scholarly journals Electrochemical Fluorination of Vinyl Boronates through Donor‐Stabilized Vinyl Carbocation Intermediates

2022 ◽  
Author(s):  
Hosea M. Nelson ◽  
Benjamin Wigman ◽  
Woojin Lee ◽  
Wenjing Wei ◽  
K. N. Houk
2021 ◽  
Author(s):  
Benjamin Wigman ◽  
Woojin Lee ◽  
Wenjing Wei ◽  
Ken Houk ◽  
Hosea Nelson

2021 ◽  
Author(s):  
Bethan Winterson ◽  
Tim Rennigholtz ◽  
Thomas Wirth

The heightened activity of compounds containing fluorine, especially in the field of pharmaceuticals, provides major impetus for the development of new fluorination procedures. A scalable, versatile, and safe electrochemical fluorination...


1976 ◽  
Vol 6 (1) ◽  
pp. 23-32 ◽  
Author(s):  
F. G. Drakesmith ◽  
D. A. Hughes

2015 ◽  
Vol 11 ◽  
pp. 85-91 ◽  
Author(s):  
Bin Yin ◽  
Shinsuke Inagi ◽  
Toshio Fuchigami

Anodic fluorination of dithioacetals bearing electron-withdrawing ester, acetyl, amide, and nitrile groups at their α-positions was comparatively studied using various supporting poly(HF) salts like Et3N·nHF (n = 3–5) and Et4NF·nHF (n = 3–5). In the former two cases, the corresponding α-fluorination products or fluorodesulfurization products were obtained selectively depending on supporting poly(HF) salts used. In sharp contrast, in the latter two cases, fluorination product selectivity was strongly affected by the electron-withdrawing ability of α-substituents: A dithioacetal bearing a relatively weak electron-withdrawing amide group provided a fluorodesulfurization product selectively while a dithioacetal having a strongly electron-withdrawing nitrile group gave the α-fluorination product predominantly regardless of the poly(HF) salts used.


Author(s):  
I. N. Rozhkov ◽  
A. V. Bukhtiarov ◽  
I. L. Knunyants

2018 ◽  
Vol 6 (1) ◽  
pp. 97-100 ◽  
Author(s):  
Kazuhiro Miyamoto ◽  
Hiroki Nishiyama ◽  
Ikuyoshi Tomita ◽  
Shinsuke Inagi

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