Using the Secondary PH/BH Functional Groups of an Active Geminal Frustrated Lewis Pair for Carbon Monoxide Reduction and Reactions with Nitriles and Isonitriles

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Jun Li ◽  
Christian Mück‐Lichtenfeld ◽  
Constantin G. Daniliuc ◽  
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Christian Mück‐Lichtenfeld ◽  
Constantin G. Daniliuc ◽  
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Gerhard Erker

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Utilizing an intramolecular frustrated Lewis pair (FLP) decorated with a strongly donating guanidino moiety enabled the formation of a thermally remarkably stable FLP-CO adduct, which at 120°C underwent CO migration...


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pp. 719-725 ◽  
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T. R. Mankhand ◽  
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ACS Catalysis ◽  
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