Thermally activated construction of open metal sites on a Zn-organic framework: An effective strategy to enhance Lewis acid properties and catalytic performance for CO2 cycloaddition reactions

2022 ◽  
Vol 572 ◽  
pp. 151408
Author(s):  
Jie Zhang ◽  
Moliang Zou ◽  
Qing Li ◽  
Weili Dai ◽  
Dan Wang ◽  
...  
2019 ◽  
Vol 55 (95) ◽  
pp. 14347-14350 ◽  
Author(s):  
Dingxuan Ma ◽  
Yaowen Zhang ◽  
Shaoshao Jiao ◽  
Jixin Li ◽  
Kang Liu ◽  
...  

A novel tri-functional MOF catalyst was achieved by PSM method. Because of the synergistic effect of Lewis acid, Brønsted acid and Br− anion, MIL-IMAc-Br− displayed an efficient catalytic performance for CO2 conversion.


2019 ◽  
Vol 7 (10) ◽  
pp. 5575-5582 ◽  
Author(s):  
Hao Huang ◽  
Fumin Li ◽  
Ying Zhang ◽  
Yu Chen

Employing metalloporphyrin as monomer is an effective strategy to overcome the drawback of graphdiyne in electrocatalytic process. The Co–N4 active centers, expanded pores, and conjugated structure altogether endow the Co-PDY with excellent OER catalytic performance.


2013 ◽  
Vol 3 (3) ◽  
pp. 606-617 ◽  
Author(s):  
Laura Mitchell ◽  
Berenice Gonzalez-Santiago ◽  
John P. S. Mowat ◽  
Mary E. Gunn ◽  
Patrick Williamson ◽  
...  

Nanoscale ◽  
2020 ◽  
Vol 12 (30) ◽  
pp. 16136-16142
Author(s):  
Xuan Wang ◽  
Ming-Jie Dong ◽  
Chuan-De Wu

An effective strategy to incorporate accessible metalloporphyrin photoactive sites into 2D COFs by establishing a 3D local connection for highly efficient photocatalysis was developed.


2021 ◽  
Author(s):  
Sergio Rojas-Buzo ◽  
Benjamin Bohigues ◽  
Christian W. Lopes ◽  
Débora M. Meira ◽  
Mercedes Boronat ◽  
...  

The Brønsted/Lewis acid properties of Hf-MOF-808 can be tuned by simply controlling the solvent employed in its synthesis, with direct catalytic implications on the activity and selectivity of organic reactions sensitive to the active site nature.


2012 ◽  
Vol 51 (9) ◽  
pp. 4947-4953 ◽  
Author(s):  
Zhangjing Zhang ◽  
Shengchang Xiang ◽  
Kunlun Hong ◽  
Madhab, C. Das ◽  
Hadi D. Arman ◽  
...  

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