Kinetics and Mechanism of Benzene Derivative Degradation with Fenton's Reagent in Aqueous Medium Studied by MIMS

1998 ◽  
Vol 102 (52) ◽  
pp. 10723-10727 ◽  
Author(s):  
Rodinei Augusti ◽  
Adelson O. Dias ◽  
Lilian L. Rocha ◽  
Rochel M. Lago
Keyword(s):  
Aqueous Medium ◽  
Kinetics And Mechanism ◽  
Benzene Derivative ◽  
Fenton’S Reagent ◽  
Fenton's Reagent

Kinetics and mechanism of oxidative decomposition of Congo red by Fenton’s reagent and its synergic effects on exposure to UV radiation

2021 ◽  
Vol 25 (7) ◽  
pp. 8-12
Author(s):  
P. Rajendran ◽  
K. Geethu ◽  
P. Bashpa ◽  
K. Bijudas
Keyword(s):  
Congo Red ◽  
Homogeneous Medium ◽  
Ultra Violet ◽  
Kinetics And Mechanism ◽  
Fenton’S Reagent ◽  
Fenton Reagent ◽  
Fenton's Reagent ◽  
Oxidative Decomposition ◽  
Ultra Violet Radiation ◽  
Thermodynamic Variables

Congo red is a toxic azo dye which is used extensively in industries like textile, paper, pulp and paper. Very high amount of Congo red from these industrial sources is discharged into natural water bodies resulting environmental pollution. The present work reports the kinetics and mechanism of oxidative decomposition of Congo red by Fenton’s reagent in homogeneous medium and also under ultra violet light irradiation. Kinetic parameters like effect of [Fe2+], [H2O2], [Congo red] and temperature on the decomposition of Congo red were studied. The reaction is found to be fractional order with [Fe2+] and first order with [H2O2] and [Congo red]. The rate of oxidative decomposition of Congo red by Fenton’ reagent showed a rapid increase of three times when irradiated with ultra violet radiation and completion of reaction occurred within 5-6 minute. Various thermodynamic variables were determined and the presence of isosbestic points on sequential scanning of oxidation kinetics proves that the reaction is very smooth, spontaneous and endothermic. A suitable mechanism is suggested based on the experimental results obtained.

A green approach to Fenton chemistry: mono-hydroxylation of salicylic acid in aqueous medium by the electrogeneration of Fenton's reagent

2012 ◽  
Vol 36 (5) ◽  
pp. 1265 ◽  
Author(s):  
Janjira Panchompoo ◽  
Leigh Aldous ◽  
Mikhail Kabeshov ◽  
Ben S. Pilgrim ◽  
Timothy J. Donohoe ◽  
...  
Keyword(s):  
Salicylic Acid ◽  
Aqueous Medium ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Fenton Chemistry ◽  
Green Approach

Use of Fenton's Reagent for the Degradation of TCE in Aqueous Systems and Soil Slurries

2000 ◽  
Vol 9 (4) ◽  
pp. 331-345 ◽  
Author(s):  
Katherine R. Weeks ◽  
Clifford J. Bruell ◽  
Nihar R. Mohanty
Keyword(s):  
Fenton’S Reagent ◽  
Aqueous Systems ◽  
Fenton's Reagent

The action of fenton's reagent on carbohydrates

Tetrahedron ◽  
1963 ◽  
Vol 19 (11) ◽  
pp. 1705-1710 ◽  
Author(s):  
G.J. Moody
Keyword(s):  
Fenton’S Reagent ◽  
Fenton's Reagent

Additions and Corrections - Oxidation of Mandelic Acid by Fenton's Reagent

1982 ◽  
Vol 104 (13) ◽  
pp. 3783-3783
Author(s):  
Cheves Walling ◽  
Kalyani Amarnath ◽  
Curt Campbell
Keyword(s):  
Mandelic Acid ◽  
Fenton’S Reagent ◽  
Fenton's Reagent

Coagulation of textile secondary effluents with Fenton's reagent

1997 ◽  
Vol 36 (12) ◽  
pp. 215-222 ◽  
Author(s):  
Shyh-Fang Kang ◽  
Huey-Min Chang
Keyword(s):  
Hydrogen Peroxide ◽  
Cod Removal ◽  
Color Removal ◽  
Fenton’S Reagent ◽  
Fenton's Reagent ◽  
Effluent Standards ◽  
Secondary Effluents ◽  
Removal Efficiencies

This study was designed to use both artificial and real textile secondary effluents to evaluate (1) the COD and color removal efficiencies for ferrous coagulation and Fenton's coagulation, and (2) the feasibility of using hydrogen peroxide to improve ferrous coagulation to meet more stringent effluent standards. The results indicate that the optimum pHs for both ferrous coagulation and Fenton's preoxidation processes range between 8.0–10 and 3.0–5.0, respectively. The rate for color removal is faster than that for COD removal in the Fenton's preoxidation process. The removals of COD and color are mainly accomplished during Fenton's preoxidation step. The ratio of COD removal for Fenton's coagulation versus ferrous coagulation, given the same ferrous dosage, ranges from 1.4 to 2.3, and it ranges from 1.1 to 1.9 for color removal, using two effluent samples. Therefore, using hydrogen peroxide can enhance the ferrous coagulation, and this ensures more stringent effluent standards of COD and color are met.

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