Phase behavior on the binary and ternary mixtures of poly(isooctyl acrylate) + supercritical fluid solvents + isooctyl acrylate and CO2 + isooctyl acrylate system

2007 ◽  
Vol 107 (2) ◽  
pp. 1124-1132 ◽  
Author(s):  
Hun-Soo Byun ◽  
Young-Jin Park ◽  
Jong-Sung Lim
Keyword(s):  
Phase Behavior ◽  
Supercritical Fluid ◽  
Ternary Mixtures ◽  
Binary And Ternary Mixtures ◽  
Supercritical Fluid Solvents

Phase Behavior of Polymers in Supercritical Fluid Solvents

1999 ◽  
Vol 99 (2) ◽  
pp. 565-602 ◽  
Author(s):  
Christopher F. Kirby ◽  
Mark A. McHugh
Keyword(s):  
Phase Behavior ◽  
Supercritical Fluid ◽  
Supercritical Fluid Solvents

ChemInform Abstract: Phase Behavior of Polymers in Supercritical Fluid Solvents

ChemInform ◽  
2010 ◽  
Vol 30 (18) ◽  
pp. no-no
Author(s):  
Christopher F. Kirby ◽  
Mark A. McHugh
Keyword(s):  
Phase Behavior ◽  
Supercritical Fluid ◽  
Supercritical Fluid Solvents

scholarly journals Phase Behavior of Selected Condensed Double-Decker Shaped Silsesquioxane Compounds

2021 ◽  
Author(s):  
David F. Vogelsang ◽  
Robert E. Maleczka ◽  
Andre Lee
Keyword(s):  
Thermal Properties ◽  
Phase Behavior ◽  
Melting Temperature ◽  
Ternary Eutectic ◽  
Thermal Characteristics ◽  
Ternary Mixtures ◽  
Double Decker ◽  
Binary And Ternary Mixtures

Abstract Bisfunctional dichlorosilanes were reacted with tetrasilanol of double-decker shaped octaphenylsilsesquioxane (DDSQ) to form fully condensed DDSQ compounds. The crystallographic and thermal characteristics of these compounds were examined. For compounds capped with dichlorosilanes bearing linear aliphatic moieties, as the number of carbon increases from methyl to n-butyl (from 1 to 4) the melting temperature, Tm, dropped from 546 K to 416 K. While for compounds capped with cycloaliphatic, as the moiety changes from cyclopentyl to cyclohexyl, the value of Tm increases from 533 K to 555 K. Surprising, the highest Tm observed was that when capping was done using diisopropyl dichlorosilane. A Tm of around 565 K was observed, which was even higher as compare to diphenyl dichlorosilane capped DDSQ, which had Tm of about 526 K. Phase behavior of binary and ternary mixtures of these condensed DDSQ was also investigated. To our surprise, mixtures of these compounds form eutectic. The eutectic points were calculated based on ideal binary and ternary eutectic from the thermal properties of pure components. Depending on the crystallography, experimental observations of eutectic match well with calculated values.

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