Structure elucidation by Sparkle/RM1, and solution behavior of lanthanideIII complexes: NMR, 4f‒4f absorption spectra and Photoluminescent properties

AbstractThe dual laser-produced plasma technique for the study of ionic absorption spectra has been developed by the use of two Q-switched ruby lasers to enable independent generation of the absorbing and back-lighting plasmas. Optical pulse handling is used in the coupling cicuits to enable reproducible pulse delays from 250 nsec. to 10 msec, to be achieved. At delay times > 700 nsec. spectra of essentially pure neutral species are observed. The technique is valuable, not only for obtaining the neutral spectra of highly refractory and/or corrosive materials but also for studying behaviour of ionic species as a function of time. Typical spectra are shown in Fig. 1.

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XUV Absorption Spectra of Carbon Ions

International Astronomical Union Colloquium ◽

10.1017/s0252921100107444 ◽

1988 ◽

Vol 102 ◽

pp. 71-73

Author(s):

E. Jannitti ◽

P. Nicolosi ◽

G. Tondello

Keyword(s):

Absorption Spectra ◽

Cross Section ◽

Theoretical Calculations ◽

Photoionization Cross Section ◽

Carbon Ions

AbstractThe photoabsorption spectra of the carbon ions have been obtained by using two laser-produced plasmas. The photoionization cross-section of the CV has been absolutely measured and the value at threshold, σ=(4.7±0.5) × 10−19cm2, as well as its behaviour at higher energies agrees quite well with the theoretical calculations.

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Optimizing NMR Methods for Structure Elucidation

10.1039/9781788010498 ◽

2018 ◽

Keyword(s):

Structure Elucidation ◽

Nmr Methods

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Water soluble palladium(ii) and platinum(ii) acyclic diaminocarbene complexes: solution behavior, DNA binding, and antiproliferative activity

New Journal of Chemistry ◽

10.1039/d0nj00060d ◽

2020 ◽

Vol 44 (15) ◽

pp. 5762-5773 ◽

Cited By ~ 1

Author(s):

Tatiyana V. Serebryanskaya ◽

Mikhail A. Kinzhalov ◽

Vladimir Bakulev ◽

Georgii Alekseev ◽

Anastasiya Andreeva ◽

...

Keyword(s):

Dna Binding ◽

Antiproliferative Activity ◽

Water Soluble ◽

Solution Behavior ◽

Antitumor Potential ◽

Acyclic Diaminocarbene

Water soluble Pd(ii) and Pt(ii)–ADC species synthesized via the metal-mediated coupling of isocyanides and 1,2-diaminobenzene have demonstrated antitumor potential.

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