Catalytic activity of hierarchical beta zeolites in the Prins cyclization of (−)-isopulegol with acetone

2021 ◽  
pp. 118131
Author(s):  
Mathias Laluc ◽  
Roman Barakov ◽  
Päivi Mäki-Arvela ◽  
Nataliya Shcherban ◽  
Dmitry Yu. Murzin
2018 ◽  
Vol 8 (11) ◽  
pp. 2966-2974 ◽  
Author(s):  
Xuebin Zhao ◽  
Linying Wang ◽  
Peng Guo ◽  
Nana Yan ◽  
Tantan Sun ◽  
...  

High-Si single-crystalline beta zeolites with intracrystal mesopores were synthesized for the first time and investigated as catalysts for the methanol to propene (MTP) reaction.


2020 ◽  
Vol 594 ◽  
pp. 117380 ◽  
Author(s):  
Roman Barakov ◽  
Nataliya Shcherban ◽  
Pavel Yaremov ◽  
Igor Bezverkhyy ◽  
Valentina Tsyrina ◽  
...  

Catalysts ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 25
Author(s):  
Su-Un Lee ◽  
You-Jin Lee ◽  
Soo-Jin Kwon ◽  
Jeong-Rang Kim ◽  
Soon-Yong Jeong

With the growing global propylene demand, propane dehydrogenation (PDH) has attracted great attention for on-purpose propylene production. However, its industrial application is limited because catalysts suffer from rapid deactivation due to coke deposition and metal catalyst sintering. To enhance metal catalyst dispersion and coke resistance, Pt-based catalysts have been widely investigated with various porous supports. In particular, zeolite can benefit from large surface area and acid sites, which favors high metal dispersion and promoting catalytic activity. In this work, we investigated the PDH catalytic properties of Beta zeolites as a support for Pt-Sn based catalysts. In comparison with Pt-Sn supported over θ-Al2O3 and amorphous silica (Q6), Beta zeolite-supported Pt-Sn catalysts exhibited a different reaction trend, achieving the best propylene selectivity after a proper period of reaction time. The different PDH catalytic behavior over Beta zeolite-supported Pt-Sn catalysts has been attributed to their physicochemical properties and reaction mechanism. Although Pt-Sn catalyst supported over Beta zeolite with low acidity showed low Pt dispersion, it formed a relatively lower amount of coke on PDH reaction and maintained a high surface area and active Pt surfaces, resulting in enhanced stability for PDH reaction. This work can provide a better understanding of zeolite-supported Pt-Sn catalysts to improve PDH catalytic activity with high selectivity and low coke formation.


2017 ◽  
Vol 7 (1) ◽  
pp. 181-190 ◽  
Author(s):  
M. Linares ◽  
C. Vargas ◽  
A. García ◽  
C. Ochoa-Hernández ◽  
J. Čejka ◽  
...  

Hierarchical Beta zeolites with different Si/Al molar ratios, synthesized by crystallization of silanized protozeolitic units, were investigated in the liquid-phase Beckmann rearrangement of cyclohexanone and cyclododecanone oximes.


2020 ◽  
Vol 10 (14) ◽  
pp. 4602-4611 ◽  
Author(s):  
Ke Zhang ◽  
Sergio Fernandez ◽  
Elisha S. Converse ◽  
Sarah Kobaslija

Hierarchical zeolites can be synthesized by different strategies, resulting in the creation of mesoporosity with different configurations (inter-crystalline or intra-crystalline) in addition to unique porous and catalytic properties.


2018 ◽  
Vol 304 ◽  
pp. 89-96 ◽  
Author(s):  
J.M. Escola ◽  
D.P. Serrano ◽  
R. Sanz ◽  
R.A. Garcia ◽  
A. Peral ◽  
...  

2017 ◽  
Vol 248 ◽  
pp. 30-39 ◽  
Author(s):  
Gang Huang ◽  
Peng Ji ◽  
Hao Xu ◽  
Jin-Gang Jiang ◽  
Li Chen ◽  
...  

AIChE Journal ◽  
2020 ◽  
Vol 66 (9) ◽  
Author(s):  
Sergio Fernandez ◽  
Michele L. Ostraat ◽  
Ke Zhang

Author(s):  
Elise Peeters ◽  
Ibrahim Khalil ◽  
Pierre Eloy ◽  
Sergio Calderon-Ardila ◽  
Jan Dijkmans ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document