Characterization of modifications of polymer surfaces after excimer laser treatments below the ablation threshold

2000 ◽  
Vol 154-155 ◽  
pp. 211-216 ◽  
Author(s):  
P Laurens ◽  
M Ould Bouali ◽  
F Meducin ◽  
B Sadras
2001 ◽  
Author(s):  
K. P. Adhi ◽  
R. L. Owings ◽  
T. A. Railkar ◽  
W. D. Brown ◽  
A. P. Malshe

Abstract We have investigated, using X-ray photoelectron spectroscopy (XPS), the surface of polyterafluoroethylene (PTFE) films which were subjected to micromachining by femtosecond UV radiation from an excimer laser (KrF: λ = 248 nm, tp ∼ 380 fs) in air ambient. Bulk characterization of processed PTFE films by Fourier transform infrared spectroscopy (FTIR) allowed us to study laser-induced modifications of the material at energy densities below the ablation threshold. No features in the XPS or FTIR spectra indicated incorporation of hydrogen and/or oxygen or the formation of cross-linked networks of carbon, indicating chemically clean processing in contrast to nanosecond excimer laser processing which chemically degrades the surface being machined. Scanning electron microscopy (SEM) of micrometer size microvias indicates mechanically and thermally damage-free processing of PTFE with good edge quality, again in contrast to nanosecond excimer laser processing.


1998 ◽  
Vol 544 ◽  
Author(s):  
G. Padeletti ◽  
M. Lapczyna ◽  
M. Stuke

AbstractSmooth polymer surfaces can be generated by VUV laser ablation at 157 nm. This has been demonstrated for poly-methyl-metacrylate (PMMA) by atomic force microscopy (AFM) analysis of laser-exposed surfaces. At excimer laser fluences below 30 mJ/cm2 the mean roughness (Ra) remains below 10 nm for both single and 10 shot exposures.A detailed characterization of the surface nano-morphology distribution carried out by the “power spectral density” (PSD) analysis, shows that the surface is smoothened by the VUV laser for lateral scales smaller than 20 μm.


1998 ◽  
Vol 72 (12) ◽  
pp. 1472-1474 ◽  
Author(s):  
Takashi Sugino ◽  
Hideaki Ninomiya ◽  
Junji Shirafuji ◽  
Koichiro Matsuda

1995 ◽  
Vol 34 (Part 1, No. 11) ◽  
pp. 6084-6091 ◽  
Author(s):  
Masamitsu Haruna ◽  
\ast ◽  
Hideki Ishizuki ◽  
Jun Tsutsumi ◽  
Yusaku Shimaoka ◽  
...  

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