scholarly journals Modified epoxy resin with SEBS-g-MAH to fabricate crack-free and robust hydrophobic coatings on the surface of PP/SEBS matrix

2021 ◽  
pp. 101662
Author(s):  
Haoxuan Sun ◽  
Jun Zhang
Author(s):  
Georgel MIHU ◽  
Claudia Veronica UNGUREANU ◽  
Vasile BRIA ◽  
Marina BUNEA ◽  
Rodica CHIHAI PEȚU ◽  
...  

Epoxy resins have been presenting a lot of scientific and technical interests and organic modified epoxy resins have recently receiving a great deal of attention. For obtaining the composite materials with good mechanical proprieties, a large variety of organic modification agents were used. For this study gluten and gelatin had been used as modifying agents thinking that their dispersion inside the polymer could increase the polymer biocompatibility. Equal amounts of the proteins were milled together and the obtained compound was used to form 1 to 5% weight ratios organic agents modified epoxy materials. To highlight the effect of these proteins in epoxy matrix mechanical tests as three-point bending and compression were performed.


Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 89
Author(s):  
Wei Yuan ◽  
Qian Hu ◽  
Jiao Zhang ◽  
Feng Huang ◽  
Jing Liu

This study modified graphene oxide (GO) with hydrophilic octadecylamine (ODA) via covalent bonding to improve its dispersion in silicone-modified epoxy resin (SMER) coatings. The structural and physical properties of ODA-GO were characterized by field-emission scanning electron microscopy (FE-SEM), X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS), and contact angle tests. The ODA-GO composite materials were added to SMER coatings by physical mixing. FE-SEM, water absorption, and contact angle tests were used to evaluate the physical properties of the ODA-GO/SMER coatings, while salt spray, electrochemical impedance spectroscopy (EIS), and scanning Kelvin probe (SKP) methods were used to test the anticorrosive performance of ODA-GO/SMER composite coatings on Q235 steel substrates. It was found that ODA was successfully grafted onto the surfaces of GO. The resulting ODA-GO material exhibited good hydrophobicity and dispersion in SMER coatings. The anticorrosive properties of the ODA-GO/SMER coatings were significantly improved due to the increased interfacial adhesion between the nanosheets and SMER, lengthening of the corrosive solution diffusion path, and increased cathodic peeling resistance. The 1 wt.% ODA-GO/SMER coating provided the best corrosion resistance than SMER coatings with other amounts of ODA-GO (including no addition). After immersion in 3.5 wt.% NaCl solution for 28 days, the low-frequency end impedance value of the 1 wt.% ODA-GO/SMER coating remained high, at 6.2 × 108 Ω·cm2.


1992 ◽  
Vol 25 (13) ◽  
pp. 3492-3499 ◽  
Author(s):  
Alexander J. MacKinnon ◽  
Stephen D. Jenkins ◽  
Patrick T. McGrail ◽  
Richard A. Pethrick

2014 ◽  
Vol 1053 ◽  
pp. 263-267 ◽  
Author(s):  
Xiu Juan Tian

Thermal stability and thermal degradation kinetics of epoxy resins with 2-(Diphenylphosphinyl)-1, 4-benzenediol were investegated by thermogravimetric analysis (TGA) at different heating rates of 5 K/min, 10 K/min, 20 K/min and 40 K/min. The thermal degradation kinetic mechanism and models of the modified epoxy resins were determined by Coast Redfern method.The results showed that epoxy resins modified with the flame retardant had more thermal stability than pure epoxy resin. The solid-state decomposition mechanism of epoxy resin and the modified epoxy resin corresponded to the controlled decelerating ځ˽̈́˰̵̳͂͆ͅ˼˰̴̱̾˰̸̵̈́˰̵̸̳̱̹̽̾̓̽˰̶̳̹̾̈́̿̾̓ͅ˰̶˸ځ˹˰̵̵͇͂˰̃˸́˽ځ˹2/3. The introduction of phosphorus-containing flame retardant reduced thermal degradation rate of epoxy resins in the primary stage, and promote the formation of carbon layer.


2012 ◽  
Vol 510-511 ◽  
pp. 577-584 ◽  
Author(s):  
A. Quddos ◽  
Mohammad Bilal Khan ◽  
R.N. Khan ◽  
M.K.K. Ghauri

The impregnation of the fiber with a resin system, the polymeric matrix with the interface needs to be properly cured so that the dimensional stability of the matrix and the composite is ensured. A modified epoxy resin matrix was obtained with a reactive toughening agent and anhydride as a curing agent. The mechanical properties of the modified epoxy matrix and its fiber reinforced composites were investigated systematically. The polymeric matrix possessed many good properties, including high strength, high elongation at break, low viscosity, long pot life at room temperature, and good water resistance. The special attentions are given to the matrix due to its low out gassing, low water absorption and radiation resistance. In addition, the fiber-reinforced composites showed a high strength conversion ratio of the fiber and good fatigue resistance. The dynamic and static of the composite material were studied by thermo gravimetric analysis (TGA), Differential Scanning Calorimetry (DSC) and Scanning Electron Microscopy (SEM) with EDX. The influences of processing technique such as curing and proper mixing on the mechanical and interfacial properties were determined. The results demonstrated that the modified epoxy resin matrix is very suitable for applications in products fabricated with fiber-reinforced composites.


2003 ◽  
Vol 22 (4) ◽  
pp. 429-437 ◽  
Author(s):  
M.I. Giannotti ◽  
M.J. Galante ◽  
P.A. Oyanguren ◽  
C.I. Vallo

2016 ◽  
Vol 167 ◽  
pp. 160-167 ◽  
Author(s):  
I. Papa ◽  
M.R. Ricciardi ◽  
V. Antonucci ◽  
V. Lopresto ◽  
A. Langella

2014 ◽  
Vol 775-776 ◽  
pp. 588-592
Author(s):  
Camila Rodrigues Amaral ◽  
Ruben Jesus Sanchez Rodriguez ◽  
Magno Luiz Tavares Bessa ◽  
Verônica Scarpini Cândido ◽  
Sergio Neves Monteiro

The correlation between the structural network of a diglycidyl ether of the bisphenol-A (DGEBA) epoxy resin, modified by two distinct aliphatic amines (tetraethylenepentamine TEPA and jeffamine D230), and its mechanical properties, was investigated as possible matrix for abrasive composites applications. Both flexural tests, to determine the yield stress and the elastic modulus, as well as impact tests to determine the notch toughness, were performed. The DGEBA/D230 presented the highest stiffness and toughness but lowest yield stress. This epoxy network also displayed a greater plastic deformation during fracture.


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