A new strategy for obtaining highly concentrated phosphorus recovery solution in biofilm phosphorus recovery process

2022 ◽  
Vol 112 ◽  
pp. 366-375
Author(s):  
Wanjing Yang ◽  
Jie Shan ◽  
Yang Pan ◽  
Zhen Bi ◽  
Yong Huang ◽  
...  
Author(s):  
Haiming ZOU ◽  
Xiwu LU ◽  
Ting LI

An excessive discharge of phosphorus from wastewater to water bodies may potentially contribute to eutrophication. On the other hand, mineral phosphorus resources will be depleted in the near future, because of difficulty to automatically recycle from water to land, unlike nitrogen. A new process for nutrients removal coupled with phosphorus recovery was proposed in this study by combining biological nutrients removal (BNR) with induced crystallization (IC), BNR-IC for short later, differently from conventional phosphorus recovery process. Our results showed that the BNR-IC system can maintain not only high and stable carbon, nitrogen and phosphorus removal efficiencies, all presenting above 90%, but also good phosphorus recovery performance from synthetic domestic wastewater, displaying about 70.2% of phosphorus recovery rate. When the COD, TN, NH4–N and P concentrations of 250 mg L−1, 42 mg L−1, 40 mg L−1, and 10 mg L−1, respectively were given in the influent, a stable removal efficiencies of 92.5% COD, 78.6% TN, 85.9% NH4–N and 95.2% P were obtained for the BNR-IC process and correspondingly the COD, TN, NH4–N and P concentrations of 18.75 mg L−1, 8.99 mg L−1, 5.64 mg L−1, 0.42 mg L−1 were monitored in the effluent, meeting the Chinese National Class I (grade A) Sewage Discharge Standard. Analyses of SEM and EDS, moreover, also demonstrated that the surface of seed crystal (calcite used here) was completely covered by hydroxyl calcium phosphate (HAP) produced during the induced crystallization process to recover phosphorus. Although our study involved only a small-scale trial, the proposed BNR-IC process here may be a promising technology, and can potentially aid in improvement of the effluent quality from WWTP and in recycle of mineral phosphorus resources when applied to practice.


2015 ◽  
Vol 71 (4) ◽  
pp. 487-494 ◽  
Author(s):  
A. Marchi ◽  
S. Geerts ◽  
M. Weemaes ◽  
S. Wim ◽  
V. Christine

To date, phosphorus recovery as struvite in wastewater treatment plants has been mainly implemented on water phases resulting from dewatering processes of the sludge line. However, it is possible to recover struvite directly from sludge phases. Besides minimising the return loads of phosphorus from the sludge line to the water line, placing such a process within the sludge line is claimed to offer advantages such as a higher recovery potential, enhanced dewaterability of the treated sludge, and reduced speed of scaling in pipes and dewatering devices. In the wastewater treatment plant at Leuven (Belgium), a full-scale struvite recovery process from digested sludge has been tested for 1 year. Several monitoring campaigns and experiments provided indications of the efficiency of the process for recovery. The load of phosphorus from the sludge line returning to the water line as centrate accounted for 15% of the P-load of the plant in the reference situation. Data indicated that the process divides this phosphorus load by two. An improved dewaterability of 1.5% of dry solids content was achieved, provided a proper tuning of the installation. Quality analyses showed that the formed struvite was quite pure.


2008 ◽  
Vol 57 (3) ◽  
pp. 451-456 ◽  
Author(s):  
K. Shimamura ◽  
H. Ishikawa ◽  
A. Mizuoka ◽  
I. Hirasawa

Removal and recovery of phosphorus from sewage in form of MAP (magnesium ammonium phosphate) have attracted attention from the viewpoint of eutrophication prevention and phosphorus resource recovery as well as scaling prevention inside digestion tanks. In this work, phosphorus recovery demonstration tests were conducted in a 50 m3/d facility having a complete mixing type reactor and a liquid cyclone. Digested sludge, having 690 mg/L T-P and 268 mg/L PO4-P, was used as test material. The T-P and PO4-P of treated sludge were 464 mg/L and 20 mg/L achieving a T-P recovery efficiency of 33% and a PO4-P crystallization ratio of 93%. The reacted phosphorus did not become fine crystals and the recovered MAP particles were found to be valuable as a fertilizer. A case study in applying this phosphorus recovery process for treatment of sludge from an anaerobic-aerobic process of a 21,000 m3/d sewage system, showed that 30% of phosphorus concentration can be reduced in the final effluent, recovering 315 kg/d as MAP.


2011 ◽  
Vol 6 (4) ◽  
Author(s):  
Kazuaki Shimamura ◽  
Tateki Kurosawa

A novel phosphorus recovery process enabling an effective reuse of recovered phosphorus as a resource has been developed. Three processes, which match the characteristics (sewage component, concentration and flow rate, etc.) of the waste water or the sludge generated form sewage treatment, are introduced here. Verification tests carried out using a crystallization of magnesium ammonium phosphate revealed a phosphorus crystallization exceeding 85%. Moreover, these tests show that the recovered phosphorus can be reused as a fertilizer. Another verification test carried out using a crystallization of hydroxylapatite revealed that the phosphorus concentration is reduced to a few milligrams per liter. In addition it is found that the recovered hydroxylapatite can be reused as a phosphorus ore. Each of the three processes is revealed to contribute to prevention of water contamination, as well as the recovery of phosphorus as a resource.


2006 ◽  
Vol 1 (4) ◽  
Author(s):  
K. Gethke ◽  
H. Herbst ◽  
D. Montag ◽  
D. Bruszies ◽  
J. Pinnekamp

A process to recover nutrients from human urine was tested at the Institute of Environmental Engineering (ISA) of RWTH Aachen University. Before testing the recovery process the urine was stored and the decomposition processes during this period were observed. Throughout the storage the pH value and the concentration of ammonia nitrogen increased, the concentration of phosphate phosphorus decreased. These variances can be speed up by addition of urease. The recovery process is easy to handle and approx. 99% of the load of phosphate phosphorus was eliminated and transferred into the product. Analysing the product indicators for struvite could be identified. The final step of the process is the stripping of the remaining ammonia-nitrogen by air followed by a gas washing


2019 ◽  
Vol 79 (9) ◽  
pp. 1777-1789 ◽  
Author(s):  
Sina Shaddel ◽  
Seniz Ucar ◽  
Jens-Petter Andreassen ◽  
Stein W. Østerhus

Abstract The enhanced biological phosphorus removal process makes the phosphorus recovery feasible from the dewatering streams of biological sludge. The physicochemical properties of these sidestreams, as an input to a crystallizer, are different before and after anaerobic digestion. In this study, phosphorus recovery by calcium phosphate is proposed for pre-digestion sidestreams and by struvite precipitation for post-digestion sidestreams. The thermodynamic modeling followed by experimental tests was performed to evaluate the recovery efficiency and product properties of struvite and calcium phosphates. The variations in phosphorus recovery potential, reaction kinetics and particle size distribution emphasize the importance of the adjustment of initial supersaturation and pH of the reaction. The optimum pH, considering the economics and recovery efficiency, for both calcium phosphate and struvite precipitation was found to be pH = 8.5, whereas further increase of pH will not improve the overall efficiency of the process. In the case of calcium phosphate precipitation, it was shown that possible phase transformations should be considered and controlled as they affect both process efficiency and product properties. The economic evaluation indicated that the optimized operational condition should be determined for the phosphorus recovery process and that chemical costs for the production of calcium phosphates is lower than for struvite.


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