ChemInform Abstract: A Metal-Centered Radical-Pair Mechanism for Alkyne Hydrogenation with a Binuclear Rhodium Hydride Complex. CIDNP without Organic Radicals.

1986 ◽  
Vol 17 (52) ◽  
Author(s):  
S. I. HOMMELTOFT ◽  
D. H. BERRY ◽  
R. EISENBERG
Keyword(s):  
Radical Pair ◽  
Organic Radicals ◽  
Radical Pair Mechanism ◽  
Hydride Complex ◽  
Alkyne Hydrogenation

Application of the radical pair mechanism to free radicals in organized systems: Can the effects of 60 Hz be predicted from studies under static fields?

1994 ◽  
Vol 15 (6) ◽  
pp. 549-554 ◽  
Author(s):  
J. C. Scaiano ◽  
N. Mohtat ◽  
F. L. Cozens ◽  
J. McLean ◽  
A. Thansandote
Keyword(s):  
Free Radicals ◽  
Radical Pair ◽  
Radical Pair Mechanism

scholarly journals Could radical pairs play a role in xenon-induced general anesthesia?

2020 ◽  
Author(s):  
Jordan Smith ◽  
Hadi Zadeh Haghighi ◽  
Christoph Simon
Keyword(s):  
General Anesthesia ◽  
Radical Pair ◽  
The Body ◽  
Radical Pair Mechanism ◽  
General Anesthetic ◽  
Radical Pairs ◽  
Naturally Occurring ◽  
Isotopic Dependence ◽  
Anesthetic Potency ◽  
Recombination Dynamics

ABSTRACTUnderstanding the mechanisms underlying anesthesia would be a key step towards understanding consciousness. The process of xenon-induced general anesthesia has been shown to involve electron transfer, and the potency of xenon as a general anesthetic exhibits isotopic dependence. We propose that these observations can be explained by a mechanism in which the xenon nuclear spin influences the recombination dynamics of a naturally occurring radical pair of electrons. We develop a simple model inspired by the body of work on the radical-pair mechanism in cryptochrome in the context of avian magnetoreception, and we show that our model can reproduce the observed isotopic dependence of the general anesthetic potency of xenon in mice. Our results are consistent with the idea that radical pairs of electrons with entangled spins could be important for consciousness.

scholarly journals Environment-induced anisotropy and sensitivity of the radical pair mechanism in the avian compass

2015 ◽  
Vol 92 (1) ◽  
Author(s):  
Alejandro Carrillo ◽  
Marcio F. Cornelio ◽  
Marcos C. de Oliveira
Keyword(s):  
Radical Pair ◽  
Radical Pair Mechanism ◽  
Induced Anisotropy

Resonance effects indicate a radical-pair mechanism for avian magnetic compass

Nature ◽  
2004 ◽  
Vol 429 (6988) ◽  
pp. 177-180 ◽  
Author(s):  
Thorsten Ritz ◽  
Peter Thalau ◽  
John B. Phillips ◽  
Roswitha Wiltschko ◽  
Wolfgang Wiltschko
Keyword(s):  
Radical Pair ◽  
Magnetic Compass ◽  
Radical Pair Mechanism ◽  
Resonance Effects
Sign in / Sign up

Export Citation Format

Share Document