Sulfonic and phosphonic porous solids as proton conductors

2022 ◽  
Vol 451 ◽  
pp. 214241
Author(s):  
Shan-Shan Liu ◽  
Qing-Qing Liu ◽  
Sheng-Zheng Huang ◽  
Chong Zhang ◽  
Xi-Yan Dong ◽  
...  
2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.


2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.


2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>


2009 ◽  
Vol 24 (6) ◽  
pp. 1197-1200
Author(s):  
Lin-Na HU ◽  
Jun-Hua HE ◽  
Hui-Fen PENG ◽  
Yue-Xing ZHANG
Keyword(s):  

1999 ◽  
Vol 600 ◽  
Author(s):  
Yong-Il Park ◽  
Jae-Dong Kim ◽  
Masayuki Nagai

AbstractA drastic increase of electrical conductivity was observed in the composite of amorphous phosphate and ion-exchange resins (Nafion) as phosphorus concentration increased. Incorporation of amorphous phosphate into Nafion caused a large increase of conductivity to about 4×10−1S/cm at 23°C. However, the fabricated composite showed very low chemical stability.A high proton conductivity was also observed in a new inorganic-organic hybrids through incorporating PMA(molibdo-phosphoric acid)/PWA(tungsto-phosphoric acid) as a proton source in amorphous silicophosphate gel structure. Obtained gels were homogeneous and chemically stable. Resulting proton conductivity is very high (up to 5.5×10−3S/cm) compared to those of silicophosphate gels.


Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1205
Author(s):  
Hai Qiu ◽  
Ying Li ◽  
Tianfu Guo ◽  
Shan Tang ◽  
Zhaoqian Xie ◽  
...  

Structural topology and loading condition have important influences on the mechanical behaviors of porous soft solids. The porous solids are usually set to be under uniaxial tension or compression. Only a few studies have considered the biaxial loads, especially the combined loads of tension and compression. In this study, porous soft solids with oblique and square lattices of circular voids under biaxial loadings were studied through integrated experiments and numerical simulations. For the soft solids with oblique lattices of circular voids, we found a new pattern transformation under biaxial compression, which has alternating elliptic voids with an inclined angle. This kind of pattern transformation is rarely reported under uniaxial compression. Introducing tensile deformation in one direction can hamper this kind of pattern transformation under biaxial loading. For the soft solids with square lattices of voids, the number of voids cannot change their deformation behaviors qualitatively, but quantitatively. In general, our present results demonstrate that void morphology and biaxial loading can be harnessed to tune the pattern transformations of porous soft solids under large deformation. This discovery offers a new avenue for designing the void morphology of soft solids for controlling their deformation patterns under a specific biaxial stress-state.


1995 ◽  
Vol 51 (14) ◽  
pp. 8709-8714 ◽  
Author(s):  
S. J. Sze ◽  
T. Y. Lee

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