Recyclable-by-design mono-material flexible packaging with high barrier properties realized through graphene hybrid coatings

2022 ◽  
Vol 179 ◽  
pp. 106126
Author(s):  
Marco Guerritore ◽  
Federico Olivieri ◽  
Rachele Castaldo ◽  
Roberto Avolio ◽  
Mariacristina Cocca ◽  
...  
2009 ◽  
Vol 26 (6) ◽  
pp. 1550-1555 ◽  
Author(s):  
Sungkoo Lee ◽  
Kyeong Keun Oh ◽  
Sunyoung Park ◽  
Jun-Seok Kim ◽  
Hyunjoon Kim

2020 ◽  
Vol 147 ◽  
pp. 105788 ◽  
Author(s):  
Xiaowei Meng ◽  
Peng Qi ◽  
Jun Sun ◽  
Hongfei Li ◽  
Sheng Zhang ◽  
...  

2020 ◽  
Vol 44 (11) ◽  
Author(s):  
Luís Marangoni Júnior ◽  
Rosa Maria Vercelino Alves ◽  
Christiane Quartaroli Moreira ◽  
Marcelo Cristianini ◽  
Marisa Padula ◽  
...  

2006 ◽  
Vol 951 ◽  
Author(s):  
Katsunori Nishiura ◽  
Toshihiko Takaki ◽  
Makoto Nakaura

ABSTRACTIt is important to develop flexible transparent polymer films having high gas barrier properties and abrasion resistance because new applications involving transparent polymer films for flat panel displays require these properties. We report on organic-inorganic hybrid coatings of polyvinylalcohol (PVA)/polyacrylicacid (PAA)-silica, which have high gas barrier properties almost equivalent to those achieved by the dry coating process. The hybrid coatings were prepared by the sol-gel reaction of alkoxysilane in a PVA/PAA aqueous solution. In order to obtain transparent coating films, 3-aminopropyltrimethoxysilane (APTMOS) was used as a compatibilizer in the sol-gel reaction of tetramethoxysilane (TMOS). No structure could be seen in the TEM of the cross-sectional coating layer, indicating that polymers and silica were mixed homogeneously. PVA/PAA-silica hybrid coatings were shown to have excellent abrasion resistance based on the ΔHaze index. O2 permeability of PVA/PAA-silica hybrid coatings evaluated by MOCON under the conditions of 23°C, 90% RH was lower than that of PVA/PAA polymer coating, which suggests that silica affects the barrier property of the hybrid coating in humid conditions. Furthermore, O2 permeability decreased as silica content increased in the coatings. Unexpectedly, high gas barrier properties appeared when the silica content exceeded 50 wt%. From the result of element distribution analysis measured by EF-TEM, it was confirmed that phase separation occurred between PVA/PAA and silica on a nanometer scale and silica forms continuous structures, which are considered to suppress O2 permeability.


2020 ◽  
Vol 710 ◽  
pp. 138261 ◽  
Author(s):  
Wolfgang Hering ◽  
Ronny Koecher ◽  
Bjoern S.M. Kretzschmar ◽  
Bernd Gruenler ◽  
Stefan Spange

2011 ◽  
Vol 519 (10) ◽  
pp. 3146-3154 ◽  
Author(s):  
Tommi O. Kääriäinen ◽  
Philipp Maydannik ◽  
David C. Cameron ◽  
Kimmo Lahtinen ◽  
Petri Johansson ◽  
...  

2009 ◽  
Vol 50 (1) ◽  
pp. 144-153 ◽  
Author(s):  
Matteo Minelli ◽  
Maria Grazia De Angelis ◽  
Ferruccio Doghieri ◽  
Marco Rocchetti ◽  
Angelo Montenero

2020 ◽  
Vol 2 (1) ◽  
pp. 24
Author(s):  
Karol Szubert

Wood is one of the most important materials in the construction industry. Because of its organic constitution, it is slowly destroyed by the long-term impacts of water, oxygen and light under atmospheric conditions and, hence, needs to be sufficiently protected. Appropriate protection of wood leads to it having longer life and, hence, a huge reduction in maintenance costs. There are several methods to protect wood, either by its chemical modification or by its surface treatment. Unfortunately, many of the wood preservatives that have been used so far are highly toxic to humans and, hence, much attention has been paid to the development of nontoxic materials/methods for the protection of wood. Recently, several reports have been published on the use of inorganic–organic hybrid coatings for the protection of wood substrates. The sol–gel process to generate hybrid coatings is quite versatile and even allows room temperature deposition of hybrid inorganic–organic films on a wide range of substrates, including wood. Wood surface modification with multifunctional alkoxysilanes by the sol–gel process is one promising method to improve and provide new properties for wood materials. The advantage of the sol–gel process is that it allows deposition of a thin inorganic–organic layer on various substrates as a result of controlled hydrolysis and polycondensation of alkoxysilanes. The sol–gel coatings created on the wood surface provide barrier properties, moisture control and repellency properties. In this communication we present new trialkoxysilanes synthesised from fatty acid derivatives and their application in wood protective coatings.


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