Chiral amine ligands at rhenium(V) pentahydride complexes allow for characterization of an energetically accessible and reversible steric inversion of diastereotopic phosphorus atoms

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The stoichiometry and stereochemistry of bis(2-picolyl)amine (bpa) or bis(2-quinaldyl)amine (bqa) metal complexes were studied by spectroscopy, crystallography and DFT calculations.


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