Catalytic effect of dimethyl sulfoxide in the Cu(0)/tris(2-dimethylaminoethyl)amine-catalyzed living radical polymerization of methyl methacrylate at 0-90 �C initiated with CH3CHClI as a model compound for ?,?-di(iodo)poly(vinyl chloride) chain ends

2005 ◽  
Vol 43 (9) ◽  
pp. 1935-1947 ◽  
Author(s):  
Virgil Percec ◽  
Tamaz Guliashvili ◽  
Anatoliy V. Popov ◽  
Ernesto Ramirez-Castillo
Keyword(s):  
Methyl Methacrylate ◽  
Dimethyl Sulfoxide ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Model Compound ◽  
Catalytic Effect ◽  
Living Radical Polymerization ◽  
Poly Vinyl Chloride

Scale-up of Poly[(Vinyl Chloride)-b-(n-Butyl Acrylate)-b-(Vinyl Chloride)] prepared by Living Radical Polymerization

2006 ◽  
Vol 514-516 ◽  
pp. 975-979 ◽  
Author(s):  
Jorge F.J. Coelho ◽  
Patricia Alves ◽  
Joana Monteiro ◽  
M. Margarida C.A. Castro ◽  
Mariana Abreu ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Glass Transition ◽  
Transition Temperature ◽  
Glass Transition Temperature ◽  
Radical Polymerization ◽  
Vinyl Chloride ◽  
Scale Up ◽  
Living Radical Polymerization ◽  
Poly Vinyl Chloride

Vinyl Chloride (VCM) based copolymers were synthesised by using Living Radical Polymerization. The obtained materials were characterized by determining their molecular weight, glass transition temperature and mechanical properties after processing in industrial equipments. Their chemical composition was evaluated by using NMR.

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