Knitting a sweater with UV-induced in situ polymerization of poly(pyrrole-co-citral nitrile) on Ni-rich layer oxide cathode materials for lithium ion batteries

2022 ◽  
Vol 520 ◽  
pp. 230768
Author(s):  
Kaiji Lin ◽  
Shaodian Yang ◽  
Zhicong Shi ◽  
Qinglu Fan ◽  
Zhiling Liu ◽  
...  
2017 ◽  
Vol 8 (11) ◽  
pp. 1702514 ◽  
Author(s):  
Aram Choi ◽  
Jungwoo Lim ◽  
Hyung-Jin Kim ◽  
Sung Chul Jung ◽  
Hyung-Woo Lim ◽  
...  

Nanoscale ◽  
2021 ◽  
Author(s):  
Dongdong Wang ◽  
Qizhang Yan ◽  
Mingqian Li ◽  
Hongpeng Gao ◽  
Jianhua Tian ◽  
...  

Nickel (Ni)-rich layered oxides such as LiNi0.6Co0.2Mn0.2O2 (NCM622) represent one of the most promising candidates for the next-generation high-energy lithium-ion batteries (LIBs). However, the pristine Ni-rich cathode materials usually suffer...


2013 ◽  
Vol 779-780 ◽  
pp. 52-55
Author(s):  
Guang Jin Zhao ◽  
Wen Long Wu ◽  
Yang Guo

Following during development of electric vehicles and other modern-life appliances, numerous lithium-ion batteries are fabricated and used every year, and their consumption is constantly expanding. However, the battery life of the lithium-ion batteries is about 3 to 5 years, and there are some hazardous and noxious substances in spent lithium-ion batteries. Therefore, it is necessary to recycling these spent batteries with some resourceful and environment friendly technology. In this work, we propose a novel technology of resourceful disposing and utilizing oxide cathode materials from spent power lithium-ion batteries, which is using the recovered compounds from spent lithium-ion batteries to capture carbon dioxide from fossil fuel plant. The detailed technical routes of laboratory scale test and bench scale test are also given in the work.


2015 ◽  
Vol 17 (47) ◽  
pp. 32033-32043 ◽  
Author(s):  
Jing Wang ◽  
Yangyang Yu ◽  
Bing Li ◽  
Tao Fu ◽  
Dongquan Xie ◽  
...  

The Li2TiO3-coated LiNi0.5Co0.2Mn0.3O2 (LTO@NCM) cathode materials are synthesized via an in situ coprecipitation method to improve the electrochemical performance of NCM.


Materials ◽  
2019 ◽  
Vol 13 (1) ◽  
pp. 40 ◽  
Author(s):  
Jun Liu ◽  
Qiming Liu ◽  
Huali Zhu ◽  
Feng Lin ◽  
Yan Ji ◽  
...  

Li-rich layered oxide cathode materials have become one of the most promising cathode materials for high specific energy lithium-ion batteries owning to its high theoretical specific capacity, low cost, high operating voltage and environmental friendliness. Yet they suffer from severe capacity and voltage attenuation during prolong cycling, which blocks their commercial application. To clarify these causes, we synthesize Li1.5Mn0.55Ni0.4Co0.05O2.5 (Li1.2Mn0.44Ni0.32Co0.04O2) with high-nickel-content cathode material by a solid-sate complexation method, and it manifests a lot slower capacity and voltage attenuation during prolong cycling compared to Li1.5Mn0.66Ni0.17Co0.17O2.5 (Li1.2Mn0.54Ni0.13Co0.13O2) and Li1.5Mn0.65Ni0.25Co0.1O2.5 (Li1.2Mn0.52Ni0.2Co0.08O2) cathode materials. The capacity retention at 1 C after 100 cycles reaches to 87.5% and the voltage attenuation after 100 cycles is only 0.460 V. Combining X-ray diffraction (XRD), scanning electron microscope (SEM), and transmission electron microscopy (TEM), it indicates that increasing the nickel content not only stabilizes the structure but also alleviates the attenuation of capacity and voltage. Therefore, it provides a new idea for designing of Li-rich layered oxide cathode materials that suppress voltage and capacity attenuation.


2019 ◽  
Vol 7 (20) ◽  
pp. 12593-12603 ◽  
Author(s):  
Münir M. Besli ◽  
Alpesh Khushalchand Shukla ◽  
Chenxi Wei ◽  
Michael Metzger ◽  
Judith Alvarado ◽  
...  

The structural integrity of layered Ni-rich oxide cathode materials is one of the most essential factors that critically affect the performance and reliability of lithium-ion batteries.


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