Second-Order Magnetic Transition and Low Field Magnetocaloric Effect in Nanocrystalline $$\hbox {Pr}_ {5}\hbox {Co}_{19}$$ Pr 5 Co 19 Compound

2018 ◽  
Vol 47 (5) ◽  
pp. 2776-2781 ◽  
Author(s):  
W. Bouzidi ◽  
N. Mliki ◽  
L. Bessais
2016 ◽  
Vol 28 (17) ◽  
pp. 3321-3325 ◽  
Author(s):  
Sanjay Singh ◽  
Luana Caron ◽  
Sunil Wilfred D'Souza ◽  
Tina Fichtner ◽  
Giacomo Porcari ◽  
...  

2018 ◽  
Vol 32 (26) ◽  
pp. 1850290
Author(s):  
S. Qaseem ◽  
M. Naeem ◽  
S. Rizwan Ali

We study ferromagnetic to paramagnetic transition using Banerjee criterion in colossal magnetoresistive La[Formula: see text]Ca[Formula: see text]MnO3 nanoparticles of different sizes (20, 26 and 32 nm). These particles are chemically prepared by a modified citrate route. Particle sizes are estimated by X-ray diffraction (XRD). Sample morphology and size distribution are examined by a transmission electron microscope. Order of transition is determined by measuring magnetic field dependence of magnetization near Curie temperature T[Formula: see text]. Our results reveal second-order magnetic transition in all three different-sized particles in contrast to the first-order transition reported in bulk samples. This is further supported by temperature dependences of zero-field-cooled (ZFC) and field-cooled (FC) magnetizations. FC curves show gradual transition for all three samples without any saturation region as is the case of bulk. T[Formula: see text] is extracted from ZFC curves and is found to be 240 K for 20 nm particles and 258 K for both 26 and 32 nm particles. Magnetocaloric effect as a function of particle size also confirms the second-order magnetic transition in all three samples. The relative cooling power at 20 kOe is found to be decreasing with decreasing particle size.


2020 ◽  
Author(s):  
Jia-Wang Xu ◽  
Xinqi Zheng ◽  
Shu-Xian Yang ◽  
L. Xi ◽  
J. Y. Zhang ◽  
...  

2018 ◽  
Vol 445 ◽  
pp. 71-76 ◽  
Author(s):  
Zhenzhuang Li ◽  
Zongbin Li ◽  
Bo Yang ◽  
Yiqiao Yang ◽  
Yudong Zhang ◽  
...  

Crystals ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 329 ◽  
Author(s):  
Chengfen Xing ◽  
Hu Zhang ◽  
Kewen Long ◽  
Yaning Xiao ◽  
Hanning Zhang ◽  
...  

The effect of different atomic substitutions at Mn sites on the magnetic and magnetocaloric properties in Ni50Mn35Co2Sn13 alloy has been studied in detail. The substitution of Ni or Co for Mn atoms might lower the Mn content at Sn sites, which would reduce the d-d hybridization between Ni 3d eg states and the 3d states of excess Mn atoms at Sn sites, thus leading to the decrease of martensitic transformation temperature TM in Ni51Mn34Co2Sn13 and Ni50Mn34Co3Sn13 alloys. On the other hand, the substitution of Sn for Mn atoms in Ni50Mn34Co2Sn14 would enhance the p-d covalent hybridization between the main group element (Sn) and the transition metal element (Mn or Ni) due to the increase of Sn content, thus also reducing the TM by stabilizing the parent phase. Due to the reduction of TM, a magnetostructural martensitic transition from FM austenite to weak-magnetic martensite is realized in Ni51Mn34Co2Sn13 and Ni50Mn34Co2Sn14, resulting in a large magnetocaloric effect around room temperature. For a low field change of 3 T, the maximum ∆SM reaches as high as 30.9 J/kg K for Ni50Mn34Co2Sn14. A linear dependence of ΔSM upon μ0H has been found in Ni50Mn34Co2Sn14, and the origin of this linear relationship has been discussed by numerical analysis of Maxwell’s relation.


2021 ◽  
Author(s):  
Huicai Xie ◽  
Lu Tian ◽  
Qi Chen ◽  
Hao Sun ◽  
Xinqiang Gao ◽  
...  

Cryogenic refrigeration technology is gradually penetrating into increasing aspects in human life and industrial production. Magnetic refrigeration shows excellent application potential due to its high efficiency, good stability and environmental...


AIP Advances ◽  
2019 ◽  
Vol 9 (3) ◽  
pp. 035206 ◽  
Author(s):  
Shaohui Chen ◽  
Guiquan Yao ◽  
Jinsong Zhang ◽  
Xiaomeng Fan ◽  
Xiaowei Yin ◽  
...  

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