scholarly journals Oxygenated boron-doped carbon via polymer dehalogenation as an electrocatalyst for high-efficiency O2 reduction to H2O2

Author(s):  
Yingna Chang ◽  
Jiawei Li ◽  
Jun Ma ◽  
Yu Liu ◽  
Rong Xing ◽  
...  
1996 ◽  
Vol 452 ◽  
Author(s):  
P. Pemet ◽  
M. Goetz ◽  
H. Keppner ◽  
A. Shah

AbstractThe <p> μc-SiC:H / <i> a-Si:H junction can be considered to be a sub-system of a n/i/p solar cell. Optimised performance of this junction can be assumed to be a key feature for obtaining high efficiency solar cells.In this paper the authors present results on the conductivity of boron doped microcrystalline hydrogenated silicon (<p> μc-Si:H) thin films deposited on amorphous substrates (e.g. glass or glass/<i> a-Si:H). It is shown that, without any treatment of the substrate or of the underlying surface, the <p> layers showed a strongly reduced conductivity. This indicates either a bad nucleation or a poor microcrystalline behaviour. By using an appropriate surface treatment of the substrate, a gain in photoconductivity of about three orders of magnitude could be obtained (σ > 3 S/cm at a layer thickness of 400Å). We conclude from this, that for thin <p> type μc-Si:H layers the nucleation conditions are essential for obtaining best electric properties of the film w.r.t. solar cell performance.Based on these results, interface treatment was successfully implemented in n/i/p solar cells deposited on TCO coated glass and stainless steel. The results of these experiments are also presented.


2012 ◽  
Vol 1395 ◽  
Author(s):  
E. Saito ◽  
A.F. Azevedo ◽  
F.A. Souza ◽  
N.G. Ferreira ◽  
M.R. Baldan

ABSTRACTComparative study of boron doped micro/nanocrystalline diamond (BDD/BDND) electrodes was performed using electrochemical impedance spectroscopy measurements (EIS). The morphological and structural characterizations of BDD/BDND films were analyzed by scanning electron microscopy and Raman scattering spectroscopy. The films were grown with different boron amounts added in the feed gas. The boron source for BDND was smaller in concentration than that for BDD sample. Nonetheless, differential capacitance (Mott-Schottky plots) and heterogeneous charge transfer constant results showed similar doping level for both electrodes. This behavior indicated the high efficiency to dope nanocrystalline diamond films.


2015 ◽  
Vol 54 (8S1) ◽  
pp. 08KD06 ◽  
Author(s):  
Yuka Tomizawa ◽  
Tetsuya Imamura ◽  
Masaya Soeda ◽  
Yoshinori Ikeda ◽  
Takashi Shiro

2011 ◽  
Vol 697-698 ◽  
pp. 458-461 ◽  
Author(s):  
Liang Wang ◽  
X.L. Lei ◽  
Bin Shen ◽  
Fang Hong Sun ◽  
Z.M. Zhang ◽  
...  

In this investigation, conventional microcrystalline diamond (MCD) and boron doped diamond (BDD) films are deposited onto commercially available cemented tungsten carbide (WC-Co) Ball-nose endmills by using hot filament chemical vapour deposition (HFCVD). The quality and properties of the as-deposited diamond film are characterized by field emission scanning electron microscope (FESEM) and Raman spectroscopy. Milling tests of graphite materials using MCD, BDD coated and uncoated tool are carried out. Experiment results reveal that BDD films possess higher adhesive strength to the substrate than that of MCD films, and the BDD coated mills allow to be given smaller flank wear and longer tool life, when compared with MCD coated and uncoated WC-Co tools. Cutting performances of WC-Co mills in graphite milling are greatly improved by BDD coating, and typically more than 10 times the tool life is obtained. The research results are of great significance for high efficiency and quality machining of graphite materials.


Author(s):  
Wenhua Li ◽  
Shule Zhang ◽  
Qianqiao Chen ◽  
Qin Zhong

1. Tunable BCNTs are prepared by the pre-oxidation strategy. 2. B-Doped CNTs exhibit excellent activity for Sn2− reduction. 3. The QDSSC based on CdS/CdSe QDs and BCNT1 shows a PCE of 4.55% under one sunlight illumination.


Energies ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 346 ◽  
Author(s):  
K. Pérez-Salcedo ◽  
Xuan Shi ◽  
Arunachala Kannan ◽  
Romeli Barbosa ◽  
Patricia Quintana ◽  
...  

This work reports the synthesis of N-doped porous carbon (NPC) with a high surface area from Sargassum spp. as a low-cost alternative for electrocatalyst production for the oxygen reduction reaction (ORR). Sargassum spp. was activated with potassium hydroxide at different temperatures (700, 750, and 800 °C) and then doped with pyridine (N700, N750, and N800). As a result of the activation process, the 800 °C sample showed a high surface area (2765 m2 g−1) and good onset potential (0.870 V) and current density (4.87 mA cm−2). The ORR performance of the electrocatalysts in terms of their current density was N800 > N750 > N700 > 750 > 800 > 700, while the onset potential decreased in the following order: N800 > 800 > 750 > 700 > N700 > N750. The fuel cell performance of the membrane electrode assembly (MEA) prepared with electrocatalyst synthesized at 750 °C and doped with pyridine was 12.72 mW cm−2, which was close to that from Pt/C MEA on both the anode and cathode (14.42 mW cm−2). These results indicate that NPCs are an alternative to the problem of Sargassum spp. accumulation in the Caribbean due to their high efficiency as electrocatalysts for ORR.


2019 ◽  
Author(s):  
Maxim Hayes ◽  
Benoit Martel ◽  
Sébastien Dubois ◽  
Audrey Morisset ◽  
Olivier Palais

Author(s):  
Hassen Trabelsi ◽  
Nasr Bensalah ◽  
Abdellatif Gadri

AbstractThe electrochemical oxidation of 1,4 dihydroxybenzene, was studied by galvanostatic electrolysis using boron-doped diamond (BDD) as anode. The efficiency of the electrochemical process was found to depend mainly on the pollutant concentration present in the waste and on the applied current density. The voltammetric results showed that hydroquinone oxidation takes place in the same potential region as that of phenol where the supporting electrolyte is stable. Synthetic wastewaters containing hydroquinone have been treated in a bench-scale electrolysis plant. This plant operates in a discontinuous mode by recirculating the waste continuously through a single-chamber electrochemical flow cell. The complete mineralization of hydroquinone and the electro-generated pollutants is obtained in the electrolytic device. HPLC analyses show the formation of carboxylic acids as the main intermediates. The high efficiency of this technology can be explained in terms of the direct electro-oxidation at the BDD surface and the oxidation carried out by hydroxyl radicals and other electro-generated oxidants.


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