Construction of novel benzoxazine-linked covalent organic framework with antimicrobial activity via postsynthetic cyclization

2022 ◽  
Vol 23 ◽  
pp. 100707
Author(s):  
Q. Ma ◽  
X. Liu ◽  
H. Wang ◽  
Q. Zhuang ◽  
J. Qian
Nanoscale ◽  
2020 ◽  
Vol 12 (30) ◽  
pp. 16136-16142
Author(s):  
Xuan Wang ◽  
Ming-Jie Dong ◽  
Chuan-De Wu

An effective strategy to incorporate accessible metalloporphyrin photoactive sites into 2D COFs by establishing a 3D local connection for highly efficient photocatalysis was developed.


2020 ◽  
Author(s):  
Junxia Ren ◽  
Yaozu Liu ◽  
Xin Zhu ◽  
Yangyang Pan ◽  
Yujie Wang ◽  
...  

<p><a></a><a></a><a></a><a></a><a></a><a></a><a></a><a>The development of highly-sensitive recognition of </a><a></a><a></a><a></a><a></a><a>hazardous </a>chemicals, such as volatile organic compounds (VOCs) and polycyclic aromatic hydrocarbons (PAHs), is of significant importance because of their widespread social concerns related to environment and human health. Here, we report a three-dimensional (3D) covalent organic framework (COF, termed JUC-555) bearing tetraphenylethylene (TPE) side chains as an aggregation-induced emission (AIE) fluorescence probe for sensitive molecular recognition.<a></a><a> </a>Due to the rotational restriction of TPE rotors in highly interpenetrated framework after inclusion of dimethylformamide (DMF), JUC-555 shows impressive AIE-based strong fluorescence. Meanwhile, owing to the large pore size (11.4 Å) and suitable intermolecular distance of aligned TPE (7.2 Å) in JUC-555, the obtained material demonstrates an excellent performance in the molecular recognition of hazardous chemicals, e.g., nitroaromatic explosives, PAHs, and even thiophene compounds, via a fluorescent quenching mechanism. The quenching constant (<i>K</i><sub>SV</sub>) is two orders of magnitude better than those of other fluorescence-based porous materials reported to date. This research thus opens 3D functionalized COFs as a promising identification tool for environmentally hazardous substances.</p>


2021 ◽  
Vol 2 (7) ◽  
pp. 100495
Author(s):  
Chun-Te Kuo ◽  
Yubing Lu ◽  
Pezhman Arab ◽  
K. Shamara Weeraratne ◽  
Hani El-Kaderi ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (18) ◽  
pp. 10512-10523
Author(s):  
Sanan Song ◽  
Yue Shi ◽  
Ning Liu ◽  
Fengqi Liu

Volatile nuclear wastes, such as iodine, have received worldwide attention because it poses risks to public safety and pollutes the environment.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Pengcheng Zhang ◽  
Sifan Chen ◽  
Changjia Zhu ◽  
Linxiao Hou ◽  
Weipeng Xian ◽  
...  

AbstractThermal sensation, which is the conversion of a temperature stimulus into a biological response, is the basis of the fundamental physiological processes that occur ubiquitously in all organisms from bacteria to mammals. Significant efforts have been devoted to fabricating artificial membranes that can mimic the delicate functions of nature; however, the design of a bionic thermometer remains in its infancy. Herein, we report a nanofluidic membrane based on an ionic covalent organic framework (COF) that is capable of intelligently monitoring temperature variations and expressing it in the form of continuous potential differences. The high density of the charged sites present in the sub-nanochannels renders superior permselectivity to the resulting nanofluidic system, leading to a high thermosensation sensitivity of 1.27 mV K−1, thereby outperforming any known natural system. The potential applicability of the developed system is illustrated by its excellent tolerance toward a broad range of salt concentrations, wide working temperatures, synchronous response to temperature stimulation, and long-term ultrastability. Therefore, our study pioneers a way to explore COFs for mimicking the sophisticated signaling system observed in the nature.


Author(s):  
Dongyang Zhu ◽  
Yifan Zhu ◽  
Qianqian Yan ◽  
Morgan Barnes ◽  
Fangxin Liu ◽  
...  

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