Investigating temperature-driven water transport in cathode gas diffusion media of PEMFC with a non-isothermal, two-phase model

2021 ◽  
Vol 248 ◽  
pp. 114791
Author(s):  
Yiming Xu ◽  
Ruijia Fan ◽  
Guofeng Chang ◽  
Sichuan Xu ◽  
Tao Cai
Author(s):  
Ugur Pasaogullari ◽  
Chao-Yang Wang ◽  
Ken S. Chen

A two-phase, multi-component, full cell model is developed in order to analyze the two-phase transport in polymer electrolyte fuel cells with multi-layer cathode gas diffusion media, consisting of a coarse gas diffusion layer (GDL) (average pore size ~ 10 μm) and a micro-porous layer (MPL) (average pore size ~ 0.2–2 μm). The relevant structural properties of MPL, including average pore size, wettability, thickness and porosity are examined and their effects on liquid water transport are discussed. It is found that MPL promotes back-flow of liquid water across the membrane towards the anode, consequently alleviating cathode flooding. Furthermore, it is seen that unique porous and wetting characteristics of MPL causes a discontinuity in the liquid saturation at MPL-GDL interface, which in turn reduces the amount of liquid water in cathode catalyst layer-gas diffusion medium interface in some cases. Our analyses show that the back-flow of liquid water increases with the increasing thickness and decreasing pore size, hydrophobicity and bulk porosity of the MPL.


2014 ◽  
Vol 64 (3) ◽  
pp. 839-851 ◽  
Author(s):  
T. Kotaka ◽  
Y. Tabuchi ◽  
U. Pasaogullari ◽  
C.-Y. Wang

Author(s):  
Xiao-Dong Wang ◽  
Xin-Xin Zhang ◽  
Tao Liu ◽  
Yuan-Yuan Duan ◽  
Wei-Mon Yan ◽  
...  

This study presents a complete three-dimensional, two-phase transport model for proton exchange membrane fuel cells based on the two-fluid method, which couples the mass, momentum, species, and electrical potential equations. The different liquid water transport mechanisms in the flow channels, gas diffusion layers, catalyst layers, and membrane are modeled using two different liquid water transport equations. In the flow channels, gas diffusion layers, and catalyst layers, the generalized Richards equation is used to describe the liquid water transport including the effect of the pressure gradient, capillary diffusion, evaporation and condensation, and electro-osmotic, while in the membrane, the liquid water transport equation only takes into account the effect of back diffusion and electro-osmotic. Springer’s model is utilized on the catalyst layer-membrane interface to maintain continuum of the liquid water distribution. The model is used to investigate the effect of flow channel aspect ratio on the performance of fuel cells with single and triple serpentine flow fields. The predictions show that for both flow fields, the cell performance improves with decreasing aspect ratio. The aspect ratio has less effect on the cell performance for the triple serpentine flow field than for the single serpentine flow field due to the weaker under-rib convection.


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