Coordination polymers based on zinc(ii) and manganese(ii) with 1,4-cyclohexanedicarboxylic acid

2018 ◽  
Vol 67 (3) ◽  
pp. 490-496 ◽  
Author(s):  
P. A. Demakov ◽  
S. A. Sapchenko ◽  
D. G. Samsonenko ◽  
D. N. Dybtsev ◽  
V. P. Fedin
Keyword(s):  
Coordination Polymers ◽  
Cyclohexanedicarboxylic Acid

Exploration of semiconducting properties of Zn(II) and Cd(II) based coordination polymers with dicarboxylate of chair-type backbone

CrystEngComm ◽  
2021 ◽  
Author(s):  
Akhtaruz Zaman ◽  
Baishakhi Pal ◽  
Samim Khan ◽  
Basudeb Dutta ◽  
Sanobar Naaz ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Room Temperature ◽  
Mixed Ligand ◽  
Two Dimensional ◽  
Slow Diffusion ◽  
Ligand System ◽  
Diffusion Technique ◽  
Semiconducting Properties ◽  
Cyclohexanedicarboxylic Acid

A new Cd(II)-based two-dimensional coordination polymer (2D CP) [{Cd2(cis-1,4-chdc)2(1,10-phen)2}۰5H2O]n (1) has been synthesized at room temperature by slow diffusion technique using 1,4-cyclohexanedicarboxylic acid (1,4-H2chdc) and 1,10-phenanthroline (1,10-phen) mixed-ligand system. The...

Structural Study of a new Compound Based on Acid 1,4-Cyclohexanedicarboxylic (1,4-CDC)

2010 ◽  
Vol 6 (1) ◽  
pp. 891-896
Author(s):  
Manel Halouani ◽  
M. Dammak ◽  
N. Audebrand ◽  
L. Ktari
Keyword(s):  
Aqueous Solution ◽  
Water Molecules ◽  
Carboxyl Group ◽  
X Ray Diffraction ◽  
Compound I ◽  
Unit Cell Parameters ◽  
Monoclinic System ◽  
X Ray ◽  
Cell Parameters ◽  
Cyclohexanedicarboxylic Acid

One nickel 1,4-cyclohexanedicarboxylate coordination polymers, Ni2 [(O10C6H4)(COO)2].2H2O  (I), was hydrothermally synthesized from an aqueous solution of Ni (NO3)2.6H2O, (1,4-CDC) (1,4-CDC = 1,4-cyclohexanedicarboxylic acid) and tetramethylammonium nitrate. Compound (I) crystallizes in the monoclinic system with the C2/m space group. The unit cell parameters are a = 20.1160 (16) Å, b = 9.9387 (10) Å, c = 6.3672 (6) Å, β = 97.007 (3) (°), V= 1263.5 (2) (Å3) and Dx= 1.751g/cm3. The refinement converged into R= 0.036 and RW = 0.092. The structure, determined by single crystal X-ray diffraction, consists of two nickel atoms Ni (1) and Ni (2). Lots of ways of which is surrounded by six oxygen atoms, a carboxyl group and two water molecules.

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