in high-energy-density/high-power-density batteries. The “graphene battery”, combining two Nobel Prize-winning concepts, is also frequently mentioned in the news and articles all over the world. This review paper introduces how graphene can be adopted in Li-ion/Li metal battery components, the designs of graphene-enhanced battery materials, and the role of graphene in different battery applications.

Approaching the maximum capacity of nickel-rich LiNi0.8Co0.1Mn0.1O2 cathodes by charging to high-voltage in a non-flammable electrolyte of propylene carbonate and fluorinated linear carbonates

2019 ◽  
Vol 55 (9) ◽  
pp. 1256-1258 ◽  
Author(s):  
Hieu Quang Pham ◽  
Eui-Hyung Hwang ◽  
Young-Gil Kwon ◽  
Seung-Wan Song
Keyword(s):  
Energy Density ◽  
Propylene Carbonate ◽  
High Voltage ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Lithium Metal ◽  
Maximum Capacity ◽  
Lithium Metal Batteries ◽  
First Time

We report for the first time a promising approach to achieve the maximum capacity of LiNi0.8Co0.1Mn0.1O2 cathodes in a non-flammable electrolyte for safe and high-energy density lithium-ion and lithium metal batteries.

Electrical Circuit Model of Lithium-ion Batteries and Revisiting of its Parametrization Procedures

2021 ◽  
Vol 105 (1) ◽  
pp. 487-499
Author(s):  
Anna Pražanová ◽  
Václav Knap
Keyword(s):  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
Optimal Operation ◽  
Electrical Circuit ◽  
Circuit Model ◽  
Consumer Electronics ◽  
High Energy Density ◽  
Battery Management System ◽  
Electrical Circuit Model

Nowadays, Lithium-ion batteries are as the most preferable technology for consumer electronics. They found their way also to electric vehicles or even satellites, mainly due to their high energy density and long life. In the applications, the batteries require a battery management system for safe and optimal operation. Often, state estimation functionalities (as state-of-charge or state-of-health) require a running battery model. Therefore, an electrical circuit model (ECM) that accurately captures a battery behavior in suitable complexity is needed. This paper presents a three steps parametrization technique of ECM for Lithium-ion batteries based on laboratory experiments. Furthermore, an analysis of SOC and temperature dependence of battery parameters has been conducted. The developed ECM is validated, and its accuracy is evaluated by Root Mean Square Error (RMSE) and Maximal Absolute Error (MaE).

Long-lifespan lithium–metal batteries obtained using a perovskite intercalation layer to stabilize the lithium electrode

2020 ◽  
Vol 8 (18) ◽  
pp. 9137-9145
Author(s):  
Nahid Kaisar ◽  
Anupriya Singh ◽  
Po-Yu Yang ◽  
Yu-Ting Chen ◽  
Shenghan Li ◽  
...  
Keyword(s):  
Energy Density ◽  
Reduction Potential ◽  
Specific Capacity ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Low Density ◽  
Lithium Metal ◽  
Lithium Electrode ◽  
Lithium Metal Batteries

Because it has the highest specific capacity and lowest reduction potential among the elements, as well as a low density, lithium (Li) metal has been the most practical anode material for high energy density lithium-ion batteries.

Towards High Energy Density 3D-integrated Lithium-ion Micro-batteries

2009 ◽  
Vol 1168 ◽  
Author(s):  
Jos F.M. Oudenhoven ◽  
Loïc Baggetto ◽  
Rogier A.H. Niessen ◽  
Harm C.H Knoops ◽  
Merijn Donders ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Lithium Ion ◽  
Current Collector ◽  
High Energy ◽  
High Energy Density ◽  
Battery Materials ◽  
Silicon Anodes ◽  
Planar Substrates ◽  
Deposition Techniques

AbstractTo investigate the feasibility of a 3D integrated all-solid-state micro-battery, the deposition of several battery materials was investigated. Deposition techniques where used that are in principle able to deposit step conformally in 3D structures: ALD was used to create a conductive Pt current collector, and LPCVD was applied for the deposition of poly-silicon anodes and LiCoO2 cathodes. The layers, initially deposited on planar substrates, showed the expected physical and electrochemical behavior and are in principle suitable for solid state micro-batteries.

scholarly journals Optimized Interfaces in Anti-Perovskite Electrolyte-Based Solid-State Lithium Metal Batteries for Enhanced Performance

2021 ◽  
Vol 9 ◽  
Author(s):  
Pengcheng Yu ◽  
Yu Ye ◽  
Jinlong Zhu ◽  
Wei Xia ◽  
Yusheng Zhao
Keyword(s):  
Solid State ◽  
Cycling Performance ◽  
High Energy ◽  
Internal Resistance ◽  
Consumer Electronics ◽  
High Energy Density ◽  
Lithium Metal ◽  
Metal Anode ◽  
Lithium Metal Batteries ◽  
The Poor

Solid-state lithium metal batteries have attracted broad interest as a promising energy storage technology because of the high energy density and enhanced safety that are highly desired in the markets of consumer electronics and electric vehicles. However, there are still many challenges before the practical application of the new battery. One of the major challenges is the poor interface between lithium metal electrodes and solid electrolytes, which eventually lead to the exceptionally high internal resistance of the cells and limited output. The interface issue arises largely due to the poor contact between solid and solid, and the mechanical/electrochemical instability of the interface. In this work, an in situ “welding” strategy is developed to address the interfacial issue in solid-state batteries. Microliter-level of liquid electrolyte is transformed into an organic–inorganic composite buffer layer, offering a flexible and stable interface and promoting enhanced electrochemical performance. Symmetric lithium–metal batteries with the new interface demonstrate good cycling performance for 400 h and withstand the current density of 0.4 mA cm−2. Full batteries developed with lithium–metal anode and LiFePO4 cathode also demonstrate significantly improved cycling endurance and capacity retention.

scholarly journals Titanium doped niobium oxide for stable pseudocapacitive lithium ion storage and its application in 3 V non-aqueous supercapacitors

2015 ◽  
Vol 3 (43) ◽  
pp. 21706-21712 ◽  
Author(s):  
Xu Wang ◽  
Pooi See Lee
Keyword(s):  
Energy Density ◽  
Niobium Oxide ◽  
Lithium Ion ◽  
Orthorhombic Phase ◽  
High Energy ◽  
Consumer Electronics ◽  
High Energy Density ◽  
Single Wall Carbon Nanotubes ◽  
Ion Storage ◽  
Electrode Combination

Developing high energy density supercapacitors is of great importance to the transportation, consumer electronics and micro-grid energy storage sectors. We introduce a new electrode combination with titanium-doped orthorhombic phase niobium oxide and polyaniline-single wall carbon nanotubes. The organic electrolyte based supercapacitor achieves an energy density over 110.3 Wh kg−1 at 150 W kg−1.

Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery

2013 ◽  
Vol 28 (11) ◽  
pp. 1207-1212 ◽  
Author(s):  
Jian-Wen LI ◽  
Ai-Jun ZHOU ◽  
Xing-Quan LIU ◽  
Jing-Ze LI
Keyword(s):  
Energy Density ◽  
Lithium Ion Battery ◽  
Chemical Etching ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Si Nanowire

scholarly journals Na0.76V6O15/Activated Carbon Hybrid Cathode for High-Performance Lithium-Ion Capacitors

Materials ◽  
2020 ◽  
Vol 14 (1) ◽  
pp. 122
Author(s):  
Renwei Lu ◽  
Xiaolong Ren ◽  
Chong Wang ◽  
Changzhen Zhan ◽  
Ding Nan ◽  
...  
Keyword(s):  
Activated Carbon ◽  
Energy Density ◽  
Power Density ◽  
Cathode Materials ◽  
Low Cost ◽  
Lithium Ion ◽  
High Energy ◽  
Cycling Stability ◽  
High Energy Density ◽  
Artificial Graphite

Lithium-ion hybrid capacitors (LICs) are regarded as one of the most promising next generation energy storage devices. Commercial activated carbon materials with low cost and excellent cycling stability are widely used as cathode materials for LICs, however, their low energy density remains a significant challenge for the practical applications of LICs. Herein, Na0.76V6O15 nanobelts (NaVO) were prepared and combined with commercial activated carbon YP50D to form hybrid cathode materials. Credit to the synergism of its capacitive effect and diffusion-controlled faradaic effect, NaVO/C hybrid cathode displays both superior cyclability and enhanced capacity. LICs were assembled with the as-prepared NaVO/C hybrid cathode and artificial graphite anode which was pre-lithiated. Furthermore, 10-NaVO/C//AG LIC delivers a high energy density of 118.9 Wh kg−1 at a power density of 220.6 W kg−1 and retains 43.7 Wh kg−1 even at a high power density of 21,793.0 W kg−1. The LIC can also maintain long-term cycling stability with capacitance retention of approximately 70% after 5000 cycles at 1 A g−1. Accordingly, hybrid cathodes composed of commercial activated carbon and a small amount of high energy battery-type materials are expected to be a candidate for low-cost advanced LICs with both high energy density and power density.

scholarly journals Nitrogen-enriched graphene framework from a large-scale magnesiothermic conversion of CO2 with synergistic kinetics for high-power lithium-ion capacitors

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Chen Li ◽  
Xiong Zhang ◽  
Kai Wang ◽  
Xianzhong Sun ◽  
Yanan Xu ◽  
...  
Keyword(s):  
Energy Density ◽  
High Power ◽  
Power Output ◽  
Large Scale ◽  
Electrode Materials ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Chemical Doping ◽  
Lithium Ion Capacitor

AbstractLithium-ion capacitors are envisaged as promising energy-storage devices to simultaneously achieve a large energy density and high-power output at quick charge and discharge rates. However, the mismatched kinetics between capacitive cathodes and faradaic anodes still hinder their practical application for high-power purposes. To tackle this problem, the electron and ion transport of both electrodes should be substantially improved by targeted structural design and controllable chemical doping. Herein, nitrogen-enriched graphene frameworks are prepared via a large-scale and ultrafast magnesiothermic combustion synthesis using CO2 and melamine as precursors, which exhibit a crosslinked porous structure, abundant functional groups and high electrical conductivity (10524 S m−1). The material essentially delivers upgraded kinetics due to enhanced ion diffusion and electron transport. Excellent capacities of 1361 mA h g−1 and 827 mA h g−1 can be achieved at current densities of 0.1 A g−1 and 3 A g−1, respectively, demonstrating its outstanding lithium storage performance at both low and high rates. Moreover, the lithium-ion capacitor based on these nitrogen-enriched graphene frameworks displays a high energy density of 151 Wh kg−1, and still retains 86 Wh kg−1 even at an ultrahigh power output of 49 kW kg−1. This study reveals an effective pathway to achieve synergistic kinetics in carbon electrode materials for achieving high-power lithium-ion capacitors.

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