BrettPhos Ligand Supported Palladium-Catalyzed CO Bond Formation through an Electronic Pathway of Reductive Elimination: Fluoroalkoxylation of Activated Aryl Halides

T. M. Rangarajan; Rajendra Singh; Raju Brahma; Kavita Devi; Rishi Pal Singh; R. P. Singh; Ashok K. Prasad

doi:10.1002/chem.201404121

BrettPhos Ligand Supported Palladium-Catalyzed CO Bond Formation through an Electronic Pathway of Reductive Elimination: Fluoroalkoxylation of Activated Aryl Halides

Chemistry - A European Journal ◽

10.1002/chem.201404121 ◽

2014 ◽

Vol 20 (44) ◽

pp. 14218-14225 ◽

Cited By ~ 38

Author(s):

T. M. Rangarajan ◽

Rajendra Singh ◽

Raju Brahma ◽

Kavita Devi ◽

Rishi Pal Singh ◽

...

Keyword(s):

Bond Formation ◽

Reductive Elimination ◽

Aryl Halides ◽

Palladium Catalyzed ◽

Supported Palladium

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ChemInform Abstract: BrettPhos Ligand Supported Palladium-Catalyzed C-O Bond Formation Through an Electronic Pathway of Reductive Elimination: Fluoroalkoxylation of Activated Aryl Halides.

ChemInform ◽

10.1002/chin.201515097 ◽

2015 ◽

Vol 46 (15) ◽

pp. no-no

Author(s):

T. M. Rangarajan ◽

Rajendra Singh ◽

Raju Brahma ◽

Kavita Devi ◽

Rishi Pal Singh ◽

...

Keyword(s):

Bond Formation ◽

Reductive Elimination ◽

Aryl Halides ◽

Palladium Catalyzed ◽

Supported Palladium

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Carbon-Carbon Bond Formation via Palladium-Catalyzed Reductive Coupling of Aryl Halides in Air and Water

Advanced Synthesis & Catalysis ◽

10.1002/1615-4169(200206)344:3/4<399::aid-adsc399>3.0.co;2-x ◽

2002 ◽

Vol 344 (3-4) ◽

pp. 399-405 ◽

Cited By ~ 33

Author(s):

Sripathy Venkatraman ◽

Taisheng Huang ◽

Chao-Jun Li

Keyword(s):

Bond Formation ◽

Aryl Halides ◽

Reductive Coupling ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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ChemInform Abstract: Palladium-Catalyzed C-N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes.

ChemInform ◽

10.1002/chin.199825077 ◽

2010 ◽

Vol 29 (25) ◽

pp. no-no

Author(s):

G. MANN ◽

J. F. HARTWIG ◽

M. S. DRIVER ◽

C. FERNANDEZ-RIVAS

Keyword(s):

Bond Formation ◽

Reductive Elimination ◽

Palladium Catalyzed

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ChemInform Abstract: Reusable, Polymer-Supported, Palladium-Catalyzed, Atom-Efficient Coupling Reaction of Aryl Halides with Sodium Tetraphenylborate in Water by Focused Microwave Irradiation.

ChemInform ◽

10.1002/chin.200822101 ◽

2008 ◽

Vol 39 (22) ◽

Author(s):

Lin Bai ◽

Jin-Xian Wang

Keyword(s):

Microwave Irradiation ◽

Coupling Reaction ◽

Aryl Halides ◽

Sodium Tetraphenylborate ◽

Palladium Catalyzed ◽

Efficient Coupling ◽

Supported Palladium ◽

Polymer Supported

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ChemInform Abstract: Carbon-Carbon Bond Formation via Palladium-Catalyzed Reductive Coupling of Aryl Halides in Air and Water.

ChemInform ◽

10.1002/chin.200243108 ◽

2010 ◽

Vol 33 (43) ◽

pp. no-no

Author(s):

Sripathy Venkatraman ◽

Taisheng Huang ◽

Chao-Jun Li

Keyword(s):

Bond Formation ◽

Aryl Halides ◽

Reductive Coupling ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Palladium Catalyzed

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First reusable ligand-free palladium catalyzed C–P bond formation of aryl halides with trialkylphosphites in neat water

RSC Advances ◽

10.1039/c4ra07680j ◽

2014 ◽

Vol 4 (99) ◽

pp. 55732-55737 ◽

Cited By ~ 17

Author(s):

Nasser Iranpoor ◽

Habib Firouzabadi ◽

Khashayar Rajabi Moghadam ◽

Somayeh Motavalli

Keyword(s):

Bond Formation ◽

Aryl Halides ◽

Neat Water ◽

Ligand Free ◽

Palladium Catalyzed

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Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers

Journal of the American Chemical Society ◽

10.1021/ja984321a ◽

1999 ◽

Vol 121 (13) ◽

pp. 3224-3225 ◽

Cited By ~ 318

Author(s):

Grace Mann ◽

Christopher Incarvito ◽

Arnold L. Rheingold ◽

John F. Hartwig

Keyword(s):

Reductive Elimination ◽

Aryl Halides ◽

Diaryl Ethers ◽

Palladium Catalyzed ◽

Sterically Induced

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ChemInform Abstract: Palladium-Catalyzed C-O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination to Form the C-O Bond in Diaryl Ethers.

ChemInform ◽

10.1002/chin.199929098 ◽

2010 ◽

Vol 30 (29) ◽

pp. no-no

Author(s):

Grace Mann ◽

Christopher Incarvito ◽

Arnold L. Rheingold ◽

John F. Hartwig

Keyword(s):

Reductive Elimination ◽

Aryl Halides ◽

Diaryl Ethers ◽

Palladium Catalyzed ◽

Sterically Induced

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Aqueous Flow Hydroxycarbonylation of Aryl Halides Catalyzed by an Amphiphilic Polymer-Supported Palladium–Diphenylphosphine Catalyst

Synlett ◽

10.1055/s-0037-1611769 ◽

2019 ◽

Vol 30 (08) ◽

pp. 961-966

Author(s):

Takao Osako ◽

Reinhard Kaiser ◽

Kaoru Torii ◽

Yasuhiro Uozumi

Keyword(s):

Flow Reactor ◽

Reaction System ◽

Aryl Halides ◽

Benzoic Acids ◽

Poly Ethylene Glycol ◽

Palladium Catalyzed ◽

Solution Proceeds ◽

Aqueous Flow ◽

Supported Palladium ◽

Poly Ethylene

An aqueous continuous-flow reaction system is developed for the palladium-catalyzed hydroxycarbonylation of aryl halides. Flow hydroxycarbonylation of aryl halides in aqueous solution proceeds efficiently in a flow reactor containing a palladium–diphenylphosphine complex immobilized on an amphiphilic polystyrene–poly(ethylene glycol) resin to give the corresponding benzoic acids in excellent yields.

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