Conversion of CO2 to cyclic carbonates by metal-ethylenediamine complexes in ionic liquid: A DFT mechanistic study

2022 ◽  
Vol 57 ◽  
pp. 101872
Author(s):  
Madhu Deepan Kumar ◽  
Shilpa Sunny ◽  
Madhavan Jaccob
Keyword(s):  
Ionic Liquid ◽  
Mechanistic Study ◽  
Cyclic Carbonates

Bifunctional Porphyrin Catalysts for the Synthesis of Cyclic Carbonates from Epoxides and CO2: Structural Optimization and Mechanistic Study

2014 ◽  
Vol 136 (43) ◽  
pp. 15270-15279 ◽  
Author(s):  
Tadashi Ema ◽  
Yuki Miyazaki ◽  
Junta Shimonishi ◽  
Chihiro Maeda ◽  
Jun-ya Hasegawa
Keyword(s):  
Structural Optimization ◽  
Mechanistic Study ◽  
Cyclic Carbonates

Hydrogen bond donor functionalized poly(ionic liquid)s for efficient synergistic conversion of CO2 to cyclic carbonates

2020 ◽  
Author(s):  
Haibin Gou ◽  
Xifei Ma ◽  
Qian Su ◽  
Lei Liu ◽  
Ting Ying ◽  
...  
Keyword(s):  
Hydrogen Bond ◽  
Ionic Liquid ◽  
Value Added ◽  
Pivotal Role ◽  
Cyclic Carbonates ◽  
Hydrogen Bond Donor ◽  
Metal Free ◽  
Recyclable Catalysts ◽  
Poly Ionic Liquid ◽  
Value Added Products

The development of metal-free, high effective and recyclable catalysts plays a pivotal role in transforming CO2 into high value-added products such as cyclic carbonates. In this paper, we have introduced...

Polyamine Functionalized Imidazolyl Poly(ionic liquid)s for the Efficient Conversion of CO2 into Cyclic Carbonates

2021 ◽  
Author(s):  
Yizhen Zou ◽  
Yuansheng Ge ◽  
Qiang Zhang ◽  
Wei Liu ◽  
Xiaoguang Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Global Warming ◽  
Greenhouse Gases ◽  
Cyclic Carbonates ◽  
Challenging Issue ◽  
Efficient Conversion ◽  
Poly Ionic Liquid ◽  
Additional Value

Global warming is becoming a challenging issue due to the emissions of large number of greenhouse gases, mainly CO2. The transformation of CO2 into chemicals with high additional value is...

scholarly journals Heterogeneous conversion of CO2 into cyclic carbonates at ambient pressure catalyzed by ionothermal-derived meso-macroporous hierarchical poly(ionic liquid)s

2015 ◽  
Vol 6 (12) ◽  
pp. 6916-6924 ◽  
Author(s):  
Xiaochen Wang ◽  
Yu Zhou ◽  
Zengjing Guo ◽  
Guojian Chen ◽  
Jing Li ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ambient Pressure ◽  
Cyclic Carbonates ◽  
Excellent Activity ◽  
Poly Ionic Liquid

Meso-macroporous hierarchical poly(ionic liquid)s are ionothermally synthesized through self-polymerization of the new divinylimidazole IL, exhibiting enhanced CO2 capture and excellent activity in the cycloaddition of CO2 to epoxides.

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