Barite scale formation and dissolution at high ionic strength studied with atomic force microscopy

Author(s):  
Peter Risthaus ◽  
Dirk Bosbach ◽  
Udo Becker ◽  
Andrew Putnis
1999 ◽  
Vol 33 (21) ◽  
pp. 3911-3917 ◽  
Author(s):  
Eric Balnois ◽  
Kevin J. Wilkinson ◽  
Jamie R. Lead ◽  
Jacques Buffle

2000 ◽  
Vol 348 (3) ◽  
pp. 557-563 ◽  
Author(s):  
Matthew P. DEACON ◽  
Simon McGURK ◽  
Clive J. ROBERTS ◽  
Phillip M. WILLIAMS ◽  
Saul J. B. TENDLER ◽  
...  

Atomic force microscopy has been utilized to probe, at a molecular level, the interaction between purified pig gastric mucin (PGM) and a mucoadhesive cationic polymer, chitosan (sea cure 210+), with a low degree (approx. 11%) of acetylation. Images were produced detailing the structures of both PGM and chitosan in 0.1 M acetate buffer (pH 4.5), followed by the complex of the two structures in the same buffer. PGM in 0.1 M acetate buffer revealed long linear filamentous structures, consistent with earlier electron microscopy and scanning tunnelling micoscopy studies. The chitosan molecules also adopted a linear conformation in the same buffer, although with a smaller average length and diameter. They appeared to adopt a stiff-coil conformation consistent with earlier hydrodynamic measurements. The complexes formed after mixing PGM and chitosan together revealed large aggregates. In 0.1 M ionic strength buffer they were of the order of 0.7 μm in diameter, consistent with previous electron microscopy studies. The effect of ionic strength of the buffer on the structure of the complex was also studied and, together with molecular hydrodynamic data, demonstrates that the interaction is principally electrostatic in nature.


Nanomaterials ◽  
2021 ◽  
Vol 11 (9) ◽  
pp. 2320
Author(s):  
Gema Marcelo ◽  
María del Mar López-González ◽  
Milena Vega ◽  
Carlos Pecharromán

The polymerization of 3,4-dihydroxy-L-phenylalanine leads to a carboxylic acid-rich synthetic melanin-like material (poly-L-DOPA). Synthetic melanin most resembles natural eumelanin in chemical structure. However, its deposition on surfaces leading to colored surfaces by interference is not as easy to accomplish as in the case of the preparation of colored surfaces by dopamine hydrochloride polymerization. This study deals with the preparation of new colored surfaces made from poly-L-DOPA displaying vivid colors by interference. These surfaces were obtained by depositing thin films of poly-L-DOPA on a reflective silicon nitride substrate. A high ionic strength in the polymerization medium was essential to accomplish the coating. The effect of ionic strength on the resulting surfaces was studied via reflectance, Atomic Force Microscopy (AFM) and Scanning Electron Microscopy (SEM). The refractive index was determined by ellipsometry, and was nearly constant to 1.8 when λ > 650 nm. In the visible spectral region, the imaginary part of the refractive index becomes relevant. The refractive index in the visible wavelength range (400–600 nm) was in the range 1.7–1.80.


2014 ◽  
Vol 118 (31) ◽  
pp. 9322-9328 ◽  
Author(s):  
Yasunori Yokoyama ◽  
Kosuke Yamada ◽  
Yosuke Higashi ◽  
Satoshi Ozaki ◽  
Haorang Wang ◽  
...  

2013 ◽  
Vol 53 (supplement1-2) ◽  
pp. S176
Author(s):  
Yasunori Yokoyama ◽  
Kosuke Yamada ◽  
Yosuke Higashi ◽  
Satoshi Ozaki ◽  
Haorang Wang ◽  
...  

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