Lithiation-Induced Dilation Mapping in a Lithium-Ion Battery Electrode by 3D X-Ray Microscopy and Digital Volume Correlation

2013 ◽  
Vol 4 (4) ◽  
pp. 1300506 ◽  
Author(s):  
David S. Eastwood ◽  
Vladimir Yufit ◽  
Jeff Gelb ◽  
Allen Gu ◽  
Robert S. Bradley ◽  
...  
2012 ◽  
Vol 538-541 ◽  
pp. 2405-2408
Author(s):  
Duo Wang ◽  
Ai Dong Tang

The mixed valence copper Cu2SO3•CuSO3•2H2O with durian-like was synthesized by a simple hydrothermal method at 80 °C. The double sulfites obtained were identified by X-ray powder diffraction (XRD) and scanning electron microscopy (SEM). The electrochemical performance of the salt was evaluated by cyclic voltammetry (CV) and charge-discharge test as the lithium ion battery electrode material. The electrode exhibited high initial discharge capacity but extremely low charge capacity, which illustrates that Cu2SO3•CuSO3•2H2O is not suitable for lithium ion battery electrode negative material.


2015 ◽  
Vol 69 (18) ◽  
pp. 81-85 ◽  
Author(s):  
O. O. Taiwo ◽  
D. S. Eastwood ◽  
P. D. Lee ◽  
J. M. Paz-Garcia ◽  
S. A. Hall ◽  
...  

2018 ◽  
Vol 2018 ◽  
pp. 1-7 ◽  
Author(s):  
Benjamin T. Young ◽  
David R. Heskett ◽  
Joseph C. Woicik ◽  
Brett L. Lucht

The surface sensitivity available to photoelectron spectroscopies (PESs) makes them popular techniques for characterization of chemical environments at shallower depths than other, more bulk-sensitive techniques and because they are generally thought to be nondestructive. Variable energy, synchrotron radiation (SR), permits access to information not available to common lab-based radiation sources, making high-energy PES studies extremely useful for understanding thin films and interfaces. High-SR photon flux has been useful for developing models of soft X-ray-induced effects, but hard X-ray SR-induced effects are less well studied and will be increasingly important as popularity and availability of SR for thin film analysis continues to grow. We report here on observed modification of the solid electrolyte interphase of a lithium-ion battery electrode during prolonged exposure to 4 keV SR. The effects can be summarized by desorption of oxygen-containing species from the sample surface and by reactions within the film. Also presented is an estimate of the layer thickness’ time evolution during the prolonged SR exposure.


2018 ◽  
Author(s):  
Shuichiro Hirai ◽  
H. Naito ◽  
T. Yoshida ◽  
Takashi Sasabe ◽  
K. Kawamura ◽  
...  

2012 ◽  
Vol 736 ◽  
pp. 127-132
Author(s):  
Kuldeep Rana ◽  
Anjan Sil ◽  
Subrata Ray

Lithium alloying compounds as an anode materials have been a focused for high capacity lithium ion battery due to their highenergy capacity and safety characteristics. Here we report on the preparation of graphite-tin composite by using ball-milling in liquid media. The composite material has been characterized by scanning electron microscope, energy depressive X-ray spectroscopy, X-ray diffraction and Raman spectra. The lithium-ion cell made from graphite-tin composite presented initial discharge capacity of 1065 mAh/g and charge capacity 538 mAh/g, which becomes 528 mAh/g in the second cycle. The composite of graphite-tin with higher capacity compared to pristine graphite is a promising alternative anode material for lithium-ion battery.


2002 ◽  
Vol 5 (1) ◽  
pp. A22 ◽  
Author(s):  
M. Balasubramanian ◽  
H. S. Lee ◽  
X. Sun ◽  
X. Q. Yang ◽  
A. R. Moodenbaugh ◽  
...  

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