Radiation-induced cationic polymerization of vinyl ethers in solution: 3. The influence of monomer and solvent concentrations on the rate of polymerization of ethyl vinyl ether in ether solvent

Polymer ◽  
1982 ◽  
Vol 23 (3) ◽  
pp. 427-430 ◽  
Author(s):  
W.C. Hsieh ◽  
A. Deffieux ◽  
D.R. Squire ◽  
V. Stannett
Keyword(s):  
Vinyl Ether ◽  
Cationic Polymerization ◽  
Ethyl Vinyl Ether ◽  
Vinyl Ethers ◽  
Ethyl Vinyl ◽  
Rate Of Polymerization ◽  
Radiation Induced

scholarly journals Successive Activation of C–H and C–O Bonds of Vinyl Ethers by a Diphosphine and Hydrido-Bridged Diiridium Complex

Inorganics ◽  
2019 ◽  
Vol 7 (10) ◽  
pp. 121
Author(s):  
Takahashi ◽  
Shimbayashi ◽  
Fujita
Keyword(s):  
Vinyl Ether ◽  
Bond Activation ◽  
Ethyl Vinyl Ether ◽  
Vinyl Ethers ◽  
Ethyl Vinyl

The reaction of [(Cp*Ir)2(μ-dmpm)(μ-H)][OTf] (2) [Cp* = η5-C5Me5, dmpm = bis(dimethylphosphino)methane] with 2,3-dihydrofuran gives [(Cp*IrH)2(μ-dmpm){μ-(2,3-dihydrofuranyl)}][OTf] (3) in an isolated yield of 70% via the C–H bond activation at the 5-position of 2,3-dihydrofuran. Complex 3 is slowly converted into [(Cp*Ir)2(μ-dmpm)(μ-C=C(H)CH2CH2OH)][OTf] (4) quantitatively via the proton-mediated C–O bond activation. The reaction of 2 with ethyl vinyl ether gives [(Cp*Ir)2(μ-dmpm)(μ-CH=CH2)][OTf] (5) in the isolated yield of 64% via the successive activation of C–H and C–O bonds.

Radiation-Induced Polymerization of Ethyl Vinyl Ether in n-Pentane and Neopentane

1978 ◽  
Vol 12 (9) ◽  
pp. 1299-1305 ◽  
Author(s):  
H. Kubota ◽  
V. Ya. Kabanov ◽  
D. R. Squire ◽  
V. Stannett
Keyword(s):  
Vinyl Ether ◽  
Ethyl Vinyl Ether ◽  
Ethyl Vinyl ◽  
Radiation Induced
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