Organosolv and ionosolv processes for autohydrolyzed poplar fractionation: Lignin recovery and characterization

2022 ◽  
Vol 197 ◽  
pp. 131-140
Author(s):  
Antonio Ovejero-Pérez ◽  
Victoria Rigual ◽  
Juan Carlos Domínguez ◽  
M. Virginia Alonso ◽  
Mercedes Oliet ◽  
...  
Keyword(s):  
Lignin Recovery

scholarly journals An extensive parameter study of hydrotropic extraction of steam-pretreated birch

2021 ◽  
Author(s):  
Johanna Olsson ◽  
Michael Persson ◽  
Mats Galbe ◽  
Ola Wallberg ◽  
Ann-Sofi Jönsson
Keyword(s):  
Residence Time ◽  
Steam Explosion ◽  
Room Temperature ◽  
Initial Step ◽  
Parameter Study ◽  
Hydrothermal Degradation ◽  
Steam Explosion Pretreatment ◽  
Lignin Extraction ◽  
Extraction Step ◽  
Lignin Recovery

AbstractEfficient fractionation of lignocellulosic biomass is an important step toward the replacement of fossil-based products. However, the utilisation of all of the components in biomass requires various fractionation techniques. One promising process configuration is to apply steam explosion for the recovery of hemicelluloses and a subsequent hydrotropic extraction step for the delignification of the remaining solids. In this work, the influence of residence time, temperature and biomass loading on lignin recovery from birch using sodium xylene sulphonate as a hydrotrope was investigated. Our results show that residence time, temperature and biomass loading correlate positively with lignin extraction, but the effects of these parameters were limited. Furthermore, when steam explosion was implemented as the initial step, hydrotropic extraction could be performed even at room temperature, yielding a lignin extraction of 50%. Also, hydrothermal degradation of the material was necessary for efficient delignification with sodium xylene sulphonate, regardless of whether it occurs during steam explosion pretreatment or is achieved at high temperatures during the hydrotropic extraction.

scholarly journals Optimization of Lignin Recovery from the Pre-Hydrolysate of Kraft-Based Dissolving Pulp Production Processes

2021 ◽  
Vol 11 (1) ◽  
pp. 454
Author(s):  
Adil Mazar ◽  
Naceur Jemaa ◽  
Waleed Wafa Al Dajani ◽  
Mariya Marinova ◽  
Michel Perrier
Keyword(s):  
Molecular Weight ◽  
Lignin Content ◽  
Sulfuric Acid Concentration ◽  
Dissolving Pulp ◽  
Potential Candidate ◽  
Lignin Extraction ◽  
Dissolved Organic Matters ◽  
Lignin Recovery ◽  
Total Lignin ◽  
Total Lignin Content

A pre-hydrolysate is an aqueous stream obtained during the production of hardwood kraft dissolving pulp. It is rich in sugars and contains dissolved organic matters. The purpose of this study is to investigate the optimization of lignin recovery from wood pre-hydrolysates and to characterize the extracted lignin. The optimal conditions for lignin extraction have been determined to be (a) a filtration temperature of 40 °C, (b) a sulfuric acid concentration of 8.5 kg·m−3, and (c) a coagulation time of 180 min. Using these conditions, high filtration rates have been obtained and the extracted lignin has a low content of impurities (8.3%), a low molecular weight (1270 Da), and a very low polydispersity (Mw/Mn = 1.22). Compared to kraft lignin, the pre-hydrolysate lignin has a much lower molecular weight and could be a potential candidate for niche applications. A high lignin recovery rate is possible (52% of the total lignin content in the pre-hydrolysate).

Probing the molecular weights of sweetgum and pine kraft lignin fractions

TAPPI Journal ◽  
2021 ◽  
Vol 20 (6) ◽  
pp. 381-391
Author(s):  
JULIANA M. JARDIM ◽  
PETER W. HART ◽  
LUCIAN LUCIA ◽  
HASAN JAMEEL
Keyword(s):  
Molecular Weight ◽  
Black Liquor ◽  
Average Molecular Weight ◽  
Gel Permeation Chromatography ◽  
Systematic Investigation ◽  
Kraft Pulping ◽  
Molecular Weights ◽  
Lignin Recovery ◽  
Lignin Reactivity ◽  
Kinetics Of

The present investigation undertook a systematic investigation of the molecular weight (MW) of kraft lignins throughout the pulping process to establish a correlation between MW and lignin recovery at different extents of the kraft pulping process. The evaluation of MW is crucial for lignin characterization and utilization, since it is known to influence the kinetics of lignin reactivity and its resultant physicochemical properties. Sweetgum and pine lignins precipitated from black liquor at different pHs (9.5 and 2.5) and different extents of kraft pulping (30–150 min) were the subject of this effort. Gel permeation chromatography (GPC) was used to deter- mine the number average molecular weight (Mn), mass average molecular weight (Mw), and polydispersity of the lignin samples. It was shown that the MW of lignins from both feedstocks follow gel degradation theory; that is, at the onset of the kraft pulping process low molecular weightlignins were obtained, and as pulping progressed, the molecular weight peaked and subsequently decreased. An important finding was that acetobromination was shown to be a more effective derivatization technique for carbohydrates containing lignins than acetylation, the technique typically used for derivatization of lignin.

scholarly journals Valorizing Waste Lignocellulose-Based Furniture Boards by Phosphoric Acid and Hydrogen Peroxide (Php) Pretreatment for Bioethanol Production and High-Value Lignin Recovery

2019 ◽  
Vol 11 (21) ◽  
pp. 6175
Author(s):  
Jingwen Zhao ◽  
Dong Tian ◽  
Fei Shen ◽  
Jinguang Hu ◽  
Yongmei Zeng ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Phosphoric Acid ◽  
Water Retention ◽  
Water Retention Capacity ◽  
Retention Capacity ◽  
Fractionation Process ◽  
Oh Groups ◽  
Lignin Recovery ◽  
High Cellulose ◽  
Simultaneous Saccharification

Three typical waste furniture boards (fiberboard, chipboard, and blockboard) were pretreated with phosphoric acid and hydrogen peroxide (PHP). The fractionation process of these feedstocks was attempted in order to harvest the cellulose-rich fraction for enzymatic hydrolysis and bioethanol conversion; further, lignin recovery was also considered in this process. The results indicated that 78.9–91.2% of the cellulose was recovered in the cellulose-rich fraction. The decreased crystallinity, which promoted the water retention capacity and enzyme accessibility, contributed greatly to the excellent hydrolysis performance of the cellulose-rich fraction. Therefore, rather high cellulose–glucose conversions of 83.3–98.0% were achieved by hydrolyzing the pretreated furniture boards, which allowed for harvesting 208–241 g of glucose from 1.0 kg of feedstocks. Correspondingly, 8.1–10.4 g/L of ethanol were obtained after 120 h of simultaneous saccharification and fermentation. The harvested lignin exhibited abundant carboxyl –OH groups (0.61–0.67 mmol g−1). In addition, approximately 15–26 g of harvested oligosaccharides were integrated during PHP pretreatment. It was shown that PHP pretreatment is feasible for these highly recalcitrant biomass board materials, which can diversify the bioproducts used in the integrated biorefinery concept.

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