ChemInform Abstract: Nucleophilic Addition of Lithiated Phenyl Trimethylsilylmethyl Sulfide to Activated Olefins. A Facile Synthesis of 2-(Functionally) Substituted Silylcyclopropanes.

ChemInform ◽  
1987 ◽  
Vol 18 (19) ◽  
Author(s):  
E. SCHAUMANN ◽  
C. FRIESE ◽  
C. SPANKA
2010 ◽  
Vol 12 (23) ◽  
pp. 5494-5497 ◽  
Author(s):  
Santos Fustero ◽  
Javier Moscardó ◽  
María Sánchez-Roselló ◽  
Elsa Rodríguez ◽  
Pablo Barrio

Synthesis ◽  
2008 ◽  
Vol 2008 (20) ◽  
pp. 3319-3325
Author(s):  
Margaret Brimble ◽  
Daryl Crimmins ◽  
Ivaylo Dimitrov ◽  
Patrick O’Connor ◽  
Vittorio Caprio

Synthesis ◽  
2022 ◽  
Author(s):  
Jun Dong ◽  
Youwei Chen ◽  
Xingcai Huang

A series of quinoxaline-2-thiol and quinoxaline were prepared in moderate to good yields from various phenacyl sulfoxides bearing 1-methyl-1H-tetrazole and o-aryl diamines. The proposed reaction mechanism involves generation of sulfines from the phenacyl sulfoxides bearing 1-methyl-1H-tetrazole through thermolysis elimination. Then, site-selectively carbophilic addition of sulfines by o-aryl diamines, followed by elimination, intramolecular nucleophilic addition and dehydration condensation. The current method provides a direct and simple strategy for the preparation of quinoxaline-2-thiols and quinoxalines.


RSC Advances ◽  
2015 ◽  
Vol 5 (36) ◽  
pp. 28270-28280 ◽  
Author(s):  
Poonam Rani ◽  
Rajendra Srivastava

Zr based MOF exhibited excellent activity in the ring opening of epoxides/nucleophilic addition of activated olefins with wide range of nucleophiles.


ChemInform ◽  
2009 ◽  
Vol 40 (9) ◽  
Author(s):  
Daryl Crimmins ◽  
Ivaylo Dimitrov ◽  
Patrick D. O'Connor ◽  
Vittorio Caprio ◽  
Margaret A. Brimble

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