scholarly journals Chitosan/wood sawdust/magnetite composite membranes for the photodegradation of agrochemicals in water

2022 ◽  
Vol 10 (1) ◽  
pp. 106967
Author(s):  
Maurício José Paz ◽  
Tainara Vieira ◽  
Heveline Enzweiler ◽  
Alexandre Tadeu Paulino
2019 ◽  
Vol 30 (11) ◽  
pp. 2802-2818 ◽  
Author(s):  
Hamed Azizi Namaghi ◽  
Ali Haghighi Asl ◽  
Mahdi Pourafshari Chenar ◽  
Mehrdad Hesampour ◽  
Arto Pihlajamäki ◽  
...  

Author(s):  
Liubov I. Kravets ◽  
Maxim A. Yarmolenko ◽  
Alexander A. Rogachev ◽  
Radmir V. Gainutdinov ◽  
Vladimir A. Altynov ◽  
...  

2017 ◽  
Vol 68 (2) ◽  
pp. 203-209
Author(s):  
Hussam Nadum Abdalraheem Al Ani ◽  
Anca Maria Cimbru ◽  
Corneliu Trisca-Rusu ◽  
Szidonia Katalin Tanczos ◽  
Adriana Cuciureanu ◽  
...  

This paper illustrates the possibility of producing iono-molecular separations using ionic colloidal ultrafiltration membrane of polysulfone synthetic solutions of cupric ions and nitro phenols through ultrafiltration assisted by polymeric nanoparticle composites based on polysulfone. In the present work, in order to reduce the operating pressure and increase the flow of water we are using the process of ultrafiltration through a polysulfone membrane in N-methylpyrrolidone 10% prepared by coagulation in isopropanol. The nanoparticles needed in colloidal ultrafiltration had been obtained through the immersion technique of precipitation of a solution of 5% PSf in N-methyl pyrrolidone containing 3% aniline in lower alcohols: methanol, ethanol, and isopropanol, followed by the oxidation of the remaining aniline in a solution of 10% hydrochloric acid and ammonium persulfate. The Nanoparticles of polysulfone (NP-PSf) and The three obtained variants of nanoparticles composites (NP-PSf-PANI) were morphologically (SEM) and (AFM), structurally and compositionally (FTIR) characterized and the results show that nanoparticles polysulfone have a much lower range than the composites. The Possibility of copper complexation by both nitrophenols, and by nanoparticle surface probably lead to the formation of more stable aggregates in the supply, which can sufficiently justify the increased retention. The Retentions of the chemical species in question use in all the tests made the same series:R NP-PSf-PANI-M] R NP-PSf-PANI-E] R NP-PSf-PANI-P] R NP-PSf


2018 ◽  
Vol 69 (7) ◽  
pp. 1603-1607
Author(s):  
Ion Spiridon Din ◽  
Anca Maria Cimbru ◽  
Abbas Abdul Kadhim Klaif Rikabi ◽  
Szidonia Katalin Tanczos ◽  
Simona Ticu (Cotorcea) ◽  
...  

The importance of removing and / or separating nitro phenols from aqueous solutions through membranes is substantiated by the multitude of recent research in the field, which broadly justifies both the economic and ecological reasons of such an approach. The present paper outlines the results of the transfer of nitro phenols through a membrane system made up of PPET impregnated polypropylene capillaries (PP) impregnated with sulfonate polyetheretherketone (SPEEK). The experiments were carried out in a PP-SPEEK capillary membrane module, with a useful size of 1 m2. Determinations made by using a 4 L / min flow rate source at a 5 mg / l nitrophenol concentration and pH 5 or pH 7, and the pH 12 receiving phase and a flow rate of 0.3 L / min, revealed that o- and p-nitrophenol were transferred much faster than m-nitrophenol (the flux is nearly double); the source phase of the system is concentrated in m-nitrophenol, and the receptor phase in o- and p-nitro phenols; the transfer data correlates with the higher water solubility of m-nitrophenol; mono nitro phenols transfer much faster than di nitrophenol, but both the mono and di nitrophenol streams decrease over time; after 4-5 hours of work, the mono nitrophenol concentration triples in the receiving phase, while the 2,4-dinitrophenol concentration doubles in the source phase.


2019 ◽  
Author(s):  
Sameh Elsaidi ◽  
Surendar Venna ◽  
Mona H. Mohamed ◽  
Michael Gipple ◽  
David Hopkinson

2020 ◽  
Vol 16 (7) ◽  
pp. 880-892
Author(s):  
Şerife Parlayıcı ◽  
Kübra Tuna Sezer ◽  
Erol Pehlivan

Background: In this work, Cr (VI) adsorption on nano-ZrO2๏TiO2 impregnated orange wood sawdust (Zr๏Ti/OWS) and nano-ZrO2๏TiO2 impregnated peach stone shell (Zr๏Ti/PSS) was investigated by applying different adsorption parameters such as Cr (VI) concentrations, contact time, adsorbent dose, and pH for all adsorbents. Methods: The adsorbents were characterized by SEM and FT-IR. The equilibrium status was achieved after 120 min of contact time and optimum pH value around 2 were determined for Cr (VI) adsorption. Adsorption data in the equilibrium is well-assembled by the Langmuir model during the adsorption process. Results: Langmuir isotherm model showed a maximum adsorption value of OWS: 21.65 mg/g and Zr๏Ti/OWS: 27.25 mg/g. The same isotherm displayed a maximum adsorption value of PSS: 17.64 mg/g, and Zr๏Ti/PSS: 31.15 mg/g. Pseudo-second-order kinetic models (R2=0.99) were found to be the best models for describing the Cr (VI) adsorption reactions. Conclusıon: Thermodynamic parameters such as changes in ΔG°, ΔH°, and ΔS° have been estimated, and the process was found to be spontaneous.


2019 ◽  
Vol 696 ◽  
pp. 133883 ◽  
Author(s):  
Min Tang ◽  
Deyin Hou ◽  
Chunli Ding ◽  
Kunpeng Wang ◽  
Dewu Wang ◽  
...  

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