Ultrafast carrier dynamics in high-performance α-bis-PCBM doped organic-inorganic hybrid perovskite solar cell

2019 ◽  
Vol 75 ◽  
pp. 105384 ◽  
Author(s):  
Yifei Tang ◽  
Meng Li ◽  
Yizhu Zhang ◽  
Zhaokui Wang ◽  
Xinya Hou ◽  
...  
RSC Advances ◽  
2017 ◽  
Vol 7 (68) ◽  
pp. 42973-42978 ◽  
Author(s):  
Yanqing Yao ◽  
Gang Wang ◽  
Fei Wu ◽  
Debei Liu ◽  
Chunyan Lin ◽  
...  

The light beam induced current (LBIC) method was adopted to nondestructively map the photoresponse of real planar organic–inorganic hybrid perovskite solar cells (PSCs).


2019 ◽  
Vol 53 (9) ◽  
pp. 095103
Author(s):  
Hui Zhang ◽  
Xinke Wang ◽  
YanSheng Sun ◽  
Peng Han ◽  
JingPeng Ren ◽  
...  

Solar Energy ◽  
2021 ◽  
Vol 220 ◽  
pp. 258-268
Author(s):  
Harish Singh ◽  
Pritam Dey ◽  
Shovon Chatterjee ◽  
Pratik Sen ◽  
Tanmoy Maiti

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1751
Author(s):  
Inga Ermanova ◽  
Narges Yaghoobi Nia ◽  
Enrico Lamanna ◽  
Elisabetta Di Bartolomeo ◽  
Evgeny Kolesnikov ◽  
...  

In this paper, we demonstrate the high potentialities of pristine single-cation and mixed cation/anion perovskite solar cells (PSC) fabricated by sequential method deposition in p-i-n planar architecture (ITO/NiOX/Perovskite/PCBM/BCP/Ag) in ambient conditions. We applied the crystal engineering approach for perovskite deposition to control the quality and crystallinity of the light-harvesting film. The formation of a full converted and uniform perovskite absorber layer from poriferous pre-film on a planar hole transporting layer (HTL) is one of the crucial factors for the fabrication of high-performance PSCs. We show that the in-air sequential deposited MAPbI3-based PSCs on planar nickel oxide (NiOX) permitted to obtain a Power Conversion Efficiency (PCE) exceeding 14% while the (FA,MA,Cs)Pb(I,Br)3-based PSC achieved 15.6%. In this paper we also compared the influence of transporting layers on the cell performance by testing material depositions quantity and thickness (for hole transporting layer), and conditions of deposition processes (for electron transporting layer). Moreover, we optimized second step of perovskite deposition by varying the dipping time of substrates into the MA(I,Br) solution. We have shown that the layer by layer deposition of the NiOx is the key point to improve the efficiency for inverted perovskite solar cell out of glove-box using sequential deposition method, increasing the relative efficiency of +26% with respect to reference cells.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Xuejian Ma ◽  
Fei Zhang ◽  
Zhaodong Chu ◽  
Ji Hao ◽  
Xihan Chen ◽  
...  

AbstractThe outstanding performance of organic-inorganic metal trihalide solar cells benefits from the exceptional photo-physical properties of both electrons and holes in the material. Here, we directly probe the free-carrier dynamics in Cs-doped FAPbI3 thin films by spatiotemporal photoconductivity imaging. Using charge transport layers to selectively quench one type of carriers, we show that the two relaxation times on the order of 1 μs and 10 μs correspond to the lifetimes of electrons and holes in FACsPbI3, respectively. Strikingly, the diffusion mapping indicates that the difference in electron/hole lifetimes is largely compensated by their disparate mobility. Consequently, the long diffusion lengths (3~5 μm) of both carriers are comparable to each other, a feature closely related to the unique charge trapping and de-trapping processes in hybrid trihalide perovskites. Our results unveil the origin of superior diffusion dynamics in this material, crucially important for solar-cell applications.


2017 ◽  
Vol 121 (48) ◽  
pp. 27233-27240 ◽  
Author(s):  
Sourav Maiti ◽  
Jayanta Dana ◽  
Yogesh Jadhav ◽  
Tushar Debnath ◽  
Santosh K. Haram ◽  
...  

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