Computer-Aided Design of a Perfluorinated Sulfonic Acid Proton Exchange Membrane Using Stochastic Optimization and Molecular Dynamic Method

2021 ◽  
Author(s):  
Wenjing Guo ◽  
Qilei Liu ◽  
Lei Zhang ◽  
Jian Du ◽  
Xiuling Zhu ◽  
...  
Keyword(s):  
Computer Aided Design ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Molecular Dynamic Method ◽  
Dynamic Method ◽  
Proton Exchange ◽  
Acid Proton ◽  
Perfluorinated Sulfonic Acid ◽  
Aided Design ◽  
Exchange Membrane

scholarly journals Evaluation of fluorine and sulfonic acid co-functionalized graphene oxide membranes under hydrogen proton exchange membrane fuel cell conditions

2019 ◽  
Vol 3 (7) ◽  
pp. 1790-1798 ◽  
Author(s):  
Robin Sandström ◽  
Alagappan Annamalai ◽  
Nicolas Boulanger ◽  
Joakim Ekspong ◽  
Alexandr Talyzin ◽  
...  
Keyword(s):  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Two Dimensional ◽  
Functionalized Graphene ◽  
Functionalized Graphene Oxide ◽  
Perfluorinated Sulfonic Acid ◽  
Exchange Membrane ◽  
Oxide Membranes ◽  
Graphene Oxide Membranes

Two-dimensional perfluorinated sulfonic acid represent an intriguing new proton exchange membrane concept.

scholarly journals Hydrocarbon-based Pemion™ proton exchange membrane fuel cells with state-of-the-art performance

2021 ◽  
Author(s):  
Hien T. T. Nguyen ◽  
Florian Lombeck ◽  
Claudia Schwarz ◽  
Philipp A. Heizmann ◽  
Michael Adamski ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Fuel Cells ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
State Of The Art ◽  
Proton Exchange ◽  
Art Performance ◽  
Perfluorinated Sulfonic Acid ◽  
Technical Cost ◽  
Exchange Membrane

Non-fluorinated hydrocarbon ionomers feature distinct technical, cost and environmental advantages over incumbent perfluorinated sulfonic acid (PFSA)-based ionomers: they offer improved thermo-mechanical properties at temperatures beyond 90 °C, likelihood of lower...

Do acid–base interactions really improve the ion conduction in a proton exchange membrane? – a study on the effect of basic groups

2019 ◽  
Vol 7 (34) ◽  
pp. 19820-19830 ◽  
Author(s):  
Yuqian Sui ◽  
Yexin Du ◽  
Huayuan Hu ◽  
Jieshu Qian ◽  
Xuan Zhang
Keyword(s):  
Physicochemical Properties ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
Acid Base ◽  
Ion Conduction ◽  
Exchange Membrane ◽  
Sulfonic Acid Groups

Generating acid–base interactions between sulfonic acid groups in a proton exchange membrane (PEM) and the incorporation of basic groups are effective approaches to improving the physicochemical properties of a membrane.

Structure and Morphology of PVDF-G-PAMPS Membrane

2011 ◽  
Vol 197-198 ◽  
pp. 1321-1324 ◽  
Author(s):  
Gui Bao Guo ◽  
Sheng Li An
Keyword(s):  
Fourier Transform ◽  
Infrared Spectroscopy ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Vinylidene Fluoride ◽  
Proton Exchange ◽  
Pvdf Membrane ◽  
Structure And Morphology ◽  
Poly Vinylidene Fluoride ◽  
Exchange Membrane

A proton exchange membrane of blended poly (acrylamido-2- methylpropane sulfonic acid) (PAMPS) grafted onto modified poly (vinylidene fluoride) (PVDF) membrane (PVDF-g-PAMPS) was prepared. Fourier transform infrared spectroscopy is used to characterize changes of the membrane's microstructures after grafting. The morphology of the membrane's microstructures after grafting is studied by scanning electrolytic microscope.The results show that 2-acrylamido-2-methylpropane sulfonic acid is easily grafted into PVDF modified by Plain sodium silicate (Na4SiO4).

Studies on Preparation and Methanol Permeability of PVDF-g-PAMPS Membrane

2011 ◽  
Vol 335-336 ◽  
pp. 157-160 ◽  
Author(s):  
Jia Xu ◽  
Gui Bao Guo
Keyword(s):  
Sodium Silicate ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Vinylidene Fluoride ◽  
Ammonium Persulfate ◽  
Proton Exchange ◽  
Methanol Permeability ◽  
Poly Vinylidene Fluoride ◽  
Methyl Pyrrolidone ◽  
Exchange Membrane

A proton exchange membrane of poly (vinylidene fluoride) grafted onto poly (2-acrylamido-2-methylpropane sulfonic acid) (PVDF-g-PAMPS) was prepared as follows: acrylamido-2-methylpropane sulfonic acid (AMPS) was first added to a N-Methyl pyrrolidone (NMP) solution containing poly (vinylidene fluoride) (PVDF) that was modified with plain sodium silicate. Ammonium persulfate was then added as an evocating agent and PAMPS was directly grafted onto the PVDF that was modified with plain sodium silicate. The influences of AMPS contents on the proton conductivity and methanol permeability were studied. The results showed that AMPS is easily grafted into PVDF modified by Plain sodium silicate (Na4SiO4), with increasing of the content of 2-acrylamido-2-methylpropane sulfonic acid, the methanol permeability became large gradually of PVDF-g-PAMPS membranes was increased.

Ionomers for Proton Exchange Membrane Fuel Cells with Sulfonic Acid Groups on the End Groups:  Novel Linear Aromatic Poly(sulfide−ketone)s

2008 ◽  
Vol 41 (2) ◽  
pp. 277-280 ◽  
Author(s):  
Sumiko Matsumura ◽  
Antisar R. Hlil ◽  
Catherine Lepiller ◽  
Julie Gaudet ◽  
Daniel Guay ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Sulfonic Acid ◽  
Proton Exchange Membrane ◽  
Proton Exchange ◽  
End Groups ◽  
Exchange Membrane ◽  
Sulfonic Acid Groups
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