Effect of Improved ThO2 Particle Dispersion in Nickel on High-Temperature Strength

Author(s):  
E. R. Kimmel ◽  
H. L. Anthony ◽  
W. Scheithauer

The strengthening effect at high temperature produced by a dispersed oxide phase in a metal matrix is seemingly dependent on at least two major contributors: oxide particle size and spatial distribution, and stability of the worked microstructure. These two are strongly interrelated. The stability of the microstructure is produced by polygonization of the worked structure forming low angle cell boundaries which become anchored by the dispersed oxide particles. The effect of the particles on strength is therefore twofold, in that they stabilize the worked microstructure and also hinder dislocation motion during loading.

Author(s):  
M.S. Grewal ◽  
S.A. Sastri ◽  
N.J. Grant

Currently there is a great interest in developing nickel base alloys with fine and uniform dispersion of stable oxide particles, for high temperature applications. It is well known that the high temperature strength and stability of an oxide dispersed alloy can be greatly improved by appropriate thermomechanical processing, but the mechanism of this strengthening effect is not well understood. This investigation was undertaken to study the dislocation substructures formed in beryllia dispersed nickel alloys as a function of cold work both with and without intermediate anneals. Two alloys, one Ni-lv/oBeo and other Ni-4.5Mo-30Co-2v/oBeo were investigated. The influence of the substructures produced by Thermo-Mechanical Processing (TMP) on the high temperature creep properties of these alloys was also evaluated.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Zhi Dong ◽  
Zongqing Ma ◽  
Liming Yu ◽  
Yongchang Liu

AbstractWith excellent creep resistance, good high-temperature microstructural stability and good irradiation resistance, oxide dispersion strengthened (ODS) alloys are a class of important alloys that are promising for high-temperature applications. However, plagued by a nerve-wracking fact that the oxide particles tend to aggregate at grain boundary of metal matrix, their improvement effect on the mechanical properties of metal matrix tends to be limited. In this work, we employ a unique in-house synthesized oxide@W core-shell nanopowder as precursor to prepare W-based ODS alloy. After low-temperature sintering and high-energy-rate forging, high-density oxide nanoparticles are dispersed homogeneously within W grains in the prepared alloy, accompanying with the intergranular oxide particles completely disappearing. As a result, our prepared alloy achieves a great enhancement of strength and ductility at room temperature. Our strategy using core-shell powder as precursor to prepare high-performance ODS alloy has potential to be applied to other dispersion-strengthened alloy systems.


2017 ◽  
Vol 209 ◽  
pp. 581-584 ◽  
Author(s):  
S. Ukai ◽  
R. Miyata ◽  
S. Kasai ◽  
N. Oono ◽  
S. Hayashi ◽  
...  

1997 ◽  
Vol 3 (S2) ◽  
pp. 399-400
Author(s):  
Y.C. Lu ◽  
H. Kung ◽  
J-P Hirvonen ◽  
T.R. Jervis ◽  
M. Nastasi ◽  
...  

Thin film multilayers have been the focus of extensive studies recently due to the interesting properties they exhibit. Since the improvement in properties can be attributed directly to the unique nanoscale microstructures, it is essential to understand the factors affecting the microstructural stability in these nanolayer structures. The intermetallic compound, MoSi2, despite its superior oxidation resistance and high melting point, suffers from inadequate high temperature strength and low temperature ductility, properties which hinder its high temperature structural applications [1]. SiC is a potential second phase reinforcement due to its high temperature strength and thermal compatibility with MoSi2. The addition of SiC in a nanolayered configuration has been shown to exhibit significant increase in hardness after annealing [2]. It has also been shown that when annealed above 900°C, the layers break down and grain growth sets in, with a significant decrease in hardness and. Due to the lack of a thermochemical driving force, the two phases remain separate at all temperatures investigated. In this study, the stability of the MoSi2/SiC nanolayers structure under ion irradiation has been investigated.


2008 ◽  
Vol 595-598 ◽  
pp. 779-787
Author(s):  
Georg Kunschert ◽  
Hans Peter Martinz ◽  
Michael Schütze

In recent years solid-oxide fuel cell (SOFC) interconnect components have proven to be a key-component accountable for the functionality of high temperature fuel cells. Amongst adequate thermal expansion and high temperature strength, highest oxidation resistance in anode and cathode gases under thermal cycling conditions is required in order to reach long term durability, particularly when using thin film light-weight components with particular focus on automotive applications. In order to match the challenging parameter profile Plansee developed the mechanically alloyed ITM, a ferritic P/M Fe26Cr alloy strengthened with additions of Y2O3 dispersoids, since it has been observed that apart from their HT strengthening effect, which is of specific interest for thin sheets components, finest ODS particles reduce the growth and enhance the adhesion of the forming oxide layers. The latter effect is of particular interest in applications where alloys are exposed to HT cyclic conditions. In this work the nucleation phase of the oxide scale formation on P/M ODS Fe26Cr ITM is compared to that on a reference ingot steel Fe22Cr in typical anode gases containing significant amounts of H2, CO and approximately 3% H2O as well as in laboratory air at 850°C. Thermal cycling oxidation tests following the COTEST standard up to 168h are carried out in both environments. Moreover cyclic oxidation tests are performed in dry anode gas. Detailed studies of oxide scale formation and evolution by means of electron microscopy of cross sections as well as oxide surfaces are undertaken.


Author(s):  
Yuhei Suzuki ◽  
Shogo Aota ◽  
Etsuo Dan ◽  
Masaki Ueyama ◽  
Takahiro Osuki ◽  
...  

Abstract Austenitic materials with high sensitization resistance and high temperature strength are required for furnace and reaction tower of desulfurizing plants in the petroleum refinery industry. For these requirements, a new steel (LowC-18Cr-11Ni-3Cu-Mo-Nb-B-N) has been developed. The steel shows no intergranular stress corrosion cracking in polythionic acid environment after aging in the temperature range from 565 to 700 °C for up to 10,000 hours. This excellent PTA-SCC resistance is attributed to the prevention of M23C6 carbide precipitation along grain boundary due to extra low carbon content with high ratio of niobium to carbon. The maximum allowable tensile stress of this steel is estimated to be more than 30% higher than that of ASME SA213 Type347H. This excellent strength is based on the precipitation strengthening effect due to fine precipitates of a copper rich phase which are coherent with the austenite matrix in addition to Z-phase (NbCrN). Moreover, boron addition improves creep strength and creep ductility of the steel. From these results, it is concluded that the newly developed steel is a promising material not only for refinery processes but also for other elevated temperature usages.


2008 ◽  
Vol 53 (21) ◽  
pp. 3416-3421 ◽  
Author(s):  
ChongHong Zhang ◽  
J. S. Jang ◽  
YiTao Yang ◽  
Yin Song ◽  
YouMei Sun ◽  
...  

Author(s):  
Yachao Wang ◽  
Jing Shi ◽  
Shiqiang Lu ◽  
Yun Wang

Graphene nanoplatelets (GNPs) have many outstanding properties, such as high mechanical strengths, light weight, and high electric conductivity. These unique properties make it an ideal reinforcement used for metal matrix composite (MMCs). In the past few years, many studies have been performed to incorporate GNPs into metal matrix and investigate the properties of obtained metal matrix composites. Meanwhile, fabrication of MMCs through laser assisted additive manufacturing (LAAM) has attracted much attention in recent years due to the advantages of low waste, high precision, short production lead time, and high workpiece complexity capability. In this study, the two attractive features are combined to produce GNPs reinforced MMC using selective laser melting (SLM) process, one of the LAAM processes. The target metal matrix material is Inconel 718, a nickel-based Ni-Cr-Fe austenitic superalloy that possesses excellent workability and mechanical performance and has wide applications in industries. Inconel 718 holds outstanding mechanical performance, corrosion, oxidation, and wear performance over a wide range of temperatures, making it an attractive superalloy used for high temperature service components. In the experiment, pure Inconel 718 and GNPs reinforced Inconel 718 composites with two levels of GNPs content (i.e., 0.25 and 1 wt.%) are obtained by SLM. Note that the SLM process, a novel powder mixture procedure is adopted to ensure the even dispersion of GNPs in the Inconel 718 powders. Room temperature tensile tests are conducted to evaluate the tensile properties. Scanning electron microscopy (SEM) observations are conducted to analyze the fracture surface of materials and to understand the reinforcing mechanism. It is found that fabrication of GNPs reinforced MMC using SLM is a viable approach. The obtained composite possesses dense microstructure and significantly enhanced tensile strength. The ultimate tensile strengths (UTS) are 997.8, 1296.3 and 1511.6 MPa, and the Young’s moduli are 475, 536, and 675 GPa, for 0 wt.% (pure Inconel 718), 0.25 wt.%, and 1 wt.% GNP additions, respectively. The bonding between GNPs and matrix material appears to be strong, and GNPs are well retained during the SLM process. The strengthening effect and mechanisms involved in the composites are discussed. Load transfer, thermal expansion coefficient mismatch, and dislocation hindering are believed to be the three main reinforcing mechanisms involved. It should be noted that more work needs to be conducted in the future to obtain more comprehensive information regarding other static and dynamic properties, and the high temperature performances of the GNP reinforced MMCs produced by SLM. Process parameter optimization should also be investigated.


2005 ◽  
Vol 475-479 ◽  
pp. 1987-1990 ◽  
Author(s):  
Yoko Yamabe-Mitarai ◽  
Toru Hara ◽  
Seiji Miura ◽  
Hideki Hosoda

We have suggested B2-(Pt, Ir)Ti as high temperature shape memory alloys. The phase transformation of (Pt, Ir)-50at% Ti from B2 to B19(2H) or 4H(4O) structures was investigated in our previous study. The microstructure suggested martensitic transformation. In this study, thermal expansion measurement and cyclic compression test were performed for (Pt, Ir)Ti to investigate if the shape memory effect appears. High temperature strength was also investigated because phase transformation temperature of the (Pt, Ir)Ti is above 1273 K and high strength is necessary as high temperature shape memory alloys in order to suppress dislocation motion and stabilize martenstic transformation. The potential of (Pt, Ir)Ti as high temperature shape memory alloys will be also discussed.


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