Concentrations of contaminants in surface water samples collected in west-central Indiana impacted by acidic mine drainage

The relationships between pH, colour, Fe, Mn, Cu, Zn, Cd and sulphates in surface water samples collected from the Tinto and Odiel Rivers (southwest Spain) have been studied. These rivers are adversely affected by the inputs of acid and heavy metals due to Acid Mine Drainage (AMD). Samples were collected from both rivers on a monthly sampling basis from 1995 to 2001. The analytical results showed that pH (mean pH 3.1) in the water samples of the Odiel River presented a greater correlation with heavy metals, colour and sulphates than in the Tinto River (mean pH 2.5). The tidal effect at the sampling point at the Odiel River appears to cause a greater variation of the pH values (2.5–4.4), resulting in the precipitation of iron hydroxide and the co-precipitation of other metals when the pH increased. This phenomenon was not observed in the samples collected from the more acidic Tinto River (pH 2.1–3.2). A similar relationship was observed for the heavy metals and the colour of the surface water of both rivers.

Download Full-text

Occurrence of 1,4-dioxane and MTBE in drinking water sources in Japan

Water Science & Technology Water Supply ◽

10.2166/ws.2006.049 ◽

2006 ◽

Vol 6 (2) ◽

pp. 47-53 ◽

Cited By ~ 5

Author(s):

D. Simazaki ◽

M. Asami ◽

T. Nishimura ◽

S. Kunikane ◽

T. Aizawa ◽

...

Keyword(s):

Drinking Water ◽

Surface Water ◽

Water Samples ◽

Quality Standards ◽

Raw Water ◽

Water Quality Standards ◽

Butyl Ether ◽

Water Treatment Plants ◽

Standard Value ◽

Surface Water Samples

Nationwide surveys of 1,4-dioxane and methyl-t-butyl ether (MTBE) levels in raw water used for the drinking water supply were conducted at 91 water treatment plants in Japan in 2001 and 2002, prior to the revision of the drinking water quality standards. 1,4-dioxane was widely and continuously detected in raw water samples and its occurrence was more frequent and its concentrations higher in groundwater than in surface water. However, its maximum concentration in raw water was much lower than its new standard value (50 μg/L), which was determined as a level of 10−5 excessive cancer risk to humans. Trace levels of MTBE were also detected in several surface water samples.

Download Full-text

Development of Surface Molecularly Imprinted Polymers as Dispersive Solid Phase Extraction Coupled with HPLC Method for the Removal and Detection of Griseofulvin in Surface Water

International Journal of Environmental Research and Public Health ◽

10.3390/ijerph17010134 ◽

2019 ◽

Vol 17 (1) ◽

pp. 134 ◽

Cited By ~ 1

Author(s):

Kamran Bashir ◽

Zhimin Luo ◽

Guoning Chen ◽

Hua Shu ◽

Xia Cui ◽

...

Keyword(s):

Surface Water ◽

Solid Phase Extraction ◽

Molecularly Imprinted Polymers ◽

Water Samples ◽

Solid Phase ◽

Phase Extraction ◽

Dispersive Solid Phase Extraction ◽

Molecularly Imprinted ◽

Imprinted Polymers ◽

Surface Water Samples

Griseofulvin (GSF) is clinically employed to treat fungal infections in humans and animals. GSF was detected in surface waters as a pharmaceutical pollutant. GSF detection as an anthropogenic pollutant is considered as a possible source of drug resistance and risk factor in ecosystem. To address this concern, a new extraction and enrichment method was developed. GSF-surface molecularly imprinted polymers (GSF-SMIPs) were prepared and applied as solid phase extraction (SPE) sorbent. A dispersive solid phase extraction (DSPE) method was designed and combined with HPLC for the analysis of GSF in surface water samples. The performance of GSF-SMIPs was assessed for its potential to remove GSF from water samples. The factors affecting the removal efficiency such as sample pH and ionic strength were investigated and optimized. The DSPE conditions such as the amount of GSF-SMIPs, the extraction time, the type and volume of desorption solvents were also optimized. The established method is linear over the range of 0.1–100 µg/mL. The limits of detection and quantification were 0.01 and 0.03 µg/mL respectively. Good recoveries (91.6–98.8%) were achieved after DSPE. The intra-day and inter-day relative standard deviations were 0.8 and 4.3% respectively. The SMIPs demonstrated good removal efficiency (91.6%) as compared to powder activated carbon (67.7%). Moreover, the SMIPs can be reused 10 times for water samples. This is an additional advantage over single-use activated carbon and other commercial sorbents. This study provides a specific and sensitive method for the selective extraction and detection of GSF in surface water samples.

Download Full-text