Solidification/stabilization of red mud with natural radionuclides in granular blast furnace slag based geopolymers

2022 ◽  
Vol 316 ◽  
pp. 125916
Author(s):  
Zhongtao Luo ◽  
Yuhua Hao ◽  
Yuandong Mu ◽  
Changbo Tang ◽  
Xiaohai Liu
2017 ◽  
Vol 68 (6) ◽  
pp. 1182-1187
Author(s):  
Ilenuta Severin ◽  
Maria Vlad

This article presents the influence of the properties of the materials in the geopolymeric mixture, ground granulated blast furnace slag (GGBFS) + wheat straw ash (WSA) + uncalcined red mud (RMu), and ground granulated blast furnace slag + wheat straw ash + calcined red mud (RMc), over the microstructure and mechanical properties of the synthesised geopolymers. The activation solutions used were a NaOH solution with 8M concentration, and a solution realised from 50%wt NaOH and 50%wt Na2SiO3. The samples were analysed: from the microstructural point of view through SEM microscopy; the chemical composition was determined through EDX analysis; and the compressive strength tests was done for samples tested at 7 and 28 days, respectively. The SEM micrographies of the geopolymers have highlighted a complex structure and an variable compressive strength. Compressive strength varied from 24 MPa in the case of the same recipe obtained from 70% of GGBFS + 25% WSA +5% RMu, alkaline activated with NaOH 8M (7 days testing) to 85 MPa in the case of the recipe but replacing RMu with RMc with calcined red mud, alkaline activated with the 50%wt NaOH and 50%wt Na2SiO3 solution (28 days testing). This variation in the sense of the rise in compressive strength can be attributed to the difference in reactivity of the materials used in the recipes, the curing period, the geopolymers structure, and the presence of a lower or higher rate of pores, as well as the alkalinity and the nature of the activation solutions used.


2021 ◽  
Vol 13 (20) ◽  
pp. 11298
Author(s):  
Alessio Occhicone ◽  
Mira Vukčević ◽  
Ivana Bosković ◽  
Claudio Ferone

The aluminum Bayer production process is widespread all over the world. One of the waste products of the Bayer process is a basic aluminosilicate bauxite residue called red mud. The aluminosilicate nature of red mud makes it suitable as a precursor for alkali-activated materials. In this work, red mud was mixed with different percentages of blast furnace slag and then activated by sodium silicate solution at different SiO2/Na2O ratios. Obtained samples were characterized by chemical–physical analyses and compressive strength determination. Very high values of compressive strength, up to 50 MPa, even for high percentage of red mud in the raw mixture (70 wt.% of RM in powder mixture), were obtained. In particular, the higher compressive strength was measured for cubic samples containing 50 wt.% of RM, which showed a value above 70 MPa. The obtained mixtures were characterized by no or scarce environmental impact and could be used in the construction industry as an alternative to cementitious and ceramic materials.


2019 ◽  
Vol 133 ◽  
pp. 105247 ◽  
Author(s):  
Lei Wang ◽  
Liang Chen ◽  
Daniel C.W. Tsang ◽  
Yaoyu Zhou ◽  
Jörg Rinklebe ◽  
...  

2017 ◽  
Vol 1143 ◽  
pp. 114-119
Author(s):  
Ilenuta Severin ◽  
Maria Vlad

Ground granulated blast furnace slag, red mud, wheat straw ash are secondary material which after alkaline activation can be used in the construction materials’ domain. Their disposal poses a threat to the environment, whereas by reusing them we would be able to reduce this negative impact. This paper describes the research carried out in order to synthesise some geopolymer recipes, which are based on ground granulated blast furnace slag, red mud and wheat straw ash, alkaline activated with sodium hydroxide or a solution made with sodium hydroxide and sodium silicate. Factors that influence the compression strength have been studied such as: the nature of the alkaline activator, the chemical composition of solid materials in the recipes and the curing time. The geopolymer samples have been dried at room temperature for 7 and 28 days, respectively, and after the compressive strength tests has been made. Following this research it has been found out that NaOH/Na2SiO3 activated geopolymer samples have shown a higher resistance in the compressive strength. From the SEM analysis it has been found out that the samples with a higher amount of ground granulated blast furnace slag in their composition had a more homogeneous and less porous design than those with a smaller amount of ground granulated blast furnace slag.


2011 ◽  
Vol 261-263 ◽  
pp. 491-495 ◽  
Author(s):  
Sang Soo Lee ◽  
Ha Young Song ◽  
Yun Seong Lee ◽  
Kang Pil Lee

Recently, as the national policy of green growth is promoted, construction field also makes an effort to reduce CO2 gas released when producing cement continuously. In other words, as the method solving environmental pollution and resources exhaustion, lots of mineral material compounds such as blast furnace slag which is industrial by-product, fly ash, red mud, etc. are examined to be used as the substitute good of cement. Therefore, this study intended to supplement the weaknesses of blast furnace slag and red mud with blast furnace slag and red mud, as the substitute good of cement, not concrete compound, manufacture inorganic composite of cement world, which can be made with only alkali accelerator at normal temperature, without high-temperature plasticity. After confirming kinds of red mud and alkali liquids and physical property by the change of addition rate with fundamental experiment, proper mix was drawn by combining blast furnace slag.


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