Probing the Intermolecular Interactions in Binary Liquid Mixtures of 1-Tert-butoxy-2-propanol with Amines Through Volumetric, Ultrasonic and FT-IR Spectroscopic Studies at Different Temperatures

2022 ◽  
Vol 43 (3) ◽  
Author(s):  
Gyan Prakash Dubey ◽  
Likhish Dhingra
Author(s):  
Ch. Praveen Babu ◽  
G. Pavan Kumar ◽  
B. Nagarjun ◽  
K. Samatha

Theoretical velocities of binary liquid mixtures of 1-bromopropane with chlorobenzene at 2 MHz and four different temperatures 303.15, 308.15, 313.15 and 318.15 K, have been evaluated as a function of concentration and temperature. The experimental values are compared with theoretical models of liquid mixtures such as Nomoto, Van Dael-Vangeel, Impedance Relation, Rao’s Specific Velocity Method, Junjie’s relations and Free Length Theory. In the chosen system there is a good agreement between experimental and theoretical values calculated by Nomoto’s theory. The deviation in the variation of U2exp/U2imx from unity has also been evaluated for explaining the non ideality in the mixtures. The results are explained in terms of intermolecular interactions occurring in these binary liquid mixtures.


2020 ◽  
Vol 27 ◽  
pp. 1324-1330
Author(s):  
S.K. Fakruddin Babavali ◽  
Timmeswara Sarma Nori ◽  
P. Naresh ◽  
Ch. Srinivasu ◽  
P. Srinivasa Sastry

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