Identification of unknown disinfection byproducts in drinking water produced from Taihu Lake source water

2022 ◽  
Vol 113 ◽  
pp. 1-11
Author(s):  
Jiabao Li ◽  
Haifeng Zhang ◽  
Juan Wang ◽  
Zhiyong Yu ◽  
Hongyan Li ◽  
...  
2020 ◽  
Author(s):  
John Weatherill ◽  
Elena Fernandez-Pascual ◽  
Jean O'Dwyer ◽  
Elizabeth Gilchrist ◽  
Simon Harrison ◽  
...  

<p>Ireland has a far greater number of regulatory exceedances for trihalomethanes (THMs) in public water supplies than the next highest European Union member state. In Ireland, 82% of public water supplies originate from surface water catchments which require disinfection to inactivate pathogens and prevent the spread of waterborne diseases. Since the 1970s, it has been known that the use of chlorine for disinfection leads to the formation of potentially harmful disinfection byproducts (DBPs) of which some are suspected carcinogens. THMs are one prominent class of at least 700 potentially harmful disinfection byproducts (DBPs) produced after chlorination of dissolved organic matter (DOM) present in source water which is not removed prior to disinfection.</p><p>We introduce a new research project, funded by the Irish Environmental Protection Agency entitled PRODOM: PRoactive Optical monitoring of catchment Dissolved Organic Matter for drinking water source protection. The overall aim of the research is to develop an integrated catchment-level understanding of the spatiotemporal dynamics of DOM precursors and associated DBP formation risk. The project will explore the relationship between optically-active DOM precursors and laboratory formation potentials for key DBPs including emerging classes of potentially more harmful nitrogenous DBPs. Through high-resolution spatial sampling we will develop geospatial DBP formation risk maps and identify risk-driving point and diffuse precursor sources. We will evaluate the potential of state-of-the-art UV fluorescence sensor technology to act as an early warning tool for proactive management of source water at sub-catchment scale. Using high-frequency time series monitoring of fluorescent precursors, we will identify high-risk periods in the catchment hydrograph and evaluate critical precursor sources and pathways to inform a series of catchment management measures designed to reduce DBP formation risk. </p>


2019 ◽  
Author(s):  
Luke Skala ◽  
Anna Yang ◽  
Max Justin Klemes ◽  
Leilei Xiao ◽  
William Dichtel

<p>Executive summary: Porous resorcinarene-containing polymers are used to remove halomethane disinfection byproducts and 1,4-dioxane from water.<br></p><p><br></p><p>Disinfection byproducts such as trihalomethanes are some of the most common micropollutants found in drinking water. Trihalomethanes are formed upon chlorination of natural organic matter (NOM) found in many drinking water sources. Municipalities that produce drinking water from surface water sources struggle to remain below regulatory limits for CHCl<sub>3</sub> and other trihalomethanes (80 mg L<sup>–1</sup> in the United States). Inspired by molecular CHCl<sub>3</sub>⊂cavitand host-guest complexes, we designed a porous polymer comprised of resorcinarene receptors. These materials show higher affinity for halomethanes than a specialty activated carbon used for trihalomethane removal. The cavitand polymers show similar removal kinetics as activated carbon and have high capacity (49 mg g<sup>–1</sup> of CHCl<sub>3</sub>). Furthermore, these materials maintain their performance in real drinking water and can be thermally regenerated under mild conditions. Cavitand polymers also outperform activated carbon in their adsorption of 1,4-dioxane, which is difficult to remove and contaminates many public water sources. These materials show promise for removing toxic organic micropollutants and further demonstrate the value of using supramolecular chemistry to design novel absorbents for water purification.<br></p>


2018 ◽  
Vol 3 (1) ◽  
Author(s):  
Nusa Idaman Said

Water disinfection means the removal, deactivation or killing of pathogenic microorganisms. Microorganisms are destroyed or deactivated, resulting in termination of growth and reproduction. When microorganisms are not removed from drinking water, drinking water usage will cause people to fall ill. Chemical inactivation of microbiological contamination in natural or untreated water is usually one of the final steps to reduce pathogenic microorganisms in drinking water. Combinations of water purification steps (oxidation, coagulation, settling, disinfection, and filtration) cause (drinking) water to be safe after production. As an extra measure many countries apply a second disinfection step at the end of the water purification process, in order to protect the water from microbiological contamination in the water distribution system. Usually one uses a different kind of disinfectant from the one earlier in the process, during this disinfection process. The secondary disinfection makes sure that bacteria will not multiply in the water during distribution. This paper describes several technique of disinfection process for drinking water treatment. Disinfection can be attained by means of physical or chemical disinfectants. The agents also remove organic contaminants from water, which serve as nutrients or shelters for microorganisms. Disinfectants should not only kill microorganisms. Disinfectants must also have a residual effect, which means that they remain active in the water after disinfection. For chemical disinfection of water the following disinfectants can be used such as Chlorine (Cl2),  Hypo chlorite (OCl-), Chloramines, Chlorine dioxide (ClO2), Ozone (O3), Hydrogen peroxide etch. For physical disinfection of water the following disinfectants can be used is Ultraviolet light (UV). Every technique has its specific advantages and and disadvantages its own application area sucs as environmentally friendly, disinfection byproducts, effectivity, investment, operational costs etc. Kata Kunci : Disinfeksi, bakteria, virus, air minum, khlor, hip khlorit, khloramine, khlor dioksida, ozon, UV.


2006 ◽  
Vol 6 (2) ◽  
pp. 125-130
Author(s):  
C.-H. Hung ◽  
K.-H. Tsai ◽  
Y.-K. Su ◽  
C.-M. Liang ◽  
M.-H. Su ◽  
...  

Due to the extensive application of artificial nitrogen-based fertilizers on land, groundwater from the central part of Taiwan faces problems of increasing concentrations of nitrate, which were measured to be well above 30 mg/L all year round. For meeting the 10 mg/L nitrate standard, optimal operations for a heterotrophic denitrification pilot plant designed for drinking water treatment was investigated. Ethanol and phosphate were added for bacteria growing on anthracite to convert nitrate to nitrogen gas. Results showed that presence of high dissolved oxygen (around 4 mg/L) in the source water did not have a significantly negative effect on nitrogen removal. When operated under a C/N ratio of 1.88, which was recommended in the literature, nitrate removal efficiency was measured to be around 70%, sometimes up to 90%. However, the reactor often underwent severe clogging problems. When operated under C/N ratio of 1.0, denitrification efficiency decreased significantly to 30%. Finally, when operated under C/N ratio of 1.5, the nitrate content of the influent was almost completely reduced at the first one-third part of the bioreactor with an overall removal efficiency of 89–91%. Another advantage for operating with a C/N ratio of 1.5 is that only one-third of the biosolids was produced compared to a C/N value of 1.88.


2018 ◽  
Vol 16 (2) ◽  
pp. 84
Author(s):  
G A Blagodatsky ◽  
A A Bass ◽  
M M Gorokhov ◽  
D S Ponomarev

Работа посвящена системному анализу данных показателей исходной воды при производстве питьевой воды в системе центрального водоснабжения крупного населенного пункта. На сегодняшний день на фоне увеличивающегося негативного антропогенного воздействия на окружающую среду наблюдается ухудшение состояния многих источников питьевого водоснабжения в широком спектре показателей, в частности, таких как органолептические свойства воды. Как следствие, возникает проблема и для питьевой воды. В работе приводится процесс подготовки данных о параметрах исходной воды, забираемой из водохранилища, которые ежемесячно (с 2002 по 2014 год) учитывались на предприятии при дезодорации воды. Приведенные параметры оказывают существенное влияние на органолептические свойства конечной воды. Подготовка данных для анализа проводится методом главных компонент К. Пирсона. Данные, полученные в пространстве R9, переводятся в пространство меньшей размерности R3. Понижение размерности позволяет снизить автокорреляцию между компонентами. Отбор компонент в пространство R3 проводится по правилу Парето. В пространстве R3 методом сферической кластеризации данных «Форель» с постоянным радиусом группировки проводится кластеризация. Приводится пошаговое визуальное представление алгоритма кластеризации в пространстве R3. В работе показано, что в данных показателях качества исходной воды имеются кластеры. Проводится корреляционно-регрессионный анализ данных, представленных в главных компонентах. Строятся регрессионные зависимости показателей органолептических свойств от главных компонент из пространства R3.


Author(s):  
Jordan Roszell ◽  
Po-Shun Chan ◽  
Brian Petri ◽  
Ted Mao ◽  
Kathleen Nolan ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (4) ◽  
pp. 521
Author(s):  
Fernando J. Beltrán ◽  
Ana Rey ◽  
Olga Gimeno

Formation of disinfection byproducts (DBPs) in drinking water treatment (DWT) as a result of pathogen removal has always been an issue of special attention in the preparation of safe water. DBPs are formed by the action of oxidant-disinfectant chemicals, mainly chlorine derivatives (chlorine, hypochlorous acid, chloramines, etc.), that react with natural organic matter (NOM), mainly humic substances. DBPs are usually refractory to oxidation, mainly due to the presence of halogen compounds so that advanced oxidation processes (AOPs) are a recommended option to deal with their removal. In this work, the application of catalytic ozonation processes (with and without the simultaneous presence of radiation), moderately recent AOPs, for the removal of humic substances (NOM), also called DBPs precursors, and DBPs themselves is reviewed. First, a short history about the use of disinfectants in DWT, DBPs formation discovery and alternative oxidants used is presented. Then, sections are dedicated to conventional AOPs applied to remove DBPs and their precursors to finalize with the description of principal research achievements found in the literature about application of catalytic ozonation processes. In this sense, aspects such as operating conditions, reactors used, radiation sources applied in their case, kinetics and mechanisms are reviewed.


1983 ◽  
Vol 15 (6-7) ◽  
pp. 211-220 ◽  
Author(s):  
G Izaguirre ◽  
C J Hwang ◽  
S W Krasner ◽  
M J McGuire

Two Oscillatoria strains have been isolated from three different water supply systems in California that have experienced taste and odor problems in their drinking water. The algae were obtained from sediment samples and rock scrapings from source-water reservoirs. Unialgal cultures, free of actinomycetes, were purged using the closed-loop stripping analysis method, and the resulting extracts were analyzed by gas chromatography and mass spectrometry. The organisms, Oscillatoriacurviceps and O.tenuis variant levis Gardner, yielded 2-methylisoborneol (MIB) at 60–150 µg/l. In both instances, MIB had previously been identified in the sediment samples from which the organisms were isolated. O.curviceps was implicated in a taste and odor episode involving MIB in a major reservoir during two consecutive summers.


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