Method dependency of relationships between specific surface area and soil physicochemical properties

2010 ◽  
Vol 50 (2) ◽  
pp. 182-190 ◽  
Author(s):  
Yeliz Yukselen-Aksoy ◽  
Abidin Kaya
Agronomy ◽  
2019 ◽  
Vol 9 (9) ◽  
pp. 531 ◽  
Author(s):  
Marta Cybulak ◽  
Zofia Sokołowska ◽  
Patrycja Boguta

There is limited information regarding the effect of biochar (BioC) on improving the fertility of degraded soils (fallow and grassland), particularly with respect to changes with time. The objective of the study was to evaluate, in a three-year field experiment, the influence of BioC on the physicochemical properties of Haplic Luvisol. BioC, obtained via wood waste pyrolysis at 650 °C, was applied to the soil of subplots under fallow and grassland at rates of 0, 1, 2, and 3 kg·m−2. Soil samples were collected eight times, from 2013 to 2015. Physicochemical characterization was performed for soil and BioC by analyzing density, pH, surface charge, as well as ash and organic carbon content. BioC’s influence on the physicochemical properties of degraded soils was determined by analyzing the changes in pH, specific surface area, radius, and volume of the micropore. The addition of BioC affected analyzed soils to varying degrees. In the case of the fallow, a positive effect on changes in these parameters was observed, particularly at the highest biochar dose and for the last year of the experiment. However, for the grassland, in most cases we observed the opposite trend—for example, pH and specific surface area values decreased with increasing biochar dose. We believe that it is necessary to examine how BioC affects sorption properties of organic matter of fallow and grassland soils, as well as the BioC’s influence on humic acids of these soils as a function on BioC dose and function of time.


2014 ◽  
Vol 16 (46) ◽  
pp. 25609-25620 ◽  
Author(s):  
Yaovi Holade ◽  
Claudia Morais ◽  
Karine Servat ◽  
Teko W. Napporn ◽  
K. Boniface Kokoh

We report a convenient and straightforward thermal pre-treatment to improve the physicochemical properties of carbon-based substrates to boost the catalytic activity of platinum nanoparticles.


1992 ◽  
Vol 29 (5) ◽  
pp. 803-818 ◽  
Author(s):  
R. N. Yong ◽  
A. M. O. Mohamed ◽  
B. W. Wang

The study of the physicochemical properties of pure amorphous materials (complexes) consisting of Fe2O3 and SiO2 in various proportions indicates that the amorphous complexes will exhibit different properties and characteristics depending on the proportions of Fe2O3 and SiO2. Addition of the amorphous complexes with illitic clay studied shows that the properties of the clay admixture will also vary according to the properties of the amorphous complex, albeit to a lesser degree. The properties and behaviour observed for the amorphous complexes and the clay admixtures can be linked directly to the large specific surface area and high surface charge of the amorphous complexes. The contribution of amorphous complexes to the clay – amorphous complex mixtures (clay admixtures) is twofold: firstly, by the amount of amorphous complex in the clay admixture, and secondly by the composition of the amorphous complex used. The contribution from the amorphous complex is in two forms: water-holding capacity and bonding action. The presence of pH-dependent surface charges associated with the amorphous complexes makes the physicochemical properties and behaviour of the clay admixtures (e.g., liquid limits and zeta potential) sensitive to the pH environment. Coating of amorphous colloids onto clay particle surfaces, shown by scanning electron microscopy, appears to, be enhanced by a decrease in pH of the system, indicating that the enhancement is likely due to the increased electrostatic attraction resulting from the increased amounts of positive charges on the amorphous colloids. Key words : amorphous materials, mass ratio, zeta potential, Bingham yield stress, clay admixtures, hydrogen bonding, specific surface area, cation exchange capacity, anion exchange capacity, fabric and soil structure.


2017 ◽  
Vol 68 (3) ◽  
pp. 483-486
Author(s):  
Constantin Sorin Ion ◽  
Mihaela Bombos ◽  
Gabriel Vasilievici ◽  
Dorin Bombos

Desulfurisation of atmospheric distillation gasoline and gas oil was performed by adsorption process on Fe/ bentonite. The adsorbent was characterized by determining the adsorption isotherms, specific surface area, pore volume and average pore diameter. Adsorption experiments of atmospheric distillation gasoline and gas oil were performed in continuous system at 280�320oC, 5 atm and volume hourly space velocities of 1�2 h-1. The efficiency of adsorption on Fe / bentonite was better at desulphurisation of gasoline versus gas oil.


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