scholarly journals Cover Feature: Crystal Structures and Melting Behaviors of 2D and 3D Anionic Coordination Polymers Containing Organometallic Ionic Liquid Components (Chem. Eur. J. 43/2019)

2019 ◽  
Vol 25 (43) ◽  
pp. 10023-10023
Author(s):  
Hironori Kimata ◽  
Tomoyuki Mochida
Keyword(s):  
Ionic Liquid ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
2D And 3D

2D and 3D Silver(I)-Ethylenediamine Coordination Polymers with Ag–Ag Argentophilic Interactions

2007 ◽  
Vol 62 (9) ◽  
pp. 1112-1116 ◽  
Author(s):  
Ji-Xiang Dai ◽  
Hai-Liang Zhu ◽  
Alexander Rothenberger ◽  
Qian-Feng Zhang
Keyword(s):  
Coordination Polymer ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Polymer Networks ◽  
2D And 3D ◽  
Argentophilic Interactions ◽  
Silver Atoms

Two complexes of silver(I) salts with ethylenediamine (etda) as a ligand were prepared and characterized. The study of the crystal structures (of the 2-hydroxy-4-nitro-benzoate trihydrate (1) and nitrate (2)) has shown that the formation of 2D and 3D coordination polymer networks results from etda ligands bridging the silver atoms which are connected via Ag-Ag argentophilic interactions.

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