Catalytic conversion of acrolein and acrylic acid drop-ins for added-value chemicals

2022 ◽  
pp. 47-62
Author(s):  
Baithy Mallesham ◽  
P. Suresh Babu ◽  
Hu Li ◽  
Putla Sudarsanam
2020 ◽  
Author(s):  
Alisson Dias da Silva Ruy ◽  
Ana Luíza Freitas Ferreira ◽  
Antônio Ésio Bresciani ◽  
Rita Maria de Brito Alves ◽  
Luiz Antônio Magalhães Pontes

Glycerol from biodiesel is a potential raw material for synthesis of several products with high added value. The world demand and the market value of these products are important information for defining the best investment for the implantation of a biorefinery. The information is available on websites of social associations, production companies and market consulting companies and can be mined, free of charge. The International Trade Center (ITC), with information on world trade and websites linked to the foreign trade agencies of every country, such as Comex Stat, in Brazil, are relevant search sources. In this context, this work presents procedures and search techniques for prospecting such information. Such a procedure is illustrated through a case study for which a search of market parameters for glycerol and its derivatives was carried out for use in the process design and economic evaluation of an industrial plant. It was found that crude glycerol had a market price close to US$ 170/ton, in 2019. Among its derivatives, acrylic acid, acrylonitrile and 1,3-propanediol have great potential for the development of new processes, within the scope of a biorefinery. Industrially, acrylic acid (US$ 1100/ton) and acrylonitrile (US$ 1500/ton) are produced from propene (US$ 880/ ton) and 1,3-propanediol (US $ 2000/ton) comes from glucose (US$ 460/t) or ethylene oxide (US$ 1200/t), which encourages the development of new sustainable processes.


Catalysts ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 370 ◽  
Author(s):  
Yi Xing ◽  
Zhiliang Ma ◽  
Wei Su ◽  
Qunhui Wang ◽  
Xiaona Wang ◽  
...  

The concentration of carbon dioxide in the air has risen sharply due to the use of fossil fuels, causing environmental problems such as the greenhouse effect, which seriously threatens humans’ living environment. Reducing carbon dioxide emissions while addressing energy shortages requires the conversion of CO2 into high added-value products. In this paper, the status of CO2 conversion research in the past ten years is analyzed using the bibliometric method; the influence of countries and institutions, journal article statistics and other aspects are statistically analyzed, and the research status of carbon dioxide catalytic conversion is briefly introduced. Finally, according to the analysis results and the existing problems of CO2 catalytic conversion research, the future development direction of CO2 catalytic conversion research is prospected.


Author(s):  
B. Lencova ◽  
G. Wisselink

Recent progress in computer technology enables the calculation of lens fields and focal properties on commonly available computers such as IBM ATs. If we add to this the use of graphics, we greatly increase the applicability of design programs for electron lenses. Most programs for field computation are based on the finite element method (FEM). They are written in Fortran 77, so that they are easily transferred from PCs to larger machines.The design process has recently been made significantly more user friendly by adding input programs written in Turbo Pascal, which allows a flexible implementation of computer graphics. The input programs have not only menu driven input and modification of numerical data, but also graphics editing of the data. The input programs create files which are subsequently read by the Fortran programs. From the main menu of our magnetic lens design program, further options are chosen by using function keys or numbers. Some options (lens initialization and setting, fine mesh, current densities, etc.) open other menus where computation parameters can be set or numerical data can be entered with the help of a simple line editor. The "draw lens" option enables graphical editing of the mesh - see fig. I. The geometry of the electron lens is specified in terms of coordinates and indices of a coarse quadrilateral mesh. In this mesh, the fine mesh with smoothly changing step size is calculated by an automeshing procedure. The options shown in fig. 1 allow modification of the number of coarse mesh lines, change of coordinates of mesh points or lines, and specification of lens parts. Interactive and graphical modification of the fine mesh can be called from the fine mesh menu. Finally, the lens computation can be called. Our FEM program allows up to 8000 mesh points on an AT computer. Another menu allows the display of computed results stored in output files and graphical display of axial flux density, flux density in magnetic parts, and the flux lines in magnetic lenses - see fig. 2. A series of several lens excitations with user specified or default magnetization curves can be calculated and displayed in one session.


2020 ◽  
Vol 8 (38) ◽  
pp. 13368-13374
Author(s):  
Muhammad Umair Khan ◽  
Gul Hassan ◽  
Jinho Bae

This paper proposes a novel soft ionic liquid (IL) electrically functional device that displays resistive memory characteristics using poly(acrylic acid) partial sodium salt (PAA-Na+:H2O) solution gel and sodium hydroxide (NaOH) in a thin polydimethylsiloxane (PDMS) cylindrical microchannel.


2015 ◽  
Vol 25 (1) ◽  
pp. 50-60
Author(s):  
Anu Subramanian

ASHA's focus on evidence-based practice (EBP) includes the family/stakeholder perspective as an important tenet in clinical decision making. The common factors model for treatment effectiveness postulates that clinician-client alliance positively impacts therapeutic outcomes and may be the most important factor for success. One strategy to improve alliance between a client and clinician is the use of outcome questionnaires. In the current study, eight parents of toddlers who attended therapy sessions at a university clinic responded to a session outcome questionnaire that included both rating scale and descriptive questions. Six graduate students completed a survey that included a question about the utility of the questionnaire. Results indicated that the descriptive questions added value and information compared to using only the rating scale. The students were varied in their responses regarding the effectiveness of the questionnaire to increase their comfort with parents. Information gathered from the questionnaire allowed for specific feedback to graduate students to change behaviors and created opportunities for general discussions regarding effective therapy techniques. In addition, the responses generated conversations between the client and clinician focused on clients' concerns. Involving the stakeholder in identifying both effective and ineffective aspects of therapy has advantages for clinical practice and education.


2011 ◽  
pp. 39-50
Author(s):  
V. Lushin

The author analyzes factors that led to a deeper fall in output and profitability in the real sector of the Russian economy in comparison with other segments during the acute phase of the financial crisis. It is argued that some contradictions in the government anti-recession policy, activities of the financial sector and natural monopolies lead to pumping out added value created in manufacturing and agriculture, increase symptoms of the «Dutch disease», etc. It is shown that it may threaten the balanced development of the Russian economy, and a set of measures is suggested to minimize these tendencies and create a basis for the state modernization policy.


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