Low platinum alloy catalyst PtCo3 obtaining high catalytic activity and stability with great water and CO2 resistance for catalytic oxidation of toluene

In this study, a series of Co3O4-CeO2 nanocomposites with various Co3O4 loading were fabricated by the impregnation method using cobalt(II) acetate as the cobalt precursor for the treatment of benzene, toluene, ethylbenzene, and xylene (BTEX). The as-prepared Co3O4-CeO2 nanocomposites were thoroughly characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brumauer-Emmett-Teller (BET), hydrogen temperature-programmed reduction (H2-TPR), and temperature-programmed desorption (O2-TPD). The excellent reproduction of active oxygen species caused by the high dispersion of Co3O4 crystals on the CeO2 supports was established. In addition, the reduction peaks of Co3O4-CeO2 nanocomposites were found at much lower temperatures compared to pure CeO2, considering their unique redox property influencing on the high catalytic activity. Among the characterized materials, the 5.0 wt.% Co3O4 supported on CeO2 (5.0Co–Ce) was the best system for catalytic oxidation of xylene, along with excellent performances in the cases of benzene, ethylbenzene, and toluene. Its catalytic activity increased in the order: benzene < xylene < ethylbenzene < toluene . Furthermore, the addition of carbon monoxide (CO) as a coreactant permitted to improve the catalytic performances in such oxidations as well as the stability of as-prepared catalysts, even under humid conditions.

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Engineering surface defects and metal–support interactions on Pt/TiO2(B) nanobelts to boost the catalytic oxidation of CO

Catalysis Science & Technology ◽

10.1039/c8cy01410h ◽

2018 ◽

Vol 8 (19) ◽

pp. 4934-4944 ◽

Cited By ~ 16

Author(s):

Jinghua Liu ◽

Tong Ding ◽

Hao Zhang ◽

Guangcheng Li ◽

Jinmeng Cai ◽

...

Keyword(s):

Catalytic Activity ◽

Catalytic Oxidation ◽

Water Resistance ◽

Surface Defects ◽

High Catalytic Activity ◽

Oxidation Of Co ◽

Catalytic Oxidation Of Co ◽

Metal Support ◽

Metal Support Interactions

The thermally reduced Pt/TiO2(B) catalysts show high catalytic activity and good water resistance for the catalytic oxidation of CO.

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Self-regeneration of a Ni–Cu alloy catalyst during a three-way catalytic reaction

Physical Chemistry Chemical Physics ◽

10.1039/c9cp01884k ◽

2019 ◽

Vol 21 (35) ◽

pp. 18816-18822 ◽

Cited By ~ 4

Author(s):

Hiroyuki Asakura ◽

Tetsuo Onuki ◽

Saburo Hosokawa ◽

Nozomi Takagi ◽

Shigeyoshi Sakaki ◽

...

Keyword(s):

Catalytic Activity ◽

Catalytic Reaction ◽

High Catalytic Activity ◽

Cu Alloy ◽

Alloy Catalyst

Ni–Cu alloy supported on γ-Al22O3 catalysts exhibit high catalytic activity and durability for a three-way catalytic reaction under both oxidative and reductive conditions because of their self-regenerating feature.

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The Catalytic Oxidation of Aqueous Phenol by H2O2Using a Macrocyclic (N-Donor) Cobalt(Ii) Complex

Progress in Reaction Kinetics and Mechanism ◽

10.3184/146867811x13103063934140 ◽

2011 ◽

Vol 36 (4) ◽

pp. 342-351 ◽

Cited By ~ 1

Author(s):

Fa-mei Feng ◽

Fu-an Liu ◽

Shu-lan Cai ◽

Jia-qing Xie

Keyword(s):

High Pressure ◽

Catalytic Activity ◽

Liquid Chromatography ◽

Catalytic Oxidation ◽

Catalytic Efficiency ◽

High Catalytic Activity ◽

Oxidation Of Phenol ◽

Effects Of Temperature ◽

Oxalic Acids ◽

Catalytic Oxidation Of Phenol

A new macrocyclic (N-donor) cobalt(II) complex, denoted CoR, was synthesized and characterized, and used as a mimetic peroxidase in the catalytic oxidation of phenol by H2O2. The catalytic system displayed high catalytic activity and the catalytic character of a metalloenzyme, although it did not attain the catalytic efficiency of enzymes. The final products were maleic and oxalic acids. Intermediate products, such as catechol and hydroquinone and p-benzoquinone, were detected by high-pressure liquid chromatography (HPLC) and UV-Vis spectrophotometry. The effects of temperature and the pH of the system on the rate of the catalytic oxidation were investigated. A reaction mechanism and kinetic model for the catalytic oxidation are proposed, which are supported by the results of the experimental and calculation data.

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Catalytic oxidation of 4-chlorophenol with magnetic Fe3O4 nanoparticles: mechanisms and particle transformation

RSC Advances ◽

10.1039/c5ra10433e ◽

2015 ◽

Vol 5 (82) ◽

pp. 66927-66933 ◽

Cited By ~ 13

Author(s):

Rong Cheng ◽

Guan-qing Li ◽

Can Cheng ◽

Lei Shi ◽

Xiang Zheng ◽

...

Keyword(s):

Catalytic Activity ◽

Catalytic Oxidation ◽

Fe3o4 Nanoparticles ◽

High Catalytic Activity ◽

Magnetic Fe3o4 Nanoparticles ◽

Magnetic Fe3o4

Nanosized Fe3O4 showed high catalytic activity even after being used several times, and reactive sites on surface increased resulted in the higher activity of particles. ˙OH produced during reaction was the main cause for degradation of 4-CP.

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Enhanced catalytic activity of low-Pt content nanocatalysts supported on hollow carbon spheres for the ORR in alkaline media

MRS Advances ◽

10.1557/adv.2020.370 ◽

2020 ◽

Vol 5 (57-58) ◽

pp. 2961-2972

Author(s):

P.C. Meléndez-González ◽

E. Garza-Duran ◽

J.C. Martínez-Loyola ◽

P. Quintana-Owen ◽

I.L. Alonso-Lemus ◽

...

Keyword(s):

Catalytic Activity ◽

Anion Exchange ◽

Average Particle Size ◽

Synthesis Method ◽

Alkaline Media ◽

High Catalytic Activity ◽

Average Particle ◽

Carbon Spheres ◽

Hollow Carbon ◽

Hollow Carbon Spheres

In this work, low-Pt content nanocatalysts (≈ 5 wt. %) supported on Hollow Carbon Spheres (HCS) were synthesized by two routes: i) colloidal conventional polyol, and ii) surfactant-free Bromide Anion Exchange (BAE). The nanocatalysts were labelled as Pt/HCS-P and Pt/HCS-B for polyol and BAE, respectively. The physicochemical characterization of the nanocatalysts showed that by following both methods, a good control of chemical composition was achieved, obtaining in addition well dispersed nanoparticles of less than 3 nm TEM average particle size (d) on the HCS. Pt/HCS-B contained more Pt0 species than Pt/HCS-P, an effect of the synthesis method. In addition, the structure of the HCS remains more ordered after BAE synthesis, compared to polyol. Regarding the catalytic activity for the Oxygen Reduction Reaction (ORR) in 0.5 M KOH, Pt/HCS-P and Pt/HCS-B showed a similar performance in terms of current density (j) at 0.9 V vs. RHE than the benchmark commercial 20 wt. % Pt/C. However, Pt/HCS-P and Pt/HCS-B demonstrated a 6 and 5-fold increase in mass catalytic activity compared to Pt/C, respectively. A positive effect of the high specific surface area of the HCS and its interactions with metal nanoparticles and electrolyte, which promoted the mass transfer, increased the performance of Pt/HCS-P and Pt/HCS-B. The high catalytic activity showed by Pt/HCS-B and Pt/HCS-P for the ORR, even with a low-Pt content, make them promising cathode nanocatalysts for Anion Exchange Membrane Fuel Cells (AEMFC).

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Ordered Intermetallic Nanoparticles with High Catalytic Activity Prepared by an Electrochemically Induced Phase Transformation

10.26434/chemrxiv.8289812 ◽

2019 ◽

Author(s):

Du Sun ◽

yunfei wang ◽

Kenneth Livi ◽

chuhong wang ◽

ruichun luo ◽

...

Keyword(s):

Catalytic Activity ◽

Diffusion Mechanism ◽

Reduction Reaction ◽

Atomic Scale ◽

High Catalytic Activity ◽

Ambient Conditions ◽

Magnetic Devices ◽

Disordered Alloys ◽

Ordered Intermetallic ◽

Intermetallic Nanoparticles

<div> The synthesis of alloys with long range atomic scale ordering (ordered intermetallics) is an emerging field of nanochemistry. Ordered intermetallic nanoparticles are useful for a wide variety of applications such as catalysis, superconductors, and magnetic devices. However, the preparation of nanostructured ordered intermetallics is challenging in comparison to disordered alloys, hindering progress in materials development. We report a process for converting colloidally synthesized ordered intermetallic PdBi2 to ordered intermetallic Pd3Bi nanoparticles under ambient conditions by an electrochemically induced phase transition. The low melting point of PdBi2 corresponds to low vacancy formation energies which enables the facile removal of the Bi from the surface, while simultaneously enabling interdiffusion of the constituent atoms via a vacancy diffusion mechanism under ambient conditions. The resulting phase-converted ordered intermetallic Pd3Bi exhibits 11x and 3.5x higher mass activty and high methanol tolerance for the oxygen reduction reaction compared to Pt/C and Pd/C, respectively,which is the highest reported for a Pd-based catalyst, to the best of our knowledge. These results establish a key development in the synthesis of noble metal rich ordered intermetallic phases with high catalytic activity, and sets forth guidelines for the design of ordered intermetallic compounds under ambient conditions. </div>

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Nickel (II) and oxovanadium (IV) complexes supported on MCM-41 mesoporous and their application in catalytic selective sulfide and thiol oxidation

Combinatorial Chemistry & High Throughput Screening ◽

10.2174/1386207323999201111192649 ◽

2020 ◽

Vol 23 ◽

Author(s):

Mohsen Nikoorazm ◽

Maryam Khanmoradi ◽

Masoumeh Sayadian

Keyword(s):

Catalytic Activity ◽

Room Temperature ◽

Sol Gel ◽

Reaction Times ◽

Significant Loss ◽

Spectral Studies ◽

High Catalytic Activity ◽

Catalytic Systems ◽

Solvent Free Conditions ◽

Mcm 41

Introduction:: MCM-41 was synthesized using the sol-gel method. Then two new transition metal complexes of Nickel (II) and Vanadium (IV), were synthesized by immobilization of adenine (6-aminopurine) into MCM-41 mesoporous. The compounds have been characterized by XRD, TGA, SEM, AAS and FT-IR spectral studies. Using these catalysts provided an efficient and enantioselective procedure for oxidation of sulfides to sulfoxides and oxidative coupling of thiols to their corresponding disulfides using hydrogen peroxide at room temperature. Materials and Methods:: To a solution of sulfide or thiol (1 mmol) and H2O2 (5 mmol), a determined amount of the catalyst was added. The reaction mixture was stirred at room temperature for the specific time under solvent free conditions. The progress of the reaction was monitored by TLC using n-hexane: acetone (8:2). Afterwards, the catalyst was removed from the reaction mixture by centrifugation and, then, washed with dichloromethane in order to give the pure products. Results:: All the products were obtained in excellent yields and short reaction times indicating the high activity of the synthesized catalysts. Besides, the catalysts can be recovered and reused for several runs without significant loss in their catalytic activity. Conclusion:: These catalytic systems furnish the products very quickly with excellent yields and VO-6AP-MCM-41 shows high catalytic activity compared to Ni-6AP-MCM-41.

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Mechanisms of methane decomposition and carbon species oxidation on the Pr0.42Sr0.6Co0.2Fe0.7Nb0.1O3−σ electrode with high catalytic activity

Journal of Materials Chemistry A ◽

10.1039/c5ta07599h ◽

2015 ◽

Vol 3 (45) ◽

pp. 22816-22823 ◽

Cited By ~ 5

Author(s):

Peng Zhang ◽

Guoqing Guan ◽

Deni S. Khaerudini ◽

Xiaogang Hao ◽

Chunfeng Xue ◽

...

Keyword(s):

Catalytic Activity ◽

Carbon Deposition ◽

Methane Decomposition ◽

High Catalytic Activity ◽

Carbon Species

Carbon deposition characteristics on PSCFN and Ni–YSZ due to thermal CH4 decomposition are investigated by using TPR technique.

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Bio-Derived Catalysts: A Current Trend of Catalysts Used in Biodiesel Production

Catalysts ◽

10.3390/catal11070812 ◽

2021 ◽

Vol 11 (7) ◽

pp. 812

Author(s):

Hoang Chinh Nguyen ◽

My-Linh Nguyen ◽

Chia-Hung Su ◽

Hwai Chyuan Ong ◽

Horng-Yi Juan ◽

...

Keyword(s):

Catalytic Activity ◽

Fossil Fuels ◽

Current Trend ◽

Biodiesel Production ◽

High Catalytic Activity ◽

Promising Alternative ◽

Advantages And Disadvantages ◽

Biodiesel Synthesis ◽

Alkali Catalysts ◽

A Current

Biodiesel is a promising alternative to fossil fuels and mainly produced from oils/fat through the (trans)esterification process. To enhance the reaction efficiency and simplify the production process, various catalysts have been introduced for biodiesel synthesis. Recently, the use of bio-derived catalysts has attracted more interest due to their high catalytic activity and ecofriendly properties. These catalysts include alkali catalysts, acid catalysts, and enzymes (biocatalysts), which are (bio)synthesized from various natural sources. This review summarizes the latest findings on these bio-derived catalysts, as well as their source and catalytic activity. The advantages and disadvantages of these catalysts are also discussed. These bio-based catalysts show a promising future and can be further used as a renewable catalyst for sustainable biodiesel production.

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