New structural phase sequence with incommensurate phases in A2BX4 halides with β-K2SO4 structure

2006 ◽  
Vol 61 (1) ◽  
pp. 87-94 ◽  
Author(s):  
S. Plesko ◽  
R. Kind ◽  
H. Arend
1998 ◽  
Vol 205 (1) ◽  
pp. 119-132
Author(s):  
I. R. Jahn ◽  
H. Ritter ◽  
K. Schwab ◽  
K. Knorr

1986 ◽  
Vol 47 (C3) ◽  
pp. C3-437-C3-446 ◽  
Author(s):  
J. W. STEEDS ◽  
R. AYER ◽  
Y. P. LIN ◽  
R. VINCENT

2001 ◽  
Vol 23 (2) ◽  
pp. 119-139
Author(s):  
R. A. GREGORY ◽  
D. W. HALL ◽  
D. W. SHIMWELL

Excavation at a crop-mark site found close to Annan, Dumfries and Galloway, revealed evidence of a ring-ditch containing a number of intriguing internal structures. Initially this was presumed to be a prehistoric monument, but pottery and radiocarbon dating, unexpectedly, indicated that the main structural phase of the site falls between the 11th-13th centuries AD. This suggests that a degree of caution is required when interpreting crop-mark sites on morphological characteristics alone. Moreover this excavation makes clear that morphological interpretation can have a constraining influence on excavation strategy, so caution is required when designing fieldwork programmes.


2020 ◽  
Author(s):  
Marvin Kraft ◽  
Lara Gronych ◽  
Theodosios Famprikis ◽  
Saneyuki Ohno ◽  
Wolfgang Zeier

<p>Sulfidic sodium ion conductors are currently investigated for the possible use in all-solid-state sodium ion batteries. The design of high performing electrolytes in terms of temperature-dependent ionic transport is based upon the fundamental understanding of structure – transport relationships within the given structural phase boundaries inherent to the investigated materials class. In this work, the Na<sup>+</sup> superionic structural family of Na<sub>11</sub>Sn<sub>2</sub>PS<sub>12</sub> is explored by using the systematic antimony substitution with phosphorous in Na<sub>11+<i>x</i></sub>Sn<sub>2+<i>x</i></sub>(Sb<sub>1-<i>y</i></sub>P<i><sub>y</sub></i>)<sub>1-<i>x</i></sub>S<sub>12</sub>. A combination of Rietveld refinements against X-ray synchrotron diffraction data with electrochemical impedance spectroscopy is used to monitor the changes in the anionic framework, the Na<sup>+</sup> substructure and the ionic transport. A new simplified descriptor for the average Na<sup>+</sup> diffusion pathways, the average Na<sup>+</sup> polyhedral volume is introduced, which is used to correlate the contraction of the overall lattice and the found activation barriers in the system. This study exemplifies how substitution affects diffusion pathways in ionic conductors and widens the knowledge about the related structural motifs and their influence on the ionic transport in this novel class of ionic conductors.</p>


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