Mechanistic study of the aqueous reaction of organic peroxides with HSO3‐ on the surface of a water droplet

2021 ◽  
Author(s):  
Joseph S. Francisco ◽  
Hao Li ◽  
Xiao Wang ◽  
Jie Zhong ◽  
Biwu Chu ◽  
...  
Keyword(s):  
Water Droplet ◽  
Mechanistic Study ◽  
Organic Peroxides

Mechanistic study of the aqueous reaction of organic peroxides with HSO3‐ on the surface of a water droplet

2021 ◽  
Author(s):  
Joseph S. Francisco ◽  
Hao Li ◽  
Xiao Wang ◽  
Jie Zhong ◽  
Biwu Chu ◽  
...  
Keyword(s):  
Water Droplet ◽  
Mechanistic Study ◽  
Organic Peroxides

Mechanistic Study of Water Droplet Coalescence and Flocculation in Diluted Bitumen Emulsions with Additives Using Microfluidics

2017 ◽  
Vol 31 (10) ◽  
pp. 10555-10565 ◽  
Author(s):  
Arash Nowbahar ◽  
Kathryn A. Whitaker ◽  
Adam K. Schmitt ◽  
Tzu-Chi Kuo
Keyword(s):  
Water Droplet ◽  
Mechanistic Study ◽  
Droplet Coalescence ◽  
Bitumen Emulsions

Mechanistic study on the cardioprotective and chemosensitizing effects of a novel danshensu derivative

Planta Medica ◽  
2014 ◽  
Vol 80 (16) ◽  
Author(s):  
L Wang ◽  
L Shan ◽  
G Cui ◽  
Y Chen ◽  
J li ◽  
...  
Keyword(s):  
Mechanistic Study

EVAPORATION OF SINGLE WATER DROPLET UNDER LASER IRRADIATION

2018 ◽  
Author(s):  
Pei Zhang ◽  
Chuang Sun ◽  
Fengxian Sun ◽  
Zicheng Jin
Keyword(s):  
Laser Irradiation ◽  
Water Droplet

Mechanistic Study and Development of Catalytic Reactions of Sm(II)

2018 ◽  
Author(s):  
Sandepan Maity ◽  
Robert Flowers
Keyword(s):  
Molecular Weight ◽  
High Molecular Weight ◽  
Proton Donor ◽  
Catalytic Reactions ◽  
Mechanistic Study ◽  
Mechanistic Studies ◽  
Cyclization Reactions ◽  
Mechanistic Approach ◽  
Donor Source

Despite the broad utility and application of SmI<sub>2</sub>in synthesis, the reagent is used in stoichiometric amounts and has a high molecular weight, resulting in a large amount of material being used for reactions requiring one or more equivalents of electrons. We report mechanistic studies on catalytic reactions of Sm(II) employing a terminal magnesium reductant and trimethyl silyl chloride in concert with a non-coordinating proton donor source. Reactions using this approach permitted reductions with as little as 1 mol% Sm. The mechanistic approach enabled catalysis employing HMPA as a ligand, facilitating the development of catalytic Sm(II) 5-<i>exo</i>-<i>trig </i>ketyl olefin cyclization reactions.

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