Physicochemical properties and oxidation reactivity of exhaust soot from a modern diesel engine: Effect of oxyfuel type

2022 ◽  
Vol 238 ◽  
pp. 111940
Author(s):  
Jiangjun Wei ◽  
Wenjian Lu ◽  
Yang Zeng ◽  
Haozhong Huang ◽  
Mingzhang Pan ◽  
...  
2019 ◽  
Author(s):  
Chem Int

Biodiesel produced by transesterification process from vegetable oils or animal fats is viewed as a promising renewable energy source. Now a day’s diminishing of petroleum reserves in the ground and increasing environmental pollution prevention and regulations have made searching for renewable oxygenated energy sources from biomasses. Biodiesel is non-toxic, renewable, biodegradable, environmentally benign, energy efficient and diesel substituent fuel used in diesel engine which contributes minimal amount of global warming gases such as CO, CO2, SO2, NOX, unburned hydrocarbons, and particulate matters. The chemical composition of the biodiesel was examined by help of GC-MS and five fatty acid methyl esters such as methyl palmitate, methyl stearate, methyl oleate, methyl linoleate and methyl linoleneate were identified. The variables that affect the amount of biodiesel such as methanol/oil molar ratio, mass weight of catalyst and temperature were studied. In addition to this the physicochemical properties of the biodiesel such as (density, kinematic viscosity, iodine value high heating value, flash point, acidic value, saponification value, carbon residue, peroxide value and ester content) were determined and its corresponding values were 87 Kg/m3, 5.63 Mm2/s, 39.56 g I/100g oil, 42.22 MJ/Kg, 132oC, 0.12 mgKOH/g, 209.72 mgKOH/g, 0.04%wt, 12.63 meq/kg, and 92.67 wt% respectively. The results of the present study showed that all physicochemical properties lie within the ASTM and EN biodiesel standards. Therefore, mango seed oil methyl ester could be used as an alternative to diesel engine.


2017 ◽  
Vol 24 (3) ◽  
pp. 99-105 ◽  
Author(s):  
Ireneusz Pielecha ◽  
Jacek Pielecha ◽  
Maciej Skowron ◽  
Aleksander Mazanek

Abstract The process of fuel combustion in a diesel engine is determined by factors existing during liquid fuel injection and atomisation. The physicochemical properties of the fuel to a large extent decide upon the quality of this phase of cylinder fuelling. So it is important to ensure appropriate properties of a fuel affecting its atomisation and, as a result, combustion. The paper deals with the topic of diesel oil improvers and the analysis of their influence on atomisation and combustion indices. In the studies base diesel oil and a diesel fuel improved by a package of additives, were used. The process of conventional and improved fuel injection was analysed by using optical examinations. The amount of released heat was evaluated during the studies carried out on combustion. Significant aspects of the applied improvers in relation to fuel injection and its combustion have been indicated.


Author(s):  
Alex Y ◽  
Roji George Roy

Biodiesel has become more attractive recently, because of its environmental benefits and the fact that it is made from renewable resources. Over the past few decades, most of the countries depending on diesel engines for transportation. Some of its valuable advantages like highest thermal efficiency made it very popular. At the same time, the cost of diesel fuel is increasing, due to the depletion of fossil fuels. In this current scenario, we need an alternative fuel instead of diesel fuel. Many of the researchers have successfully placed several works on generating energy from different types of alternative sources including solar and some kind of conversion processes including renewable agricultural products into liquid fuel. One of the biggest challenges for developing countries in relation to energy consumption is to develop and implement technologies that help to improve efficiency of automobile engines, also to reduce the emissions of harmful gases and particulate matters. In order to avoid environmental impacts, emissions are reduced or eliminated by introducing renewable energy resources. The present research chronicles the production and testing of renewable biodiesel fuel derived from virgin coconut oil on a diesel engine, to analyses the engine performance and emission characteristics. In the first phase of work, production of biodiesel fuel from virgin coconut oil using transeterification process with two types of catalysts (homogenous and heterogeneous). The preliminary results shows that, with the addition of homogenous catalyst called Potassium Hydroxide (KOH) with methanol shows much higher activity than that of heterogeneous catalysts, and it shows more similar properties with diesel fuel. The results obtained from the chemical test and physicochemical properties of transesterified biodiesel fuel clearly proves the above-mentioned statement. The chemical tests such as GCMS and FT-IR clearly shows that the biodiesel fuel has sufficient amount of volatile components and functional groups. Then, physicochemical properties include, Fire point, Flashpoint, density, and viscosity were analyzed. Finally, Engine performance and Emission characteristics were analysed to confirm, whether this biodiesel fuel is suitable for diesel engines, without any engine modifications. It was found to be, the transesterified virgin coconut oil biodiesel has similar properties to that of the diesel fuel. From the physiochemical properties and engine performance clearly shows that, coconut oil biodiesel is suitable for diesel engine on blending, at a blending percentage level of 20% with conventional diesel fuel. Since the obtained transesterified biofuel can be used as an alternative fuel for diesel engines. The several journal reports and find outs from experimental investigation clearly depicts that the efficiency of the transesterified biofuel mainly depends upon the amount of catalyst adding and type of catalysts present in the biofuel, whether it is homogenous or heterogeneous catalyst is suitable with methanol. Finally, from the analysis made from biodiesel fuel. Coconut Oil Biodiesel fuel has less emission characteristics than that of the diesel fuels.


2021 ◽  
Vol 6 (1) ◽  
pp. 1-6
Author(s):  
Mohamed Yagoub Alkhalil Karar ◽  
Hamid M. Mustafa ◽  
Eltjani EL. Hago

This study was conducted to investigate physicochemical properties, copper corrosion test and test the diesel engine performance of diethyl ether diesel blend fuel. With aid of distillation characteristic, the blends percentage were selected as DEE5%, DEE10, DEE15 and DEE20%. Stabinger Viscometer apparatus was used to determine the Kinematic viscosities, Digital Density Analyzer was used to determine the densities. ASTM D 4737 – 03 Test Method are used to determined calculated Cetane index. Copper strip corrosion device was used to determine corrosiveness of copper from diesel and DEE diesel blends. A single cylinder, four stroke diesel engines, mounted on a moving frame was used to conduct the engine test. From the study result we found that that blends physicochemical properties improved with diethyl ether ratio increased in the blends. While Cetane Index increased with diethyl ether ratio increased. At the higher load, the best result of Break thermal efficiency found at DEE10%, where at the low load, the best mechanical efficiency found at DEE5%, DEE15% and DEE20 and at the higher load, the best mechanical efficiency found at DEE20%, on other hand at the low load, the best specific fuel consumption found at DEE15%, While at the higher load the best specific fuel consumption found at DEE10%. Due to availability of diethyl ether in Sudan, diethyl ether can be used up to 10% in diesel blend with no further changed in diesel engine design, and this can be contributed to overcome the diesel fuel crisis in Sudan, but further information and studies are needed for diethyl ether transportation and blending facilities, beside study the effect the addition of diethyl ether on diesel price.


RSC Advances ◽  
2015 ◽  
Vol 5 (22) ◽  
pp. 17160-17170 ◽  
Author(s):  
S. Imtenan ◽  
H. H. Masjuki ◽  
M. Varman ◽  
I. M. Rizwanul Fattah

Oxygenated additives modify the physicochemical properties of the biodiesel–diesel blends which influences the combustion mechanism in a way that improves the performance and emission characteristics significantly.


Processes ◽  
2020 ◽  
Vol 8 (9) ◽  
pp. 1141
Author(s):  
Yew Heng Teoh ◽  
Heoy Geok How ◽  
Thanh Danh Le ◽  
Huu Tho Nguyen

A two-step transesterification process was employed in the biodiesel production from non-edible Alexandrian Laurel. The key physicochemical properties of the Alexandrian Laurel biodiesel (ALB), diesel and blends of both fuels were compared and analyzed. The effects of blending biodiesel (ALB) and petroleum diesel on engine performance, combustion and exhaust emissions were investigated in a turbocharged, high-pressure common-rail diesel engine under six different speed operations and at full load conditions. The test fuels comprised a conventional diesel fuel and four different fuel blends of ALB. The results showed relatively close physicochemical properties of ALB and its blends when compared with petroleum diesel. However, the use of ALB-blended fuel resulted in penalties engine brake power, brake specific fuel consumption (BSFC) despite slightly improved brake thermal efficiency (BTE). Brake specific nitrogen oxide (BSNOx) was found worsened with higher ALB content in the blends. Nonetheless, consistent improvements in brake specific carbon monoxide (BSCO), brake specific carbon dioxide (BSCO2), and smoke were noticed when ALB blends were used. Additionally, ALB blends contributed to reduction in peak combustion pressure, peak heat release rate (HRR) and combustion duration. In general, the findings suggest satisfactory operation with ALB biodiesel-diesel blends in an unmodified diesel engine.


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